Fluorine anion

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 101 to 150

Fluorine anion + Oxirane, (fluoromethyl)- = (Fluorine anion • Oxirane, (fluoromethyl)-)

By formula: F- + C3H5FO = (F- • C3H5FO)

Quantity Value Units Method Reference Comment
ΔrH°25.5 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°23.7cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°18.4 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Propanal, 2,2-dimethyl- = (Fluorine anion • Propanal, 2,2-dimethyl-)

By formula: F- + C5H10O = (F- • C5H10O)

Quantity Value Units Method Reference Comment
ΔrH°24.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.2cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°16.8 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + 2,2,2-Trifluoroethylamine = (Fluorine anion • 2,2,2-Trifluoroethylamine)

By formula: F- + C2H4F3N = (F- • C2H4F3N)

Quantity Value Units Method Reference Comment
ΔrH°28.1 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.0cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°20.3 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Aniline = (Fluorine anion • Aniline)

By formula: F- + C6H7N = (F- • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°31.2 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.2cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°23.4 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + 1-Propanol = (Fluorine anion • 1-Propanol)

By formula: F- + C3H8O = (F- • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°32.3 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.4cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°24.7 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + 1-Butanol = (Fluorine anion • 1-Butanol)

By formula: F- + C4H10O = (F- • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°32.2 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.9cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°24.5 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

Fluorine anion + Fluoroform = (Fluorine anion • Fluoroform)

By formula: F- + CHF3 = (F- • CHF3)

Quantity Value Units Method Reference Comment
ΔrH°27.1 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.2cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°19.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M

(Fluorine anion • 11Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 12Methyl Alcohol)

By formula: (F- • 11CH4O) + CH4O = (F- • 12CH4O)

Quantity Value Units Method Reference Comment
ΔrH°8.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°1.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Fluorine anion • 6Acetonitrile) + Acetonitrile = (Fluorine anion • 7Acetonitrile)

By formula: (F- • 6C2H3N) + C2H3N = (F- • 7C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°8.50kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
ΔrS°28.cal/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°0.10kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Fluorine anion • 7Water) + Water = (Fluorine anion • 8Water)

By formula: (F- • 7H2O) + H2O = (F- • 8H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°11.20 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°31.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; 0.4; M
Quantity Value Units Method Reference Comment
ΔrG°1.8 ± 1.6kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Fluorine anion + Xenon = (Fluorine anion • Xenon)

By formula: F- + Xe = (F- • Xe)

Quantity Value Units Method Reference Comment
ΔrH°6.30 ± 0.30kcal/molTDAsWada, Kikkawa, et al., 2007gas phase; B
ΔrH°6.50 ± 0.90kcal/molMoblDe Vreugd, Wijnaendts van Resandt, et al., 1979gas phase; B
ΔrH°6.5kcal/molSCATTERINGDe Vrengd, Wijnaendts van Resandt, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.53 ± 0.30kcal/molTDAsWada, Kikkawa, et al., 2007gas phase; B

(Fluorine anion • 5Water) + Water = (Fluorine anion • 6Water)

By formula: (F- • 5H2O) + H2O = (F- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°10.90 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°24.8cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3.5 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion • 6Water) + Water = (Fluorine anion • 7Water)

By formula: (F- • 6H2O) + H2O = (F- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°10.40 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°2.6 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion • 8Water) + Water = (Fluorine anion • 9Water)

By formula: (F- • 8H2O) + H2O = (F- • 9H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°11.10 ± 0.50kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°32.8cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.3 ± 2.1kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Fluorine anion + vanadium tetrafluoride = (Fluorine anion • vanadium tetrafluoride)

By formula: F- + vanadium tetrafluoride = (F- • vanadium tetrafluoride)

Quantity Value Units Method Reference Comment
ΔrH°87.2 ± 5.8kcal/molTDEqKuznetsov, Korobov, et al., 1989gas phase; Fluoride Affinity: 14.2±3.9 kcal/mol < UF4; B
ΔrH°86.8 ± 6.5kcal/molTDEqSidorov, Boltalina, et al., 1989gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion • Sulfur hexafluoride) + Sulfur hexafluoride = (Fluorine anion • 2Sulfur hexafluoride)

