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Fluorine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 101 to 150

Fluorine anion + Oxirane, (fluoromethyl)- = (Fluorine anion bullet Oxirane, (fluoromethyl)-)

By formula: F- + C3H5FO = (F- bullet C3H5FO)

Quantity Value Units Method Reference Comment
Deltar107. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar99.2J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar77.0 ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Propanal, 2,2-dimethyl- = (Fluorine anion bullet Propanal, 2,2-dimethyl-)

By formula: F- + C5H10O = (F- bullet C5H10O)

Quantity Value Units Method Reference Comment
Deltar103. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar70.3 ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + 2,2,2-Trifluoroethylamine = (Fluorine anion bullet 2,2,2-Trifluoroethylamine)

By formula: F- + C2H4F3N = (F- bullet C2H4F3N)

Quantity Value Units Method Reference Comment
Deltar118. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar84.9 ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Aniline = (Fluorine anion bullet Aniline)

By formula: F- + C6H7N = (F- bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar131. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar97.9 ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + 1-Propanol = (Fluorine anion bullet 1-Propanol)

By formula: F- + C3H8O = (F- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar135. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar103. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + 1-Butanol = (Fluorine anion bullet 1-Butanol)

By formula: F- + C4H10O = (F- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar135. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar103. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Fluoroform = (Fluorine anion bullet Fluoroform)

By formula: F- + CHF3 = (F- bullet CHF3)

Quantity Value Units Method Reference Comment
Deltar113. ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
Deltar82.0 ± 8.4kJ/molIMRELarson and McMahon, 1983gas phase; B,M

(Fluorine anion bullet 11Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 12Methyl Alcohol)

By formula: (F- bullet 11CH4O) + CH4O = (F- bullet 12CH4O)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.6 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Fluorine anion bullet 6Acetonitrile) + Acetonitrile = (Fluorine anion bullet 7Acetonitrile)

By formula: (F- bullet 6C2H3N) + C2H3N = (F- bullet 7C2H3N)

Quantity Value Units Method Reference Comment
Deltar35.6kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.42kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Fluorine anion bullet 7Water) + Water = (Fluorine anion bullet 8Water)

By formula: (F- bullet 7H2O) + H2O = (F- bullet 8H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.9 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; 0.4; M
Quantity Value Units Method Reference Comment
Deltar7.5 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Fluorine anion + Xenon = (Fluorine anion bullet Xenon)

By formula: F- + Xe = (F- bullet Xe)

Quantity Value Units Method Reference Comment
Deltar26.4 ± 1.3kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; B
Deltar27.2 ± 3.8kJ/molMoblDe Vreugd, Wijnaendts van Resandt, et al., 1979gas phase; B
Deltar27.kJ/molSCATTERINGDe Vrengd, Wijnaendts van Resandt, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.4 ± 1.3kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; B

(Fluorine anion bullet 5Water) + Water = (Fluorine anion bullet 6Water)

By formula: (F- bullet 5H2O) + H2O = (F- bullet 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar45.6 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar15. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion bullet 6Water) + Water = (Fluorine anion bullet 7Water)

By formula: (F- bullet 6H2O) + H2O = (F- bullet 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.5 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar11. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion bullet 8Water) + Water = (Fluorine anion bullet 9Water)

By formula: (F- bullet 8H2O) + H2O = (F- bullet 9H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.4 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar137.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.4 ± 8.8kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Fluorine anion + vanadium tetrafluoride = (Fluorine anion bullet vanadium tetrafluoride)

By formula: F- + vanadium tetrafluoride = (F- bullet vanadium tetrafluoride)

Quantity Value Units Method Reference Comment
Deltar365. ± 24.kJ/molTDEqKuznetsov, Korobov, et al., 1989gas phase; Fluoride Affinity: 14.2±3.9 kcal/mol < UF4; B
Deltar363. ± 27.kJ/molTDEqSidorov, Boltalina, et al., 1989gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion bullet Sulfur hexafluoride) + Sulfur hexafluoride = (Fluorine anion bullet 2Sulfur hexafluoride)

By formula: (F- bullet F6S) + F6S = (F- bullet 2F6S)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K; B
Quantity Value Units Method Reference Comment
Deltar-5.9 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K; B

Fluorine anion + Methyl Alcohol = CH3D4FO-

By formula: F- + CH4O = CH3D4FO-

Quantity Value Units Method Reference Comment
Deltar125. ± 8.4kJ/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B
Quantity Value Units Method Reference Comment
Deltar93.7 ± 8.4kJ/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B

Fluorine anion + Uranium hexafluoride = (Fluorine anion bullet Uranium hexafluoride)

