Fluorine anion

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

Fluorine anion + Potassium fluoride = (Fluorine anion • Potassium fluoride)

By formula: F- + FK = (F- • FK)

Quantity Value Units Method Reference Comment
ΔrH°53.50 ± 0.80kcal/molTDAsNikitin, Sidorov, et al., 1981gas phase; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°47.9 ± 1.0kcal/molTDEqSidorov, Nikitin, et al., 1980gas phase; Fluoride Affinity:1100K, ΔHf(KF2-):298K; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°>52.6 ± 5.0kcal/molTDEqGusarov, Gorokhov, et al., 1979gas phase; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°46.4kcal/molMSNikitin, Skokan, et al., 1979gas phase; Knudsen cell; M

Fluorine anion + Benzene, pentafluoro- = (Fluorine anion • Benzene, pentafluoro-)

By formula: F- + C6HF5 = (F- • C6HF5)

Quantity Value Units Method Reference Comment
ΔrH°29.2 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B,M
Quantity Value Units Method Reference Comment
ΔrS°20.1cal/mol*KN/ADillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M
Quantity Value Units Method Reference Comment
ΔrG°20.7 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
20.7423.PHPMSDillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M

Fluorine anion + Benzonitrile, pentafluoro- = (Fluorine anion • Benzonitrile, pentafluoro-)

By formula: F- + C7F5N = (F- • C7F5N)

Quantity Value Units Method Reference Comment
ΔrH°39.3 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B,M
Quantity Value Units Method Reference Comment
ΔrS°20.1cal/mol*KN/ADillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M
Quantity Value Units Method Reference Comment
ΔrG°30.8 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
30.8423.PHPMSDillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M

Fluorine anion + Benzene, pentafluoronitro- = (Fluorine anion • Benzene, pentafluoronitro-)

By formula: F- + C6F5NO2 = (F- • C6F5NO2)

Quantity Value Units Method Reference Comment
ΔrH°41.1 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B,M
Quantity Value Units Method Reference Comment
ΔrS°19.6cal/mol*KN/ADillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M
Quantity Value Units Method Reference Comment
ΔrG°32.8 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
32.8423.PHPMSDillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M

Fluorine anion + Methyl Alcohol = (Fluorine anion • Methyl Alcohol)

By formula: F- + CH4O = (F- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°29.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrH°29.4 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
ΔrH°23.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.0cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrS°22.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°22.8 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrG°15.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

Fluorine anion + Benzene, pentafluoro(trifluoromethyl)- = (Fluorine anion • Benzene, pentafluoro(trifluoromethyl)-)

By formula: F- + C7F8 = (F- • C7F8)

Quantity Value Units Method Reference Comment
ΔrH°33.6 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B,M
Quantity Value Units Method Reference Comment
ΔrS°20.1cal/mol*KN/ADillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(C6F6), Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M
Quantity Value Units Method Reference Comment
ΔrG°25.1 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
25.1423.PHPMSDillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(C6F6), Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M

Fluorine anion + F3Fe = (Fluorine anion • F3Fe)

By formula: F- + F3Fe = (F- • F3Fe)

Quantity Value Units Method Reference Comment
ΔrH°108.3 ± 3.6kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°104.9 ± 3.4kcal/molTDEqSorokin, Sidorov, et al., 1981gas phase; Fluoride Affinity: 14.9 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°109.0 ± 3.3kcal/molTDEqChilingarov, Korobov, et al., 1984gas phase; Fluoride Affinity: 8.8 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion • 4Water) + Water = (Fluorine anion • 5Water)

By formula: (F- • 4H2O) + H2O = (F- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°12.30 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°13.2 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°30.7cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°4.5 ± 1.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°7.10kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
ΔrG°4.6 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Fluorine anion + Acetonitrile = (Fluorine anion • Acetonitrile)

By formula: F- + C2H3N = (F- • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°24.5 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Discrepancy with Yamdagni and Kebarle, 1972 "not resolved; B,M
ΔrH°16.0 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.9cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°13.4cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrG°17.6 ± 3.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Discrepancy with Yamdagni and Kebarle, 1972 "not resolved; B
ΔrG°12.0 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Fluorine anion • 3Water) + Water = (Fluorine anion • 4Water)