By formula: (F- • F6S) + F6S = (F- • 2F6S)

Quantity Value Units Method Reference Comment
ΔrH°4.00 ± 0.30kcal/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K; B
Quantity Value Units Method Reference Comment
ΔrG°-1.40 ± 0.30kcal/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K; B

Fluorine anion + Methyl Alcohol = CH3D4FO-

By formula: F- + CH4O = CH3D4FO-

Quantity Value Units Method Reference Comment
ΔrH°29.8 ± 2.0kcal/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B
Quantity Value Units Method Reference Comment
ΔrG°22.4 ± 2.0kcal/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B

Fluorine anion + Uranium hexafluoride = (Fluorine anion • Uranium hexafluoride)

By formula: F- + F6U = (F- • F6U)

Quantity Value Units Method Reference Comment
ΔrH°56.6 ± 7.2kcal/molTherPyatenko, Guasarov, et al., 1984gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention; B
ΔrH°46. ± 10.kcal/molIMRBBeauchamp, 1976gas phase; B

Fluorine anion + 2',3',4',5',6'-Pentafluoroacetophenone = (Fluorine anion • 2',3',4',5',6'-Pentafluoroacetophenone)

By formula: F- + C8H3F5O = (F- • C8H3F5O)

Quantity Value Units Method Reference Comment
ΔrH°37.5 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B
Quantity Value Units Method Reference Comment
ΔrG°29.0 ± 2.0kcal/molIMREDillow and Kebarle, 1988gas phase; Anchored to C6F6..F- in Hiraoka, Mizuse, et al., 1987; B

(Fluorine anion • 3Carbon dioxide) + Carbon dioxide = (Fluorine anion • 4Carbon dioxide)

By formula: (F- • 3CO2) + CO2 = (F- • 4CO2)

Quantity Value Units Method Reference Comment
ΔrH°5.8 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°20.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-0.2 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion • 4Carbon dioxide) + Carbon dioxide = (Fluorine anion • 5Carbon dioxide)

By formula: (F- • 4CO2) + CO2 = (F- • 5CO2)

Quantity Value Units Method Reference Comment
ΔrH°5.6 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-1.0 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion • 5Carbon dioxide) + Carbon dioxide = (Fluorine anion • 6Carbon dioxide)

By formula: (F- • 5CO2) + CO2 = (F- • 6CO2)

Quantity Value Units Method Reference Comment
ΔrH°5.3 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.5cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-1.4 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion • 5Acetonitrile) + Acetonitrile = (Fluorine anion • 6Acetonitrile)

By formula: (F- • 5C2H3N) + C2H3N = (F- • 6C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°9.70 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°27.8cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.40 ± 0.90kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Fluorine anion + tetrafluorogermane = (Fluorine anion • tetrafluorogermane)

By formula: F- + F4Ge = (F- • F4Ge)

Quantity Value Units Method Reference Comment
ΔrH°100.0 ± 7.0kcal/molTherMallouk, Rosenthal, et al., 1984gas phase; Fluoride affinities from this method appear to be consistently about 10 kcal/mol too bound; B
ΔrH°>96.70kcal/molIMRBHarland, Cradock, et al., 1972gas phase; B

(Fluorine anion • 2Carbon dioxide) + Carbon dioxide = (Fluorine anion • 3Carbon dioxide)

By formula: (F- • 2CO2) + CO2 = (F- • 3CO2)

Quantity Value Units Method Reference Comment
ΔrH°7.2 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°0.5 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion • Carbon dioxide) + Carbon dioxide = (Fluorine anion • 2Carbon dioxide)

By formula: (F- • CO2) + CO2 = (F- • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°7.3 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°18.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.9 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Fluorine anion • 10Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 11Methyl Alcohol)

By formula: (F- • 10CH4O) + CH4O = (F- • 11CH4O)

Quantity Value Units Method Reference Comment
ΔrH°8.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.5cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.0 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 3Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 4Methyl Alcohol)