By formula: F- + F6U = (F- bullet F6U)

Quantity Value Units Method Reference Comment
Deltar237. ± 30.kJ/molTherPyatenko, Guasarov, et al., 1984gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention; B
Deltar190. ± 42.kJ/molIMRBBeauchamp, 1976gas phase; B

Fluorine anion + 2',3',4',5',6'-Pentafluoroacetophenone = (Fluorine anion bullet 2',3',4',5',6'-Pentafluoroacetophenone)

By formula: F- + C8H3F5O = (F- bullet C8H3F5O)

Quantity Value Units Method Reference Comment
Deltar157. ± 8.4kJ/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B
Quantity Value Units Method Reference Comment
Deltar121. ± 8.4kJ/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B

(Fluorine anion bullet 3Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 4Carbon dioxide)

By formula: (F- bullet 3CO2) + CO2 = (F- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar24. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-0.8 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion bullet 4Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 5Carbon dioxide)

By formula: (F- bullet 4CO2) + CO2 = (F- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar23. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-4.2 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion bullet 5Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 6Carbon dioxide)

By formula: (F- bullet 5CO2) + CO2 = (F- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar22. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar-5.9 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion bullet 5Acetonitrile) + Acetonitrile = (Fluorine anion bullet 6Acetonitrile)

By formula: (F- bullet 5C2H3N) + C2H3N = (F- bullet 6C2H3N)

Quantity Value Units Method Reference Comment
Deltar40.6 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 3.8kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Fluorine anion + tetrafluorogermane = (Fluorine anion bullet tetrafluorogermane)

By formula: F- + F4Ge = (F- bullet F4Ge)

Quantity Value Units Method Reference Comment
Deltar418. ± 29.kJ/molTherMallouk, Rosenthal, et al., 1984gas phase; Fluoride affinities from this method appear to be consistently about 10 kcal/mol too bound; B
Deltar>404.6kJ/molIMRBHarland, Cradock, et al., 1972gas phase; B

(Fluorine anion bullet 2Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 3Carbon dioxide)

By formula: (F- bullet 2CO2) + CO2 = (F- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar30. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar2. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion bullet Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 2Carbon dioxide)

By formula: (F- bullet CO2) + CO2 = (F- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar31. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.9 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion bullet 10Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 11Methyl Alcohol)

By formula: (F- bullet 10CH4O) + CH4O = (F- bullet 11CH4O)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.2 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 4Methyl Alcohol)

By formula: (F- bullet 3CH4O) + CH4O = (F- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar52.3 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar98.3J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar23. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 5Methyl Alcohol)

By formula: (F- bullet 4CH4O) + CH4O = (F- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar16. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 6Methyl Alcohol)

By formula: (F- bullet 5CH4O) + CH4O = (F- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar11. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 10Methyl Alcohol)

By formula: (F- bullet 9CH4O) + CH4O = (F- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.4 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet Carbon disulfide) + Carbon disulfide = (Fluorine anion bullet 2Carbon disulfide)

By formula: (F- bullet CS2) + CS2 = (F- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar28.0 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar64.0J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Fluorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 7Methyl Alcohol)

By formula: (F- bullet 6CH4O) + CH4O = (F- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 8Methyl Alcohol)

By formula: (F- bullet 7CH4O) + CH4O = (F- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 9Methyl Alcohol)

By formula: (F- bullet 8CH4O) + CH4O = (F- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.3 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

Fluorine anion + F3Y = (Fluorine anion bullet F3Y)

By formula: F- + F3Y = (F- bullet F3Y)

Quantity Value Units Method Reference Comment
Deltar477. ± 21.kJ/molTDEqPyatenko, Gusarov, et al., 1981gas phase; F-A at 0 K; «DELTA»Hf at 298 K. Equilibrium measured vs. AlF4-; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Benzene, hexafluoro- = (Fluorine anion bullet Benzene, hexafluoro-)

By formula: F- + C6F6 = (F- bullet C6F6)

Quantity Value Units Method Reference Comment
Deltar115. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar99.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 3gas phase; M
Quantity Value Units Method Reference Comment
Deltar85.4 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Fluorine anion + F4Th = (Fluorine anion bullet F4Th)

By formula: F- + F4Th = (F- bullet F4Th)

Quantity Value Units Method Reference Comment
Deltar436. ± 15.kJ/molTherSidirov, Zhuravlena, et al., 1983gas phase; Fluoride Affinity: 21.1 kcal < AlF3, 3.6 kcal < ZrF4; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion bullet F6S-) + F6S- = (Fluorine anion bullet 2F6S-)