By formula: (F- • 3H2O) + H2O = (F- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°13.90 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°13.5 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°26.9cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.9 ± 1.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°5.50kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
ΔrG°6.1 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Fluorine anion + F2Mn = (Fluorine anion • F2Mn)

By formula: F- + F2Mn = (F- • F2Mn)

Quantity Value Units Method Reference Comment
ΔrH°83.9 ± 3.8kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°93.4 ± 2.0kcal/molTDEqSidorov and Gubarevich, 1982gas phase; Fluoride Affinity: 23.2±0.8 kcal/mol < AlF3; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°102.70kcal/molTDEqSidorov, Sorokin, et al., 1981gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Ethanol = (Fluorine anion • Ethanol)

By formula: F- + C2H6O = (F- • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°32.40 ± 0.70kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°31.5 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrH°32.5 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°24.9cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°24.74kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°24.1 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Isopropyl Alcohol = (Fluorine anion • Isopropyl Alcohol)

By formula: F- + C3H8O = (F- • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°33.50 ± 0.70kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°32.3 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrH°33.2 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°25.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°25.69kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°24.7 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + 2-Propanol, 2-methyl- = (Fluorine anion • 2-Propanol, 2-methyl-)

By formula: F- + C4H10O = (F- • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°33.40 ± 0.70kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°33.3 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrH°32.7 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°26.1cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°26.01kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°25.5 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Benzene, pentafluoromethoxy- = (Fluorine anion • Benzene, pentafluoromethoxy-)

By formula: F- + C7H3F5O = (F- • C7H3F5O)

Quantity Value Units Method Reference Comment
ΔrH°37.5kcal/molPHPMSDillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M
Quantity Value Units Method Reference Comment
ΔrS°20.1cal/mol*KN/ADillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
29.0423.PHPMSDillow and Kebarle, 1988gas phase; switching reaction,Thermochemical ladder(F-)C6F6, Entropy change calculated or estimated; Hiraoka, Mizuse, et al., 1987; M

(Fluorine anion • 4Acetonitrile) + Acetonitrile = (Fluorine anion • 5Acetonitrile)

By formula: (F- • 4C2H3N) + C2H3N = (F- • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°11.50 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°5.30kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°29.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°7.4cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrG°2.60 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°3.10kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Fluorine anion • 2Acetonitrile) + Acetonitrile = (Fluorine anion • 3Acetonitrile)

By formula: (F- • 2C2H3N) + C2H3N = (F- • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°15.1 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°11.70kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.4cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°17.9cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrG°8.4 ± 2.5kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°6.40kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Fluorine anion • Acetonitrile) + Acetonitrile = (Fluorine anion • 2Acetonitrile)

By formula: (F- • C2H3N) + C2H3N = (F- • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°17.7 ± 1.5kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°12.90kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.9cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°14.8cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrG°10.8 ± 3.4kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°8.50kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

Fluorine anion + Toluene, α-fluoro-, = (Fluorine anion • Toluene, α-fluoro-,)

By formula: F- + C7H7F = (F- • C7H7F)

Quantity Value Units Method Reference Comment
ΔrH°24.4kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrS°26.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°16.5kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M

Fluorine anion + Propane, 2-fluoro-2-methyl- = (Fluorine anion • Propane, 2-fluoro-2-methyl-)

By formula: F- + C4H9F = (F- • C4H9F)

Quantity Value Units Method Reference Comment
ΔrH°22.3kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrS°23.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°15.3kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M

Fluorine anion + 1,1,2-Trifluoroethane = (Fluorine anion • 1,1,2-Trifluoroethane)

By formula: F- + C2H3F3 = (F- • C2H3F3)

Quantity Value Units Method Reference Comment
ΔrH°26.5kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrS°25.9cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°18.8kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M

Fluorine anion + Ketene = (Fluorine anion • Ketene)

By formula: F- + C2H2O = (F- • C2H2O)

Quantity Value Units Method Reference Comment
ΔrH°35.3kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrS°26.5cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°27.4kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M

Fluorine anion + 1,3-Difluoro-2-propanol = (Fluorine anion • 1,3-Difluoro-2-propanol)

By formula: F- + C3H6F2O = (F- • C3H6F2O)

Quantity Value Units Method Reference Comment
ΔrH°37.8kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(H2O), Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrS°26.5cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(H2O), Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°29.9kcal/molICRLarson and McMahon, 1983gas phase; switching reaction(H2O), Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M

