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Chlorine anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion = C4HClF9-

By formula: Cl- = C4HClF9-

Quantity Value Units Method Reference Comment
Deltar64.9 ± 1.3kJ/molIMREGuerrero, Herrero, et al., 2009gas phase; B

Chlorine anion = C5H10Cl-

By formula: Cl- = C5H10Cl-

Quantity Value Units Method Reference Comment
Deltar35.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.9kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C5H12Cl-

By formula: Cl- = C5H12Cl-

Quantity Value Units Method Reference Comment
Deltar37.5kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.9kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C6H12Cl-

By formula: Cl- = C6H12Cl-

Quantity Value Units Method Reference Comment
Deltar40.0kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar12.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C6H14Cl-

By formula: Cl- = C6H14Cl-

Quantity Value Units Method Reference Comment
Deltar42.59kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.4kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H14Cl-

By formula: Cl- = C7H14Cl-

Quantity Value Units Method Reference Comment
Deltar44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar14.8kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H16Cl-

By formula: Cl- = C7H16Cl-

Quantity Value Units Method Reference Comment
Deltar44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.1kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Deltar84.1 ± 6.7kJ/molCIDTHammad and Wenthold, 2000gas phase; B

Chlorine anion = C8H16Cl-

By formula: Cl- = C8H16Cl-

Quantity Value Units Method Reference Comment
Deltar44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H18Cl-

By formula: Cl- = C8H18Cl-

Quantity Value Units Method Reference Comment
Deltar49.12kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.7kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = ClN2O-

By formula: Cl- = ClN2O-

Quantity Value Units Method Reference Comment
Deltar18.8 ± 0.42kJ/molN/ABoesl, Distelrath, et al., 2008gas phase; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion bullet Aluminum chloride fluoride)

By formula: Cl- + AlClF2 = (Cl- bullet AlClF2)

Quantity Value Units Method Reference Comment
Deltar311. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100K. See also AlCl2F..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion bullet Aluminum chloride fluoride)

By formula: Cl- + AlCl2F = (Cl- bullet AlCl2F)

Quantity Value Units Method Reference Comment
Deltar315. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiemnts at 800-1100K. See also AlCl3..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + AlCl3 = (Chlorine anion bullet AlCl3)

By formula: Cl- + AlCl3 = (Cl- bullet AlCl3)

Quantity Value Units Method Reference Comment
Deltar321. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Aluminum fluoride = (Chlorine anion bullet Aluminum fluoride)

By formula: Cl- + AlF3 = (Cl- bullet AlF3)

Quantity Value Units Method Reference Comment
Deltar311. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiment at 800-1100 K. See also AlClF2..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Deltar115. ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + trifluoroarsine = (Chlorine anion bullet trifluoroarsine)

By formula: Cl- + AsF3 = (Cl- bullet AsF3)

Quantity Value Units Method Reference Comment
Deltar108. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar77.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Boron trichloride = (Chlorine anion bullet Boron trichloride)

By formula: Cl- + BCl3 = (Cl- bullet BCl3)

Quantity Value Units Method Reference Comment
Deltar289. ± 8.4kJ/molTherKrivtsov, Titova, et al., 1977gas phase; Halide affinities from this reference are too high. G3MP2B3 calculations indicate an dHaff ca. 46 kcal/mol; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Boron trifluoride = (Chlorine anion bullet Boron trifluoride)

By formula: Cl- + BF3 = (Cl- bullet BF3)

Quantity Value Units Method Reference Comment
Deltar109. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar80.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Deltar153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Bromotrifluoromethane = CBrClF3-

By formula: Cl- + CBrF3 = CBrClF3-

Quantity Value Units Method Reference Comment
Deltar69.04 ± 0.84kJ/molTDAsBogdanov and McMahon, 2006gas phase; B
Quantity Value Units Method Reference Comment
Deltar38.5kJ/molTDAsBogdanov and McMahon, 2006gas phase; B

Chlorine anion + Phosgene = (Chlorine anion bullet Phosgene)

By formula: Cl- + CCl2O = (Cl- bullet CCl2O)

Quantity Value Units Method Reference Comment
Deltar52.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar27. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Carbon Tetrachloride = (Chlorine anion bullet Carbon Tetrachloride)

By formula: Cl- + CCl4 = (Cl- bullet CCl4)

Quantity Value Units Method Reference Comment
Deltar56.1 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar59.4 ± 2.9kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.1kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar24.7 ± 3.8kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Carbonic difluoride = (Chlorine anion bullet Carbonic difluoride)

By formula: Cl- + CF2O = (Cl- bullet CF2O)

Quantity Value Units Method Reference Comment
Deltar52.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar28. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Methane, trifluoroiodo- = CClF3I-