By formula: (F- bullet F6S-) + F6S- = (F- bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M

(Fluorine anion bullet 6Nitrous oxide) + Nitrous oxide = (Fluorine anion bullet 7Nitrous oxide)

By formula: (F- bullet 6N2O) + N2O = (F- bullet 7N2O)

Quantity Value Units Method Reference Comment
Deltar14.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Fluorine anion bullet 6Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 7Carbon dioxide)

By formula: (F- bullet 6CO2) + CO2 = (F- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AHiraoka, Mizuse, et al., 1987, 2gas phase; Entropy change calculated or estimated; M

Fluorine anion + Benzene = (Fluorine anion bullet Benzene)

By formula: F- + C6H6 = (F- bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar64.02kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar39.3kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Fluorine anion + F4MoO = (Fluorine anion bullet F4MoO)

By formula: F- + F4MoO = (F- bullet F4MoO)

Quantity Value Units Method Reference Comment
Deltar402.5kJ/molTDEqBorchevsky and Sidorov, 1985gas phase; Fluoride Affinity: MoOF3 < MoF5 by 4.0±2.0 kcal/mol; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Be2F4 = (Fluorine anion bullet Be2F4)

By formula: F- + Be2F4 = (F- bullet Be2F4)

Quantity Value Units Method Reference Comment
Deltar464.4 ± 8.4kJ/molTDEqNikitin, Sorokin, et al., 1980gas phase; Fluoride Affinity of Be2F4: 6.3±2 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion bullet 4Tetrafluoromethane) + Tetrafluoromethane = (Fluorine anion bullet 5Tetrafluoromethane)

By formula: (F- bullet 4CF4) + CF4 = (F- bullet 5CF4)

Quantity Value Units Method Reference Comment
Deltar10.kJ/molPHPMSHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KN/AHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated; M

Fluorine anion + CrF4 = (Fluorine anion bullet CrF4)

By formula: F- + CrF4 = (F- bullet CrF4)

Quantity Value Units Method Reference Comment
Deltar411. ± 40.kJ/molTDEqBoltalina, Borshchevskii, et al., 1991gas phase; Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + AuF3 = (Fluorine anion bullet AuF3)

By formula: F- + AuF3 = (F- bullet AuF3)

Quantity Value Units Method Reference Comment
Deltar426. ± 25.kJ/molTDEqChilingarov, Korobov, et al., 1986gas phase; Fluoride Affinity: 1.2±5.0 kcal/mol > MnF3; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + CrF3 = (Fluorine anion bullet CrF3)

By formula: F- + CrF3 = (F- bullet CrF3)

Quantity Value Units Method Reference Comment
Deltar387. ± 15.kJ/molTDEqBoltalina, Borshchevskii, et al., 1991gas phase; Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Aluminum chloride fluoride = (Fluorine anion bullet Aluminum chloride fluoride)

By formula: F- + AlCl2F = (F- bullet AlCl2F)

Quantity Value Units Method Reference Comment
Deltar499. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Aluminum chloride fluoride = (Fluorine anion bullet Aluminum chloride fluoride)

By formula: F- + AlClF2 = (F- bullet AlClF2)

Quantity Value Units Method Reference Comment
Deltar491. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

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Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

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De Vreugd, C.; Wijnaendts van Resandt, R.W.; Los, J., The Well Depths of XeF- and XeCl- from Differential Scattering Measurements, Chem. Phys. Lett., 1979, 65, 1, 93, https://doi.org/10.1016/0009-2614(79)80134-7 . [all data]

De Vrengd, Wijnaendts van Resandt, et al., 1979
De Vrengd, C.; Wijnaendts van Resandt, R.W.; Los, J., The well depths of XeF- and XeCl- from differential scattering measurements, Chem. Phys. Lett., 1979, 65, 93. [all data]

Kuznetsov, Korobov, et al., 1989
Kuznetsov, S.V.; Korobov, M.V.; Sidorov, L.N., Gas-Phase Negative Ion Chemistry of Platinum Metal Fluorides. III. Negative Ions of Pentafluorides., Int. J. Mass Spectrom. Ion Proc., 1989, 91, 3, 283, https://doi.org/10.1016/0168-1176(89)80083-7 . [all data]

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Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya., Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections., Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4 . [all data]

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Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M.; Fujimaki, S.; Yamabe, S., The small binding energies of the negative cluster ions: SF5-(SF6)1, SF6-(SF6)1 and F-(SF6)n (n=1 and 2), in the gas phase, Chem. Phys. Lett., 1995, 241, 5-6, 623, https://doi.org/10.1016/0009-2614(95)00676-U . [all data]