(Fluorine anion • 3Acetonitrile) + Acetonitrile = (Fluorine anion • 4Acetonitrile)

By formula: (F- • 3C2H3N) + C2H3N = (F- • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°12.80 ± 0.50kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°10.40kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°19.6cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°4.9 ± 1.9kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°4.50kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

Fluorine anion + Water = (Fluorine anion • Water)

By formula: F- + H2O = (F- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°27.40 ± 0.50kcal/molTDAsWeis, Kemper, et al., 1999gas phase; B
ΔrH°23.30kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°17.4cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°21.90 ± 0.50kcal/molTDAsWeis, Kemper, et al., 1999gas phase; B
ΔrG°18.1 ± 2.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

Fluorine anion + CrF2 = (Fluorine anion • CrF2)

By formula: F- + CrF2 = (F- • CrF2)

Quantity Value Units Method Reference Comment
ΔrH°86.3 ± 3.8kcal/molTDEqBoltalina, Borshchevskii, et al., 1991gas phase; Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°157.7 ± 7.7kcal/molTherIgolkinagas phase; The derived values do not seem reasonable - JEB.; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Difluorooxosilane = (Fluorine anion • Difluorooxosilane)

By formula: F- + F2OSi = (F- • F2OSi)

Quantity Value Units Method Reference Comment
ΔrH°123.40kcal/molTherDamrauer, Simon, et al., 1991gas phase; Between HCO2H, HCl; B
ΔrH°102. ± 17.kcal/molIMRBLarson and McMahon, 1987gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M

Fluorine anion + zirconium tetrafluoride = (Fluorine anion • zirconium tetrafluoride)

By formula: F- + F4Zr = (F- • F4Zr)

Quantity Value Units Method Reference Comment
ΔrH°99.3 ± 2.0kcal/molTDEqSkokan, Sorokin, et al., 1982gas phase; Fluoride Affinity: 22±1 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°96.3 ± 1.0kcal/molTDEqSkokan, Nikitin, et al., 1981gas phase; Fluoride Affinity: 23.12 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + titanium tetrafluoride = (Fluorine anion • titanium tetrafluoride)

By formula: F- + F4Ti = (F- • F4Ti)

Quantity Value Units Method Reference Comment
ΔrH°86.3 ± 3.8kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°86.0 ± 5.3kcal/molTDEqBoltalina, Borshchevskii, et al., 1991, 2gas phase; Fluoride Affinity: 30.3 kcal/mol < AlF3 (Data at 0 K); value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + cobalt trifluoride = (Fluorine anion • cobalt trifluoride)

By formula: F- + CoF3 = (F- • CoF3)

Quantity Value Units Method Reference Comment
ΔrH°105.7 ± 6.0kcal/molTDAsRau, Chilingarov, et al., 1997gas phase; Values are at 0K; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°105.4 ± 2.0kcal/molTDEqSidorov, Nikulin, et al., 1987gas phase; Fluoride Affinity: 11.2 kcal/mol < AlF3; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + vanadium trifluoride = (Fluorine anion • vanadium trifluoride)

By formula: F- + F3V = (F- • F3V)

Quantity Value Units Method Reference Comment
ΔrH°102.5 ± 4.3kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°100.9 ± 6.7kcal/molTDEqSidorov, Boltalina, et al., 1989gas phase; Fluoride Affinity: 16.0±2.4 kcal/mol > CrF2; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Ethene, trifluoro- = (Fluorine anion • Ethene, trifluoro-)

By formula: F- + C2HF3 = (F- • C2HF3)

Quantity Value Units Method Reference Comment
ΔrH°26.3 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrH°24.3 ± 6.0kcal/molIMRBSullivan and Beauchamp, 1976gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°25.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°18.7 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Boron trichloride = (Fluorine anion • Boron trichloride)

By formula: F- + BCl3 = (F- • BCl3)

Quantity Value Units Method Reference Comment
ΔrH°>85. ± 10.kcal/molIMRBHaartz and McDaniel, 1973gas phase; Greater than PF5 ( Larson and McMahon, 1985); B
ΔrH°>40.50kcal/molTherStockdale, Nelson, et al., 1972gas phase; Fluoride Affinity: > SF5; new value of latter from Grimsrud, Chowdhury, et al., 1985; B
Quantity Value Units Method Reference Comment
ΔrG°>74. ± 10.kcal/molIMRBHaartz and McDaniel, 1973gas phase; Greater than PF5 ( Larson and McMahon, 1985); B