By formula: Cl- + CF3I = CClF3I-

Quantity Value Units Method Reference Comment
Deltar98.74 ± 0.84kJ/molTDAsBogdanov and McMahon, 2006gas phase; B

Chlorine anion + Difluorochloromethane = (Chlorine anion bullet Difluorochloromethane)

By formula: Cl- + CHClF2 = (Cl- bullet CHClF2)

Quantity Value Units Method Reference Comment
Deltar72.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar43.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Fluorodichloromethane = (Chlorine anion bullet Fluorodichloromethane)

By formula: Cl- + CHCl2F = (Cl- bullet CHCl2F)

Quantity Value Units Method Reference Comment
Deltar73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Trichloromethane = (Chlorine anion bullet Trichloromethane)

By formula: Cl- + CHCl3 = (Cl- bullet CHCl3)

Quantity Value Units Method Reference Comment
Deltar63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Deltar81.6 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar75.73kJ/molMoblGiles and Grimsrud, 1993gas phase; B
Deltar75.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar79.9 ± 2.9kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KN/ALarson and McMahon, 1984gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Deltar103.J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Deltar61.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar47. ± 5.kJ/molAVGN/AAverage of 6 values; Individual data points

Chlorine anion + Fluoroform = (Chlorine anion bullet Fluoroform)

By formula: Cl- + CHF3 = (Cl- bullet CHF3)

Quantity Value Units Method Reference Comment
Deltar70. ± 10.kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar41. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Hydrogen cyanide = (Chlorine anion bullet Hydrogen cyanide)

By formula: Cl- + CHN = (Cl- bullet CHN)

Quantity Value Units Method Reference Comment
Deltar91.2 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,B,M
Deltar87.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Deltar99.2J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar67.8 ± 6.7kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B
Deltar67.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar58.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion bullet Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 2Hydrogen cyanide)

By formula: (Cl- bullet CHN) + CHN = (Cl- bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar74.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.44kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 2Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 3Hydrogen cyanide)

By formula: (Cl- bullet 2CHN) + CHN = (Cl- bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.1kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 3Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 4Hydrogen cyanide)

By formula: (Cl- bullet 3CHN) + CHN = (Cl- bullet 4CHN)

Quantity Value Units Method Reference Comment
Deltar46.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.9J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.6kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 4Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 5Hydrogen cyanide)

By formula: (Cl- bullet 4CHN) + CHN = (Cl- bullet 5CHN)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.5kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 5Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 6Hydrogen cyanide)

By formula: (Cl- bullet 5CHN) + CHN = (Cl- bullet 6CHN)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.28kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 6Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 7Hydrogen cyanide)

By formula: (Cl- bullet 6CHN) + CHN = (Cl- bullet 7CHN)

Quantity Value Units Method Reference Comment
Deltar33. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.18kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 7Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 8Hydrogen cyanide)

By formula: (Cl- bullet 7CHN) + CHN = (Cl- bullet 8CHN)

Quantity Value Units Method Reference Comment
Deltar34. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 9.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 8Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 9Hydrogen cyanide)

By formula: (Cl- bullet 8CHN) + CHN = (Cl- bullet 9CHN)

Quantity Value Units Method Reference Comment
Deltar31. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.42kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.171.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

Chlorine anion + Methylene chloride = (Chlorine anion bullet Methylene chloride)

By formula: Cl- + CH2Cl2 = (Cl- bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar61.9 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar64.9 ± 1.3kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M
Deltar92.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar38. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar37.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar37.2 ± 2.5kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Formic acid = (Chlorine anion bullet Formic acid)

By formula: Cl- + CH2O2 = (Cl- bullet CH2O2)

Quantity Value Units Method Reference Comment
Deltar115. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Deltar116. ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; B
Deltar107. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar156. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B,M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Deltar101.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar166.J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.1 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Deltar77.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar106. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B

(Chlorine anion bullet Formic acid) + Formic acid = (Chlorine anion bullet 2Formic acid)

By formula: (Cl- bullet CH2O2) + CH2O2 = (Cl- bullet 2CH2O2)

Quantity Value Units Method Reference Comment
Deltar46.9 ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; B
Deltar143. ± 13.kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar230.J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

(Chlorine anion bullet 2Formic acid) + Formic acid = (Chlorine anion bullet 3Formic acid)

By formula: (Cl- bullet 2CH2O2) + CH2O2 = (Cl- bullet 3CH2O2)

Quantity Value Units Method Reference Comment
Deltar93. ± 11.kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar150.J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

(Chlorine anion bullet 3Formic acid) + Formic acid = (Chlorine anion bullet 4Formic acid)

By formula: (Cl- bullet 3CH2O2) + CH2O2 = (Cl- bullet 4CH2O2)

Quantity Value Units Method Reference Comment
Deltar59.0 ± 9.2kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; M