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Wilkinson, F.E.; Szulejko, J.E.; Allison, C.E.; Mcmahon, T.B., Fourier Transform Ion Cyclotron Resonance Investigation of the Deuterium Isotope Effect on Gas Phase Ion/Molecule Hydrogen Bonding Interactions in Alcohol-Fluoride Adduct Ions, Int. J. Mass Spectrom., 1992, 117, 487-505, https://doi.org/10.1016/0168-1176(92)80110-M . [all data]

Pyatenko, Guasarov, et al., 1984
Pyatenko, A.T.; Guasarov, A.V.; Gorokhov, L.N., Thermochemistry of Negative Ions in the U-F System, Russ. J. Phys. Chem., 1984, 58, 1. [all data]

Beauchamp, 1976
Beauchamp, J.L., Ion cyclotron resonance studies of endothermic reactions of UF6-Generated by surface ionization, J. Chem. Phys., 1976, 64, 929. [all data]

Dillow and Kebarle, 1988
Dillow, G.W.; Kebarle, P., Fluoride Affinities of Perfluorobenzenes C6F5X. Meisenheimer Complexes in the Gas Phase and Solution, J. Am. Chem. Soc., 1988, 110, 15, 4877, https://doi.org/10.1021/ja00223a001 . [all data]

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Hiraoka, K.; Mizuse, S.; Yamabe, S., A Determination of the Stability and Structure of F-(C6H6) and F-(C6F6) Clusters, J. Chem. Phys., 1987, 86, 7, 4102, https://doi.org/10.1063/1.451920 . [all data]

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Mallouk, T.E.; Rosenthal, G.L.; Muller, G.; Brusasco, R.; Bartlett, N., Fluoride ion affinities of GeF4 and BF4 from thermodynamic and structural data for (SF2)2GeF6, ClO2GeF5, and ClO2BF4, Inorg. Chem., 1984, 23, 3167. [all data]

Harland, Cradock, et al., 1972
Harland, P.W.; Cradock, S.; Thynne, J.C.J., Positive- and negative-ion formation due to the electron bombardment of germanium tetrafluoride, Int. J. Mass Spectrom. Ion Phys., 1972, 10, 169. [all data]

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Pyatenko, A.T.; Gusarov, A.V.; Gorokhov, L.N., Negative Ions in Vapor over Yttrium Trifluoride, High Temp., 1981, 19, 1167. [all data]

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Sidirov, Zhuravlena, et al., 1983
Sidirov, L.N.; Zhuravlena, L.V.; Varkov, M.V.; Skokan, E.V.; Sorokin, I.D.; Koronev, Yu.M.; Akishima, P.A., Mass- spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. VII. MF-ThF4 systems, Int. J. Mass Spectrom. Ion Processes, 1983, 51, 291. [all data]

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Borchevsky, A.Ya.; Sidorov, L.N., Ion-Molecule, Ion-Ion, and Molecule-Molecule Equilibria in the System Mo-U-Fe-F-O-e-, Dokl. Akad. Nauk SSSR Ser. Khim., 1985, 285, 377. [all data]

Nikitin, Sorokin, et al., 1980
Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N., Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems, Russ. J. Phys. Chem., 1980, 54, page]. [all data]

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Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Weak Ion-Molecule Complexes of F-(CF4)n and CF3-(CF4)n, Chem Phys. Let., 1995, 245, 1, 14, https://doi.org/10.1016/0009-2614(95)00980-I . [all data]

Boltalina, Borshchevskii, et al., 1991
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of Chromium Gaseous Fluorides and Their Negative Ions, Zh. Fiz. Khim. SSSR, 1991, 65, 884. [all data]

Pramann and Rademann, 1999
Pramann, A.; Rademann, K., Mass-spectrometric study of formation and stability of manganese and manganese oxide cluster anions, Int. J. Mass Spectrom., 1999, 187, 673-683, https://doi.org/10.1016/S1387-3806(98)14197-0 . [all data]

Chilingarov, Korobov, et al., 1986
Chilingarov, N.S.; Korobov, M.V.; Rudometkin, S.V.; Alikhayan, A.S.; Sidorov, L.N., Thermochemistry of Gaseous Gold Trifluoride by Knudsen Cell Mass Spectrometry, Int. J. Mass Spectrom. Ion Proc., 1986, 69, 2, 175, https://doi.org/10.1016/0168-1176(86)87031-8 . [all data]

Pervova, Korobov, et al., 1992
Pervova, Y.U.; Korobov, M.V.; Sidorov, L.N., Enthalpies of Bonds Rupture in AlClnF4-n(-) Anions, Russ. J. Phys. Chem., 1992, 66, 635. [all data]


Notes

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