(Fluorine anion • Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 2Methyl Alcohol)

By formula: (F- • CH4O) + CH4O = (F- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°20.30 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°19.3 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°23.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°12.97kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°12.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 2Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 3Methyl Alcohol)

By formula: (F- • 2CH4O) + CH4O = (F- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°15.10 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°14.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°21.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°8.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

Fluorine anion + F4Mo = (Fluorine anion • F4Mo)

By formula: F- + F4Mo = (F- • F4Mo)

Quantity Value Units Method Reference Comment
ΔrH°91.5 ± 3.3kcal/molTDEqBorshchevskii, Boltalina, et al., 1988gas phase; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°91.8 ± 4.0kcal/molTDEqBorchevsky and Sidorov, 1985gas phase; Fluoride Affinity: MoF4 > UF4 by 7.1 kcal/mol; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion • 2Carbon disulfide) + Carbon disulfide = (Fluorine anion • 3Carbon disulfide)

By formula: (F- • 2CS2) + CS2 = (F- • 3CS2)

Quantity Value Units Method Reference Comment
ΔrH°5.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
ΔrS°17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°0.3 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Fluorine anion + Carbon disulfide = (Fluorine anion • Carbon disulfide)

By formula: F- + CS2 = (F- • CS2)

Quantity Value Units Method Reference Comment
ΔrH°35.0 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
ΔrH°31.3 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°28.2cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°26.5 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
ΔrG°24.1 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B

(Fluorine anion • 9Water) + Water = (Fluorine anion • 10Water)

By formula: (F- • 9H2O) + H2O = (F- • 10H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°11.00kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
ΔrS°33.cal/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°1.10kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

Fluorine anion + Deuterium oxide = (Fluorine anion • Deuterium oxide)

By formula: F- + D2O = (F- • D2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°23.0 ± 2.0kcal/molIMRELarson and McMahon, 1988gas phase; Anchored to Arshadi, Yamdagni, et al., 1970: HOH..F- + DOD <=> DOD..F- + HOH, Keq=0.66; B
Quantity Value Units Method Reference Comment
ΔrG°17.8 ± 2.0kcal/molIMRELarson and McMahon, 1988gas phase; Anchored to Arshadi, Yamdagni, et al., 1970: HOH..F- + DOD <=> DOD..F- + HOH, Keq=0.66; B,M

Fluorine anion + Iodine monochloride = (Fluorine anion • Iodine monochloride)

By formula: F- + ClI = (F- • ClI)

Quantity Value Units Method Reference Comment
ΔrH°94.40kcal/molTherFinch, Gates, et al., 1977gas phase; This value is far more strongly bound than expected from other X3- data; B
ΔrH°43.30kcal/molN/ACheck, Faust, et al., 2001gas phase; FeH2-(q); ; ΔS(EA)=8.2; B
Quantity Value Units Method Reference Comment
ΔrG°33.00kcal/molN/ACheck, Faust, et al., 2001gas phase; FeH2-(q); ; ΔS(EA)=8.2; B

Fluorine anion + Acetonitrile, trifluoro- = (Fluorine anion • Acetonitrile, trifluoro-)

By formula: F- + C2F3N = (F- • C2F3N)

Quantity Value Units Method Reference Comment
ΔrH°29.2 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°24.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°21.9 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Fluorine anion + C4F7N = (Fluorine anion • C4F7N)

By formula: F- + C4F7N = (F- • C4F7N)

Quantity Value Units Method Reference Comment
ΔrH°30.8 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°24.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°23.6 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Fluorine anion + Carbonyl sulfide = (Fluorine anion • Carbonyl sulfide)

By formula: F- + COS = (F- • COS)

Quantity Value Units Method Reference Comment
ΔrH°31.8 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°24.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°24.6 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Fluorine anion + Silane, tetramethyl- = (Fluorine anion • Silane, tetramethyl-)

By formula: F- + C4H12Si = (F- • C4H12Si)

Quantity Value Units Method Reference Comment
ΔrH°29.9 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°21.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°23.6 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Fluorine anion + Thiothionyl fluoride = (Fluorine anion • Thiothionyl fluoride)

By formula: F- + F2S2 = (F- • F2S2)