By formula: (F- • 3CH4O) + CH4O = (F- • 4CH4O)

Quantity Value Units Method Reference Comment
ΔrH°12.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°23.5cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.5 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 4Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 5Methyl Alcohol)

By formula: (F- • 4CH4O) + CH4O = (F- • 5CH4O)

Quantity Value Units Method Reference Comment
ΔrH°11.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°27.3cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 5Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 6Methyl Alcohol)

By formula: (F- • 5CH4O) + CH4O = (F- • 6CH4O)

Quantity Value Units Method Reference Comment
ΔrH°11.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°29.8cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°2.6 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 9Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 10Methyl Alcohol)

By formula: (F- • 9CH4O) + CH4O = (F- • 10CH4O)

Quantity Value Units Method Reference Comment
ΔrH°8.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • Carbon disulfide) + Carbon disulfide = (Fluorine anion • 2Carbon disulfide)

By formula: (F- • CS2) + CS2 = (F- • 2CS2)

Quantity Value Units Method Reference Comment
ΔrH°6.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°15.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°2.1 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Fluorine anion • 6Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 7Methyl Alcohol)

By formula: (F- • 6CH4O) + CH4O = (F- • 7CH4O)

Quantity Value Units Method Reference Comment
ΔrH°9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.5cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°2.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 7Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 8Methyl Alcohol)

By formula: (F- • 7CH4O) + CH4O = (F- • 8CH4O)

Quantity Value Units Method Reference Comment
ΔrH°9.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.8cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 8Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 9Methyl Alcohol)

By formula: (F- • 8CH4O) + CH4O = (F- • 9CH4O)

Quantity Value Units Method Reference Comment
ΔrH°9.2 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.7cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°1.5 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

Fluorine anion + F3Y = (Fluorine anion • F3Y)

By formula: F- + F3Y = (F- • F3Y)

Quantity Value Units Method Reference Comment
ΔrH°114.0 ± 5.0kcal/molTDEqPyatenko, Gusarov, et al., 1981gas phase; F-A at 0 K; ΔHf at 298 K. Equilibrium measured vs. AlF4-; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Benzene, hexafluoro- = (Fluorine anion • Benzene, hexafluoro-)

By formula: F- + C6F6 = (F- • C6F6)

Quantity Value Units Method Reference Comment
ΔrH°27.5 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°23.7cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 3gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°20.4 ± 1.6kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Fluorine anion + F4Th = (Fluorine anion • F4Th)

By formula: F- + F4Th = (F- • F4Th)

Quantity Value Units Method Reference Comment
ΔrH°104.2 ± 3.5kcal/molTherSidirov, Zhuravlena, et al., 1983gas phase; Fluoride Affinity: 21.1 kcal < AlF3, 3.6 kcal < ZrF4; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion • F6S-) + F6S- = (Fluorine anion • 2F6S-)

By formula: (F- • F6S-) + F6S- = (F- • 2F6S-)

Quantity Value Units Method Reference Comment
ΔrH°4.0kcal/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°18.cal/mol*KN/AHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M

(Fluorine anion • 6Nitrous oxide) + Nitrous oxide = (Fluorine anion • 7Nitrous oxide)

By formula: (F- • 6N2O) + N2O = (F- • 7N2O)

Quantity Value Units Method Reference Comment
ΔrH°3.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°20.cal/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Fluorine anion • 6Carbon dioxide) + Carbon dioxide = (Fluorine anion • 7Carbon dioxide)

By formula: (F- • 6CO2) + CO2 = (F- • 7CO2)

Quantity Value Units Method Reference Comment
ΔrH°3.9kcal/molPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°18.cal/mol*KN/AHiraoka, Mizuse, et al., 1987, 2gas phase; Entropy change calculated or estimated; M

Fluorine anion + Benzene = (Fluorine anion • Benzene)

By formula: F- + C6H6 = (F- • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°15.30kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°19.5cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°9.40kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Fluorine anion + F4MoO = (Fluorine anion • F4MoO)

By formula: F- + F4MoO = (F- • F4MoO)