(Chlorine anion bullet 4Formic acid) + Formic acid = (Chlorine anion bullet 5Formic acid)

By formula: (Cl- bullet 4CH2O2) + CH2O2 = (Cl- bullet 5CH2O2)

Quantity Value Units Method Reference Comment
Deltar42.3 ± 8.4kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar48.1J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

Chlorine anion + Methane, bromo- = (Chlorine anion bullet Methane, bromo-)

By formula: Cl- + CH3Br = (Cl- bullet CH3Br)

Quantity Value Units Method Reference Comment
Deltar52.3 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar45.6 ± 2.1kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Deltar51. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Deltar53.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar28.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar30. ± 5.0kJ/molTDAsDougherty and Roberts, 1974gas phase; B

Chlorine anion + Chloromethane = (Chlorine anion bullet Chloromethane)

By formula: Cl- + CH3Cl = (Cl- bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar43.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar49.0 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar51.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar36.0 ± 0.84kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Deltar63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar64.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar24.3 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar20.3kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar26. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar17.2 ± 2.1kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B
Deltar45.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Chlorine anion + Methyl fluoride = (Chlorine anion bullet Methyl fluoride)

By formula: Cl- + CH3F = (Cl- bullet CH3F)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar23.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Silane, trifluoromethyl- = (Chlorine anion bullet Silane, trifluoromethyl-)

By formula: Cl- + CH3F3Si = (Cl- bullet CH3F3Si)

Quantity Value Units Method Reference Comment
Deltar67.4 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar40. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Methane, iodo- = (Chlorine anion bullet Methane, iodo-)

By formula: Cl- + CH3I = (Cl- bullet CH3I)

Quantity Value Units Method Reference Comment
Deltar41.0 ± 0.84kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.J/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar29. ± 5.4kJ/molTDAsDougherty and Roberts, 1974gas phase; B

Chlorine anion + Methane, nitro- = (Chlorine anion bullet Methane, nitro-)

By formula: Cl- + CH3NO2 = (Cl- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar65.3 ± 2.5kJ/molTDAsWincel, 2003gas phase; B
Deltar69.87 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Deltar68. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Deltar71.5J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar38.5kJ/molTDAsWincel, 2003gas phase; B
Deltar48.53 ± 0.42kJ/molTDAsSieck, 1985gas phase; B

(Chlorine anion bullet Methane, nitro-) + Methane, nitro- = (Chlorine anion bullet 2Methane, nitro-)

By formula: (Cl- bullet CH3NO2) + CH3NO2 = (Cl- bullet 2CH3NO2)

Quantity Value Units Method Reference Comment
Deltar54.4 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Deltar54.81 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar76.6J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.8kJ/molTDAsWincel, 2003gas phase; B
Deltar31.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B

Chlorine anion + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar69. ± 10.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar92.0J/mol*KPHPMSSieck, 1985gas phase; M
Deltar95.8J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar61.9J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar42. ± 3.kJ/molAVGN/AAverage of 10 values; Individual data points

(Chlorine anion bullet Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol)

By formula: (Cl- bullet CH4O) + CH4O = (Cl- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar59.0 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar57.32 ± 0.84kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar59.0 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar54.4 ± 2.9kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar92.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar81.2J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar29.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Deltar28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar30.1 ± 1.7kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 3Methyl Alcohol)

By formula: (Cl- bullet 2CH4O) + CH4O = (Cl- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar48.12 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar45.2 ± 1.3kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar49.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar51.5 ± 2.5kJ/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar95.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar98.7J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar16.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Deltar21. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar21.8 ± 1.3kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 4Methyl Alcohol)

By formula: (Cl- bullet 3CH4O) + CH4O = (Cl- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar43.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar43.93kJ/molTDAsEvans and Keesee, 1991gas phase; B
Deltar46.9 ± 2.5kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar110.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar15. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar15.5kJ/molTDAsEvans and Keesee, 1991gas phase; B
Deltar13.8 ± 0.84kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 5Methyl Alcohol)

By formula: (Cl- bullet 4CH4O) + CH4O = (Cl- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar43.9 ± 2.1kJ/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar107.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar11. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar12.1 ± 0.42kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 6Methyl Alcohol)

By formula: (Cl- bullet 5CH4O) + CH4O = (Cl- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.9J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 7Methyl Alcohol)

By formula: (Cl- bullet 6CH4O) + CH4O = (Cl- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar33. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 8Methyl Alcohol)

By formula: (Cl- bullet 7CH4O) + CH4O = (Cl- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 9Methyl Alcohol)

By formula: (Cl- bullet 8CH4O) + CH4O = (Cl- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar86.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 10Methyl Alcohol)

By formula: (Cl- bullet 9CH4O) + CH4O = (Cl- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar31. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 10Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 11Methyl Alcohol)