Quantity Value Units Method Reference Comment
ΔrH°36.0 ± 3.0kcal/molIMRBLarson and McMahon, 1987gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M

Fluorine anion + F2SSi = (Fluorine anion • F2SSi)

By formula: F- + F2SSi = (F- • F2SSi)

Quantity Value Units Method Reference Comment
ΔrH°>72.00kcal/molIMRBLarson and McMahon, 1987gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M

Fluorine anion + HfF4 = (Fluorine anion • HfF4)

By formula: F- + HfF4 = (F- • HfF4)

Quantity Value Units Method Reference Comment
ΔrH°102.5 ± 4.0kcal/molTDEqNikitin, Igolkina, et al., 1986gas phase; Reanalyzed literature data, 14.1 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°96.9 ± 2.1kcal/molTDEqNikitin, Sorokin, et al., 1980gas phase; Fluoride Affinity: 20.1 kcal < AlF3; B

Fluorine anion + Pyrrole = (Fluorine anion • Pyrrole)

By formula: F- + C4H5N = (F- • C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°34.2 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.5cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°26.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Ethane, pentafluoro- = (Fluorine anion • Ethane, pentafluoro-)

By formula: F- + C2HF5 = (F- • C2HF5)

Quantity Value Units Method Reference Comment
ΔrH°30.4 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°22.5 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nikitin, Sidorov, et al., 1981
Nikitin, M.I.; Sidorov, L.N.; Skokan, E.V.; Sorokin, I.D., Mass spectrometric determination of the heats of formation of ScF4- and KF2-, Russ. J. Phys. Chem., 1981, 55, 1107. [all data]

Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D., Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]

Gusarov, Gorokhov, et al., 1979
Gusarov, A.V.; Gorokhov, L.N.; Pyatenko, A.T.; Sidorova, I.V., Negative ions in the vapors of inorganic compounds, Adv. Mass Spectrom., 1979, 8, 262. [all data]

Nikitin, Skokan, et al., 1979
Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N., Sov. Phys. Dokl., 1979, 247, 594. [all data]

Dillow and Kebarle, 1988
Dillow, G.W.; Kebarle, P., Fluoride Affinities of Perfluorobenzenes C6F5X. Meisenheimer Complexes in the Gas Phase and Solution, J. Am. Chem. Soc., 1988, 110, 15, 4877, https://doi.org/10.1021/ja00223a001 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., A Determination of the Stability and Structure of F-(C6H6) and F-(C6F6) Clusters, J. Chem. Phys., 1987, 86, 7, 4102, https://doi.org/10.1063/1.451920 . [all data]

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

DeTuri and Ervin, 1999
DeTuri, V.F.; Ervin, K.M., Competitive threshold collision-induced dissociation: Gas-phase acidities and bond dissociation energies for a series of alcohols, J. Phys. Chem. A, 1999, 103, 35, 6911-6920, https://doi.org/10.1021/jp991459m . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Sorokin, Sidorov, et al., 1981
Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V., Mass-spectrometric determination of the enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. V. Heats of formation of FeF3- and FeF4-, Int. J. Mass Spectrom. Ion Phys., 1981, 41, 45. [all data]

Chilingarov, Korobov, et al., 1984
Chilingarov, N.S.; Korobov, M.V.; Sidirov, L.N.; Mitkin, V.N.; Shipachev, V.A.; Zemskov, S.V., Electron affinity of rhodium tetrafluoride, J. Chem. Thermodyn., 1984, 16, 965. [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Yamdagni and Kebarle, 1972
Yamdagni, R.; Kebarle, P., Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules, J. Am. Chem. Soc., 1972, 94, 2940. [all data]

Sidorov and Gubarevich, 1982
Sidorov, L.N.; Gubarevich, G.D., Dissociation of the Gaseous Complex Fluorides. Alkali Metal Trifluoromanganates and Tetrafluoromanganates, Koord. Khim., 1982, 8, 12708c. [all data]

Sidorov, Sorokin, et al., 1981
Sidorov, L.N.; Sorokin, I.D.; Nitikin, N.I.; Skokan, E.V., Effusion method for determining the electron affinity and heat of formation of negative ions, Int. J. Mass Spectrom. Ion Phys., 1981, 39, 311. [all data]

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Boltalina, Borshchevskii, et al., 1991
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of Chromium Gaseous Fluorides and Their Negative Ions, Zh. Fiz. Khim. SSSR, 1991, 65, 884. [all data]

