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Reaction data

Fluorine anion + F4U = (Fluorine anion bullet F4U)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

DeltarH° (kJ/mol) Method Reference Comment
422. ± 15.TDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention; B
412. ± 16.TDEqBorshchevskii, Boltalina, et al., 1988gas phase; value altered from reference due to conversion from electron convention to ion convention; B
427. ± 15.TDEqNikitin, Igolkina, et al., 1986gas phase; Reanalyzed literature data, 14.5 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B
424.26TherPyatenko, Guasarov, et al., 1984gas phase; Critical review, other literature data corrected; value altered from reference due to conversion from electron convention to ion convention; B
448. ± 36.TherPyatenko, Gusarov, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention; B
410.0 ± 1.3TDEqSidorov, Skokan, et al., 1980gas phase; Fluoride Affinity: 22.2 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N., Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions., J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8 . [all data]

Nikitin, Igolkina, et al., 1986
Nikitin, M.I.; Igolkina, N.A.; Skokan, E.V.; Sorokin, I.D.; Sidirov, L.N., Enthalpies of formation of the AlF4- ion, J. Phys. Chem., 1986, 60, 22. [all data]

Pyatenko, Guasarov, et al., 1984
Pyatenko, A.T.; Guasarov, A.V.; Gorokhov, L.N., Thermochemistry of Negative Ions in the U-F System, Russ. J. Phys. Chem., 1984, 58, 1. [all data]

Pyatenko, Gusarov, et al., 1980
Pyatenko, A.T.; Gusarov, A.V.; Gorokhov, L.N., Thermochemical Properties of Negative Ions in Vapor over UF4, High Temp., 1980, 18, 857. [all data]

Sidorov, Skokan, et al., 1980
Sidorov, L.N.; Skokan, E.V.; Nitikin, M.I.; Sorokin, I.D., Mass spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. III. Heat of formation of UF5- and electron affinity of UF5, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 215. [all data]


Notes

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