By formula: (Cl- bullet 10CH4O) + CH4O = (Cl- bullet 11CH4O)

Quantity Value Units Method Reference Comment
Deltar31. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar5.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion bullet Methyl Alcohol) + Water = (Chlorine anion bullet Water bullet Methyl Alcohol)

By formula: (Cl- bullet CH4O) + H2O = (Cl- bullet H2O bullet CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar45.6kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar70.7J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet 2Methyl Alcohol) + Water = (Chlorine anion bullet Water bullet 2Methyl Alcohol)

By formula: (Cl- bullet 2CH4O) + H2O = (Cl- bullet H2O bullet 2CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar32.kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet Methyl Alcohol bullet Water) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol bullet Water)

By formula: (Cl- bullet CH4O bullet H2O) + CH4O = (Cl- bullet 2CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KHPMSEvans and Keesee, 1991gas phase; M

Chlorine anion + Methanethiol = (Chlorine anion bullet Methanethiol)

By formula: Cl- + CH4S = (Cl- bullet CH4S)

Quantity Value Units Method Reference Comment
Deltar65. ± 13.kJ/molIMRBStaneke, Groothuis, et al., 1995gas phase; Chloride affinity comparable to that of CHCl3; B
Quantity Value Units Method Reference Comment
Deltar45. ± 13.kJ/molIMRBStaneke, Groothuis, et al., 1995gas phase; Chloride affinity comparable to that of CHCl3; B

Chlorine anion + Methane = CH4Cl-

By formula: Cl- + CH4 = CH4Cl-

Quantity Value Units Method Reference Comment
Deltar15.9kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar-9.04kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

Chlorine anion + Carbon dioxide = (Chlorine anion bullet Carbon dioxide)

By formula: Cl- + CO2 = (Cl- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar28.5 ± 2.1kJ/molPDisArnold, Bradforth, et al., 1995gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Deltar31.8kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B,M
Deltar33.5 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Deltar82.0J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.79kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B
Deltar8.79 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Chlorine anion bullet Carbon dioxide) + Carbon dioxide = (Chlorine anion bullet 2Carbon dioxide)

By formula: (Cl- bullet CO2) + CO2 = (Cl- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar30. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar30.1kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar-5.9 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar4.18kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B

(Chlorine anion bullet 2Carbon dioxide) + Carbon dioxide = (Chlorine anion bullet 3Carbon dioxide)

By formula: (Cl- bullet 2CO2) + CO2 = (Cl- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar28.5kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar93.7J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.4 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar0.42kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B

(Chlorine anion bullet 3Carbon dioxide) + Carbon dioxide = (Chlorine anion bullet 4Carbon dioxide)

By formula: (Cl- bullet 3CO2) + CO2 = (Cl- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar26.8kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar-3.3kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; entropy estimated.; B

Chlorine anion + Carbon disulfide = (Chlorine anion bullet Carbon disulfide)

By formula: Cl- + CS2 = (Cl- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar49.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar58.2J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Deltar84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar19. ± 9.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar24. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

(Chlorine anion bullet Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 2Carbon disulfide)

By formula: (Cl- bullet CS2) + CS2 = (Cl- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar32.2 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar66.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar13. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 3Carbon disulfide)

By formula: (Cl- bullet 2CS2) + CS2 = (Cl- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar30.1 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 3Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 4Carbon disulfide)

By formula: (Cl- bullet 3CS2) + CS2 = (Cl- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B
Quantity Value Units Method Reference Comment
Deltar-0.4 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + C2ClF3O = (Chlorine anion bullet C2ClF3O)

By formula: Cl- + C2ClF3O = (Cl- bullet C2ClF3O)

Quantity Value Units Method Reference Comment
Deltar74.5 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar46.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + C2F4O = (Chlorine anion bullet C2F4O)

By formula: Cl- + C2F4O = (Cl- bullet C2F4O)

Quantity Value Units Method Reference Comment
Deltar69.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar42.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Ethene, tetrafluoro- = C2ClF4-

By formula: Cl- + C2F4 = C2ClF4-

Quantity Value Units Method Reference Comment
Deltar>41.84kJ/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B
Quantity Value Units Method Reference Comment
Deltar10.7kJ/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B

Chlorine anion + Pentafluorodimethyl ether = (Chlorine anion bullet Pentafluorodimethyl ether)

By formula: Cl- + C2HF5O = (Cl- bullet C2HF5O)

Quantity Value Units Method Reference Comment
Deltar73.2 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar47.3 ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Deltar50.6 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + Ethane, pentafluoro- = (Chlorine anion bullet Ethane, pentafluoro-)

By formula: Cl- + C2HF5 = (Cl- bullet C2HF5)