Quantity Value Units Method Reference Comment
ΔrH°96.20kcal/molTDEqBorchevsky and Sidorov, 1985gas phase; Fluoride Affinity: MoOF3 < MoF5 by 4.0±2.0 kcal/mol; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Be2F4 = (Fluorine anion • Be2F4)

By formula: F- + Be2F4 = (F- • Be2F4)

Quantity Value Units Method Reference Comment
ΔrH°111.0 ± 2.0kcal/molTDEqNikitin, Sorokin, et al., 1980gas phase; Fluoride Affinity of Be2F4: 6.3±2 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B

(Fluorine anion • 4Tetrafluoromethane) + Tetrafluoromethane = (Fluorine anion • 5Tetrafluoromethane)

By formula: (F- • 4CF4) + CF4 = (F- • 5CF4)

Quantity Value Units Method Reference Comment
ΔrH°2.4kcal/molPHPMSHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°19.cal/mol*KN/AHiraoka, Nasu, et al., 1995gas phase; Entropy change calculated or estimated; M

Fluorine anion + CrF4 = (Fluorine anion • CrF4)

By formula: F- + CrF4 = (F- • CrF4)

Quantity Value Units Method Reference Comment
ΔrH°98.2 ± 9.6kcal/molTDEqBoltalina, Borshchevskii, et al., 1991gas phase; Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + AuF3 = (Fluorine anion • AuF3)

By formula: F- + AuF3 = (F- • AuF3)

Quantity Value Units Method Reference Comment
ΔrH°101.8 ± 6.0kcal/molTDEqChilingarov, Korobov, et al., 1986gas phase; Fluoride Affinity: 1.2±5.0 kcal/mol > MnF3; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + CrF3 = (Fluorine anion • CrF3)

By formula: F- + CrF3 = (F- • CrF3)

Quantity Value Units Method Reference Comment
ΔrH°92.5 ± 3.5kcal/molTDEqBoltalina, Borshchevskii, et al., 1991gas phase; Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Aluminum chloride fluoride = (Fluorine anion • Aluminum chloride fluoride)

By formula: F- + AlCl2F = (F- • AlCl2F)

Quantity Value Units Method Reference Comment
ΔrH°119.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

Fluorine anion + Aluminum chloride fluoride = (Fluorine anion • Aluminum chloride fluoride)

By formula: F- + AlClF2 = (F- • AlClF2)

Quantity Value Units Method Reference Comment
ΔrH°117.4 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

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Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Hiraoka, Mizuse, et al., 1988
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De Vreugd, C.; Wijnaendts van Resandt, R.W.; Los, J., The Well Depths of XeF- and XeCl- from Differential Scattering Measurements, Chem. Phys. Lett., 1979, 65, 1, 93, https://doi.org/10.1016/0009-2614(79)80134-7 . [all data]

De Vrengd, Wijnaendts van Resandt, et al., 1979
De Vrengd, C.; Wijnaendts van Resandt, R.W.; Los, J., The well depths of XeF- and XeCl- from differential scattering measurements, Chem. Phys. Lett., 1979, 65, 93. [all data]

Kuznetsov, Korobov, et al., 1989
Kuznetsov, S.V.; Korobov, M.V.; Sidorov, L.N., Gas-Phase Negative Ion Chemistry of Platinum Metal Fluorides. III. Negative Ions of Pentafluorides., Int. J. Mass Spectrom. Ion Proc., 1989, 91, 3, 283, https://doi.org/10.1016/0168-1176(89)80083-7 . [all data]

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Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya., Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections., Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4 . [all data]

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Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M.; Fujimaki, S.; Yamabe, S., The small binding energies of the negative cluster ions: SF5-(SF6)1, SF6-(SF6)1 and F-(SF6)n (n=1 and 2), in the gas phase, Chem. Phys. Lett., 1995, 241, 5-6, 623, https://doi.org/10.1016/0009-2614(95)00676-U . [all data]

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Wilkinson, F.E.; Szulejko, J.E.; Allison, C.E.; Mcmahon, T.B., Fourier Transform Ion Cyclotron Resonance Investigation of the Deuterium Isotope Effect on Gas Phase Ion/Molecule Hydrogen Bonding Interactions in Alcohol-Fluoride Adduct Ions, Int. J. Mass Spectrom., 1992, 117, 487-505, https://doi.org/10.1016/0168-1176(92)80110-M . [all data]