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Igolkina, N.A., Negative Ion Molecule Reaction in Chromium Trifluoride Vapor, Dep. Doc. VINITI 7085-83 Pt 1 102. [all data]

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Trends in Gas Phase Fluoride Ion Affinities of the Main Group Oxyfluorides and Fluoride Sulfides. Fluoride Adducts of FAsO, FPO, FPO2, F2SiO, F4SO, FBO, F2SiS, FPS, FAsS, F2S2, and S2O., Inorg. Chem., 1987, 26, 24, 4018, https://doi.org/10.1021/ic00271a011 . [all data]

Wenthold and Squires, 1995
Wenthold, P.G.; Squires, R.R., Bond dissociation energies of F2(-) and HF2(-). A gas-phase experimental and G2 theoretical study, J. Phys. Chem., 1995, 99, 7, 2002, https://doi.org/10.1021/j100007a034 . [all data]

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Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VI. Enthalpy of Formation of ZrF5-, Int. J. Mass Spectrom. Ion Phys., 1982, 43, 4, 209, https://doi.org/10.1016/0020-7381(82)80017-X . [all data]

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Skokan, E.V.; Nikitin, M.I.; Sorokin, I.D.; Gusarov, A.V.; Sidirov, L.N., Determination of the heat of formation of the tetrafluoroscandate and pentfluorozirconate ions by the effusion nethod, Russ. J. Phys. Chem., 1981, 55, 1062. [all data]

Boltalina, Borshchevskii, et al., 1991, 2
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.; Chepurnykh, V.N., Enthalpy of the Formation of TiF5- Anion in a Gas Phase, Zh. Fiz. Khim. SSSR, 1991, 65, 928. [all data]

Rau, Chilingarov, et al., 1997
Rau, J.V.; Chilingarov, N.S.; Sidorov, L.N., Mass spectrometric determination of cobalt trifluoride saturated vapor pressure. Enthalpy of formation of gaseous CoF4, and CoF4-, Rapid Commun. Mass Spectrom., 1997, 11, 18, 1977-1979, https://doi.org/10.1002/(SICI)1097-0231(199712)11:18<1977::AID-RCM808>3.0.CO;2-J . [all data]

Sidorov, Nikulin, et al., 1987
Sidorov, L.N.; Nikulin, V.V.; Chilingarov, N.S.; Korobov, M.V., The Enthalpy of Formation of the CoF4- Ion in the Gas Phase, Russ. J. Phys. Chem., 1987, 61, 555. [all data]

Sidorov, Boltalina, et al., 1989
Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya., Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections., Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4 . [all data]

Sullivan and Beauchamp, 1976
Sullivan, S.A.; Beauchamp, J.L., Competition between proton transfer and elimination in the reactions of strong bases with fluoroethanes in the gas phase. Influence of base strength on reactivity, J. Am. Chem. Soc., 1976, 98, 1160. [all data]

Haartz and McDaniel, 1973
Haartz, J.C.; McDaniel, D.H., Fluoride ion affinity of some lewis acids, J. Am. Chem. Soc., 1973, 95, 8562. [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]

Stockdale, Nelson, et al., 1972
Stockdale, J.A.D.; Nelson, D.R.; Davis, F.J.; Compton, R.N., Studies of electron impact excitation, negative ion formation, and negative ion-molecule reactions in boron trifluoride and boron trichloride, J. Chem. Phys., 1972, 56, 3336. [all data]

Grimsrud, Chowdhury, et al., 1985
Grimsrud, E.P.; Chowdhury, S.; Kebarle, P., Electron affinity of SF6 and perfluoromethylcyclohexane. The unusual kinetics of electron transfer reactions A- + B- + A, where A = SF6 or perfluorinated cycloalkanes, J. Chem. Phys., 1985, 83, 1059. [all data]

Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N., Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions., J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8 . [all data]

Borchevsky and Sidorov, 1985
Borchevsky, A.Ya.; Sidorov, L.N., Ion-Molecule, Ion-Ion, and Molecule-Molecule Equilibria in the System Mo-U-Fe-F-O-e-, Dokl. Akad. Nauk SSSR Ser. Khim., 1985, 285, 377. [all data]

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Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N., Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems, Russ. J. Phys. Chem., 1980, 54, page]. [all data]

Notes

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