Quantity Value Units Method Reference Comment
Deltar78.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar49.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 1,1,1',1'-Tetrafluorodimethyl ether = (Chlorine anion bullet 1,1,1',1'-Tetrafluorodimethyl ether)

By formula: Cl- + C2H2F4O = (Cl- bullet C2H2F4O)

Quantity Value Units Method Reference Comment
Deltar118.0 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar78.7 ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Deltar71.1 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + Acetic acid, chloro- = (Chlorine anion bullet Acetic acid, chloro-)

By formula: Cl- + C2H3ClO2 = (Cl- bullet C2H3ClO2)

Quantity Value Units Method Reference Comment
Deltar59.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar33. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B

Chlorine anion + C2H3ClO2 = (Chlorine anion bullet C2H3ClO2)

By formula: Cl- + C2H3ClO2 = (Cl- bullet C2H3ClO2)

Quantity Value Units Method Reference Comment
Deltar59.0kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar33.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Ethanol, 2,2,2-trifluoro- = (Chlorine anion bullet Ethanol, 2,2,2-trifluoro-)

By formula: Cl- + C2H3F3O = (Cl- bullet C2H3F3O)

Quantity Value Units Method Reference Comment
Deltar100. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar69.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 1,1,2-Trifluoroethane = (Chlorine anion bullet 1,1,2-Trifluoroethane)

By formula: Cl- + C2H3F3 = (Cl- bullet C2H3F3)

Quantity Value Units Method Reference Comment
Deltar79.1kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar47.7kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Acetonitrile = (Chlorine anion bullet Acetonitrile)

By formula: Cl- + C2H3N = (Cl- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar61. ± 10.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar65.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar65.7J/mol*KPHPMSYamabe, Furumiya, et al., 1986gas phase; M
Deltar59.8J/mol*KPHPMSSieck, 1985gas phase; M
Deltar59.8J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Deltar89.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar42.68 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar38. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar37. ± 11.kJ/molTDAsYamabe, Furumiya, et al., 1986gas phase; B
Deltar42.26 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Deltar38. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet Acetonitrile) + Acetonitrile = (Chlorine anion bullet 2Acetonitrile)

By formula: (Cl- bullet C2H3N) + C2H3N = (Cl- bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar52.3 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar51.04kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar68.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar79.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar32. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar27.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet 2Acetonitrile) + Acetonitrile = (Chlorine anion bullet 3Acetonitrile)

By formula: (Cl- bullet 2C2H3N) + C2H3N = (Cl- bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar46.9 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar44.35kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar84.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar22. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar19.2kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet 3Acetonitrile) + Acetonitrile = (Chlorine anion bullet 4Acetonitrile)

By formula: (Cl- bullet 3C2H3N) + C2H3N = (Cl- bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar45.6 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar37.7 ± 3.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar25.9kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar45.2J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar12. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar12.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet 4Acetonitrile) + Acetonitrile = (Chlorine anion bullet 5Acetonitrile)

By formula: (Cl- bullet 4C2H3N) + C2H3N = (Cl- bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar41.0 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar24.3 ± 3.8kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion bullet 5Acetonitrile) + Acetonitrile = (Chlorine anion bullet 6Acetonitrile)

By formula: (Cl- bullet 5C2H3N) + C2H3N = (Cl- bullet 6C2H3N)

Quantity Value Units Method Reference Comment
Deltar39.7 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar24. ± 4.2kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar122.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.3 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion bullet 6Acetonitrile) + Acetonitrile = (Chlorine anion bullet 7Acetonitrile)

By formula: (Cl- bullet 6C2H3N) + C2H3N = (Cl- bullet 7C2H3N)

Quantity Value Units Method Reference Comment
Deltar39.3 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar16. ± 4.6kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 5.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion bullet 7Acetonitrile) + Acetonitrile = (Chlorine anion bullet 8Acetonitrile)

By formula: (Cl- bullet 7C2H3N) + C2H3N = (Cl- bullet 8C2H3N)

Quantity Value Units Method Reference Comment
Deltar38.5kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Deltar12. ± 5.0kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar-1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Chlorine anion bullet 8Acetonitrile) + Acetonitrile = (Chlorine anion bullet 9Acetonitrile)

By formula: (Cl- bullet 8C2H3N) + C2H3N = (Cl- bullet 9C2H3N)

Quantity Value Units Method Reference Comment
Deltar18. ± 5.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 9Acetonitrile) + Acetonitrile = (Chlorine anion bullet 10Acetonitrile)

By formula: (Cl- bullet 9C2H3N) + C2H3N = (Cl- bullet 10C2H3N)

Quantity Value Units Method Reference Comment
Deltar8.8 ± 6.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 10Acetonitrile) + Acetonitrile = (Chlorine anion bullet 11Acetonitrile)

