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Reaction data

Fluorine anion + Aluminum fluoride = (Fluorine anion bullet Aluminum fluoride)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

DeltarH° (kJ/mol) Method Reference Comment
487.9 ± 7.9TDAsNikitin, Igolkina, et al., 1986gas phase; Summary of literature data plus new work. Recommended average value at 0K.; value altered from reference due to conversion from electron convention to ion convention; B
497.9 ± 6.7TDAsSidorov, Nikitin, et al., 1980gas phase; Fluoride Affinity:1100K «DELTA»Hf(AlF4-):298K; value altered from reference due to conversion from electron convention to ion convention; B
500.0 ± 8.4TDEqNikitin, Sidorov, et al., 1981gas phase; Fluoride Affinity: 4.1 kcal > ScF3; value altered from reference due to conversion from electron convention to ion convention; B
496. ± 13.TDEqGusarov, Pyatenko, et al., 1980gas phase; KF2- + KAlF4 <=> AlF4- + 2KF; value altered from reference due to conversion from electron convention to ion convention; B
495. ± 11.TDEqNikitin, Skokan, et al., 1979gas phase; Fluoride Affinity: 22.2±.2 kcal > UF4; value altered from reference due to conversion from electron convention to ion convention; B,M
477.MSPyatenko, Gusarov, et al., 1981gas phase; Knudsen cell; M
628. ± 42.TherSrivastava, Uy, et al., 1974gas phase; 2 AlF2 + AlF2- <=> 2AlF + AlF4-; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nikitin, Igolkina, et al., 1986
Nikitin, M.I.; Igolkina, N.A.; Skokan, E.V.; Sorokin, I.D.; Sidirov, L.N., Enthalpies of formation of the AlF4- ion, J. Phys. Chem., 1986, 60, 22. [all data]

Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D., Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]

Nikitin, Sidorov, et al., 1981
Nikitin, M.I.; Sidorov, L.N.; Skokan, E.V.; Sorokin, I.D., Mass spectrometric determination of the heats of formation of ScF4- and KF2-, Russ. J. Phys. Chem., 1981, 55, 1107. [all data]

Gusarov, Pyatenko, et al., 1980
Gusarov, A.V.; Pyatenko, A.T.; Gorokhov, L.N., Tetrafluoroaluminate (AlF4-) and Fluoroaluminate (Al2F7-) Ions in Aluminum Fluoride Vapors, Teplofiz. Vys. Temperatiur., 1980, 18, 10584y. [all data]

Nikitin, Skokan, et al., 1979
Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N., Negative Ions in Saturated Vapor of the System MF-AlF3. Heat of Formation of AlF4-, Dokl. Akad. Nauk SSSR Ser. Khim., 1979, 247, 151. [all data]

Pyatenko, Gusarov, et al., 1981
Pyatenko, A.T.; Gusarov, A.V.; Gorokhov, L.N., Negative Ions in the Vapor Over Lanthanum Trifluoride, High Temp., 1981, 19, 241. [all data]

Srivastava, Uy, et al., 1974
Srivastava, R.D.; Uy, O.M.; Farber, M., Experimental determination of heats of formation of negative ions and electron affinities of several boron and aluminum fluorides, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1033. [all data]


Notes

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