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Beauchamp, 1976
Beauchamp, J.L., Ion cyclotron resonance studies of endothermic reactions of UF6-Generated by surface ionization, J. Chem. Phys., 1976, 64, 929. [all data]

Dillow and Kebarle, 1988
Dillow, G.W.; Kebarle, P., Fluoride Affinities of Perfluorobenzenes C6F5X. Meisenheimer Complexes in the Gas Phase and Solution, J. Am. Chem. Soc., 1988, 110, 15, 4877, https://doi.org/10.1021/ja00223a001 . [all data]

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Hiraoka, K.; Mizuse, S.; Yamabe, S., A Determination of the Stability and Structure of F-(C6H6) and F-(C6F6) Clusters, J. Chem. Phys., 1987, 86, 7, 4102, https://doi.org/10.1063/1.451920 . [all data]

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Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

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Mallouk, T.E.; Rosenthal, G.L.; Muller, G.; Brusasco, R.; Bartlett, N., Fluoride ion affinities of GeF4 and BF4 from thermodynamic and structural data for (SF2)2GeF6, ClO2GeF5, and ClO2BF4, Inorg. Chem., 1984, 23, 3167. [all data]

Harland, Cradock, et al., 1972
Harland, P.W.; Cradock, S.; Thynne, J.C.J., Positive- and negative-ion formation due to the electron bombardment of germanium tetrafluoride, Int. J. Mass Spectrom. Ion Phys., 1972, 10, 169. [all data]

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Pyatenko, A.T.; Gusarov, A.V.; Gorokhov, L.N., Negative Ions in Vapor over Yttrium Trifluoride, High Temp., 1981, 19, 1167. [all data]

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Sidirov, Zhuravlena, et al., 1983
Sidirov, L.N.; Zhuravlena, L.V.; Varkov, M.V.; Skokan, E.V.; Sorokin, I.D.; Koronev, Yu.M.; Akishima, P.A., Mass- spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. VII. MF-ThF4 systems, Int. J. Mass Spectrom. Ion Processes, 1983, 51, 291. [all data]

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Borchevsky, A.Ya.; Sidorov, L.N., Ion-Molecule, Ion-Ion, and Molecule-Molecule Equilibria in the System Mo-U-Fe-F-O-e-, Dokl. Akad. Nauk SSSR Ser. Khim., 1985, 285, 377. [all data]

Nikitin, Sorokin, et al., 1980
Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N., Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems, Russ. J. Phys. Chem., 1980, 54, page]. [all data]

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Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Weak Ion-Molecule Complexes of F-(CF4)n and CF3-(CF4)n, Chem Phys. Let., 1995, 245, 1, 14, https://doi.org/10.1016/0009-2614(95)00980-I . [all data]

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Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of Chromium Gaseous Fluorides and Their Negative Ions, Zh. Fiz. Khim. SSSR, 1991, 65, 884. [all data]

Pramann and Rademann, 1999
Pramann, A.; Rademann, K., Mass-spectrometric study of formation and stability of manganese and manganese oxide cluster anions, Int. J. Mass Spectrom., 1999, 187, 673-683, https://doi.org/10.1016/S1387-3806(98)14197-0 . [all data]

Chilingarov, Korobov, et al., 1986
Chilingarov, N.S.; Korobov, M.V.; Rudometkin, S.V.; Alikhayan, A.S.; Sidorov, L.N., Thermochemistry of Gaseous Gold Trifluoride by Knudsen Cell Mass Spectrometry, Int. J. Mass Spectrom. Ion Proc., 1986, 69, 2, 175, https://doi.org/10.1016/0168-1176(86)87031-8 . [all data]

Pervova, Korobov, et al., 1992
Pervova, Y.U.; Korobov, M.V.; Sidorov, L.N., Enthalpies of Bonds Rupture in AlClnF4-n(-) Anions, Russ. J. Phys. Chem., 1992, 66, 635. [all data]

Notes

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