By formula: (Cl- bullet 10C2H3N) + C2H3N = (Cl- bullet 11C2H3N)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 6.7kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 11Acetonitrile) + Acetonitrile = (Chlorine anion bullet 12Acetonitrile)

By formula: (Cl- bullet 11C2H3N) + C2H3N = (Cl- bullet 12C2H3N)

Quantity Value Units Method Reference Comment
Deltar-2. ± 7.1kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 12Acetonitrile) + Acetonitrile = (Chlorine anion bullet 13Acetonitrile)

By formula: (Cl- bullet 12C2H3N) + C2H3N = (Cl- bullet 13C2H3N)

Quantity Value Units Method Reference Comment
Deltar4. ± 7.5kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 13Acetonitrile) + Acetonitrile = (Chlorine anion bullet 14Acetonitrile)

By formula: (Cl- bullet 13C2H3N) + C2H3N = (Cl- bullet 14C2H3N)

Quantity Value Units Method Reference Comment
Deltar-2. ± 7.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

Chlorine anion + Ethane, 1,1-difluoro- = (Chlorine anion bullet Ethane, 1,1-difluoro-)

By formula: Cl- + C2H4F2 = (Cl- bullet C2H4F2)

Quantity Value Units Method Reference Comment
Deltar62.3 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar34. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2,2,2-Trifluoroethylamine = (Chlorine anion bullet 2,2,2-Trifluoroethylamine)

By formula: Cl- + C2H4F3N = (Cl- bullet C2H4F3N)

Quantity Value Units Method Reference Comment
Deltar75.3 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar45.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Acetaldehyde = (Chlorine anion bullet Acetaldehyde)

By formula: Cl- + C2H4O = (Cl- bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar60.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Acetic acid = (Chlorine anion bullet Acetic acid)

By formula: Cl- + C2H4O2 = (Cl- bullet C2H4O2)

Quantity Value Units Method Reference Comment
Deltar102.1 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Deltar90.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Deltar100. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSSieck, 1985gas phase; M
Deltar100.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar80.8J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar77.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Deltar66.1 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Deltar69.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl bromide = (Chlorine anion bullet Ethyl bromide)

By formula: Cl- + C2H5Br = (Cl- bullet C2H5Br)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar29.0 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + 2-Chloroethanol = (Chlorine anion bullet 2-Chloroethanol)

By formula: Cl- + C2H5ClO = (Cl- bullet C2H5ClO)

Quantity Value Units Method Reference Comment
Deltar90.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)FCH2CH2OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar58.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl Chloride = (Chlorine anion bullet Ethyl Chloride)

By formula: Cl- + C2H5Cl = (Cl- bullet C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar51.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar61. ± 19.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Deltar28.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Ethanol, 2-fluoro- = (Chlorine anion bullet Ethanol, 2-fluoro-)

By formula: Cl- + C2H5FO = (Cl- bullet C2H5FO)

Quantity Value Units Method Reference Comment
Deltar85.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar54.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Dimethyl Sulfoxide = (Chlorine anion bullet Dimethyl Sulfoxide)

By formula: Cl- + C2H6OS = (Cl- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar77.82kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar52.30kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

(Chlorine anion bullet Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 2Dimethyl Sulfoxide)

By formula: (Cl- bullet C2H6OS) + C2H6OS = (Cl- bullet 2C2H6OS)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 2Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 3Dimethyl Sulfoxide)

By formula: (Cl- bullet 2C2H6OS) + C2H6OS = (Cl- bullet 3C2H6OS)

Quantity Value Units Method Reference Comment
Deltar62.3kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 3Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 4Dimethyl Sulfoxide)

By formula: (Cl- bullet 3C2H6OS) + C2H6OS = (Cl- bullet 4C2H6OS)

Quantity Value Units Method Reference Comment
Deltar61.1kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar156.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 4Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 5Dimethyl Sulfoxide)

By formula: (Cl- bullet 4C2H6OS) + C2H6OS = (Cl- bullet 5C2H6OS)

Quantity Value Units Method Reference Comment
Deltar57.7kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar168.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

Chlorine anion + Ethanol = (Chlorine anion bullet Ethanol)

By formula: Cl- + C2H6O = (Cl- bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar74.9 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar73.6 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Deltar72.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar99.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar96.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar44.56kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar43.9 ± 8.4kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar43.9 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Deltar43.5 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
41.8295.ICRRiveros, 1974gas phase; switching reaction(Cl-)CH3OH; Riveros, Breda, et al., 1973; M

(Chlorine anion bullet Ethanol) + Ethanol = (Chlorine anion bullet 2Ethanol)

By formula: (Cl- bullet C2H6O) + C2H6O = (Cl- bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar64.02 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar67.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar35. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 2Ethanol) + Ethanol = (Chlorine anion bullet 3Ethanol)

By formula: (Cl- bullet 2C2H6O) + C2H6O = (Cl- bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar58.2 ± 2.9kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar53.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.6kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar21. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 3Ethanol) + Ethanol = (Chlorine anion bullet 4Ethanol)

By formula: (Cl- bullet 3C2H6O) + C2H6O = (Cl- bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar50.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar13. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 4Ethanol) + Ethanol = (Chlorine anion bullet 5Ethanol)

By formula: (Cl- bullet 4C2H6O) + C2H6O = (Cl- bullet 5C2H6O)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 5Ethanol) + Ethanol = (Chlorine anion bullet 6Ethanol)

By formula: (Cl- bullet 5C2H6O) + C2H6O = (Cl- bullet 6C2H6O)

Quantity Value Units Method Reference Comment
Deltar46.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Ethanol) + Ethanol = (Chlorine anion bullet 7Ethanol)

By formula: (Cl- bullet 6C2H6O) + C2H6O = (Cl- bullet 7C2H6O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Ethanol) + Ethanol = (Chlorine anion bullet 8Ethanol)

By formula: (Cl- bullet 7C2H6O) + C2H6O = (Cl- bullet 8C2H6O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 8Ethanol) + Ethanol = (Chlorine anion bullet 9Ethanol)

By formula: (Cl- bullet 8C2H6O) + C2H6O = (Cl- bullet 9C2H6O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion bullet 9Ethanol) + Ethanol = (Chlorine anion bullet 10Ethanol)

By formula: (Cl- bullet 9C2H6O) + C2H6O = (Cl- bullet 10C2H6O)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
Deltar31.4 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar12. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 1,2-Ethanediol = (Chlorine anion bullet 1,2-Ethanediol)

By formula: Cl- + C2H6O2 = (Cl- bullet C2H6O2)

Quantity Value Units Method Reference Comment
Deltar106. ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar69.5 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 1,2-Ethanediol) + 1,2-Ethanediol = (Chlorine anion bullet 21,2-Ethanediol)

By formula: (Cl- bullet C2H6O2) + C2H6O2 = (Cl- bullet 2C2H6O2)

Quantity Value Units Method Reference Comment
Deltar66.5 ± 5.0kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar39. ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion bullet 2-Propanone, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3F6O = (Cl- bullet C3F6O)

Quantity Value Units Method Reference Comment
Deltar120. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar95.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar73.6 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar68.2 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Deltar68.2kJ/molICRLarson and McMahon, 1984, 3gas phase; switching reaction(Cl-)(C2H5)3B; M

Chlorine anion + Propene, hexafluoro- = C3ClF6-

By formula: Cl- + C3F6 = C3ClF6-

Quantity Value Units Method Reference Comment
Deltar52.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar21.5 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3-pentafluoro- = (Chlorine anion bullet 2-Propanone, 1,1,1,3,3-pentafluoro-)

By formula: Cl- + C3HF5O = (Cl- bullet C3HF5O)

Quantity Value Units Method Reference Comment
Deltar109. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar97.9kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar72.0 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar68.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M,M

Chlorine anion + 1,1,3,3-tetrafluoroacetone = (Chlorine anion bullet 1,1,3,3-tetrafluoroacetone)

By formula: Cl- + C3H2F4O = (Cl- bullet C3H2F4O)

Quantity Value Units Method Reference Comment
Deltar75.7 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + 2-Propanol, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion bullet 2-Propanol, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3H2F6O = (Cl- bullet C3H2F6O)

Quantity Value Units Method Reference Comment
Deltar111.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar79.5kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M

Chlorine anion + C3H3F3O- = C2H3ClF3O-

By formula: Cl- + C3H3F3O- = C2H3ClF3O-

Quantity Value Units Method Reference Comment
Deltar56.9 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 2-Propanone, 1,1,1-trifluoro- = C3H3ClF3O-

By formula: Cl- + C3H3F3O = C3H3ClF3O-

Quantity Value Units Method Reference Comment
Deltar57.3 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar34. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B

Chlorine anion + 2-Propanone, 1-fluoro- = C3H5ClFO-

By formula: Cl- + C3H5FO = C3H5ClFO-

Quantity Value Units Method Reference Comment
Deltar77.0 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar46.4 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B

Chlorine anion + 1,3-Difluoro-2-propanol = (Chlorine anion bullet 1,3-Difluoro-2-propanol)

By formula: Cl- + C3H6F2O = (Cl- bullet C3H6F2O)

Quantity Value Units Method Reference Comment
Deltar98.7kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar67.4kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Acetone = (Chlorine anion bullet Acetone)

By formula: Cl- + C3H6O = (Cl- bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar56. ± 6.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSSieck, 1985gas phase; M
Deltar82.0J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Deltar71.5J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar82.4J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar33.8 ± 0.84kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar30.5kJ/molTDAsHiraoka, Morise, et al., 1986gas phase; B
Deltar36.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Deltar34. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar33. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B

(Chlorine anion bullet Acetone) + Acetone = (Chlorine anion bullet 2Acetone)

By formula: (Cl- bullet C3H6O) + C3H6O = (Cl- bullet 2C3H6O)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 4.2kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar23. ± 9.2kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B

(Chlorine anion bullet 2Acetone) + Acetone = (Chlorine anion bullet 3Acetone)

By formula: (Cl- bullet 2C3H6O) + C3H6O = (Cl- bullet 3C3H6O)

Quantity Value Units Method Reference Comment
Deltar43.5 ± 8.4kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AHiraoka, Takimoto, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16. ± 19.kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; Entropy estimated; B

Chlorine anion + Propane, 2-bromo- = (Chlorine anion bullet Propane, 2-bromo-)

By formula: Cl- + C3H7Br = (Cl- bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar63.6 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar35.6 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 1-bromo- = (Chlorine anion bullet Propane, 1-bromo-)

By formula: Cl- + C3H7Br = (Cl- bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar59.4 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar34.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 2-chloro- = (Chlorine anion bullet Propane, 2-chloro-)

By formula: Cl- + C3H7Cl = (Cl- bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar61.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar32.6 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Isopropyl Alcohol = (Chlorine anion bullet Isopropyl Alcohol)

By formula: Cl- + C3H8O = (Cl- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar81.17 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar76.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar97.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar47.36kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar45.61kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion bullet Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 2Isopropyl Alcohol)

By formula: (Cl- bullet C3H8O) + C3H8O = (Cl- bullet 2C3H8O)

Quantity Value Units Method Reference Comment
Deltar69.9 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar65.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 2Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 3Isopropyl Alcohol)

By formula: (Cl- bullet 2C3H8O) + C3H8O = (Cl- bullet 3C3H8O)

Quantity Value Units Method Reference Comment
Deltar62.3 ± 2.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar52.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar20. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 3Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 4Isopropyl Alcohol)

By formula: (Cl- bullet 3C3H8O) + C3H8O = (Cl- bullet 4C3H8O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 4Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 5Isopropyl Alcohol)

By formula: (Cl- bullet 4C3H8O) + C3H8O = (Cl- bullet 5C3H8O)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 5Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 6Isopropyl Alcohol)

By formula: (Cl- bullet 5C3H8O) + C3H8O = (Cl- bullet 6C3H8O)

Quantity Value Units Method Reference Comment
Deltar47.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 7Isopropyl Alcohol)

By formula: (Cl- bullet 6C3H8O) + C3H8O = (Cl- bullet 7C3H8O)

Quantity Value Units Method Reference Comment
Deltar46.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 8Isopropyl Alcohol)

By formula: (Cl- bullet 7C3H8O) + C3H8O = (Cl- bullet 8C3H8O)

Quantity Value Units Method Reference Comment
Deltar45.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + 1-Propanol = (Chlorine anion bullet 1-Propanol)

By formula: Cl- + C3H8O = (Cl- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar85.4 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Deltar74.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar121.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar97.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar48.95kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar49.0 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Deltar45.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion bullet 1-Propanol) + 1-Propanol = (Chlorine anion bullet 21-Propanol)

By formula: (Cl- bullet C3H8O) + C3H8O = (Cl- bullet 2C3H8O)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 21-Propanol) + 1-Propanol = (Chlorine anion bullet 31-Propanol)

By formula: (Cl- bullet 2C3H8O) + C3H8O = (Cl- bullet 3C3H8O)

Quantity Value Units Method Reference Comment
Deltar59.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar20. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 31-Propanol) + 1-Propanol = (Chlorine anion bullet 41-Propanol)

By formula: (Cl- bullet 3C3H8O) + C3H8O = (Cl- bullet 4C3H8O)

Quantity Value Units Method Reference Comment
Deltar55.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar134.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar15. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 41-Propanol) + 1-Propanol = (Chlorine anion bullet 51-Propanol)

By formula: (Cl- bullet 4C3H8O) + C3H8O = (Cl- bullet 5C3H8O)

Quantity Value Units Method Reference Comment
Deltar52.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar138.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar11. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 51-Propanol) + 1-Propanol = (Chlorine anion bullet 61-Propanol)

By formula: (Cl- bullet 5C3H8O) + C3H8O = (Cl- bullet 6C3H8O)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 61-Propanol) + 1-Propanol = (Chlorine anion bullet 71-Propanol)

By formula: (Cl- bullet 6C3H8O) + C3H8O = (Cl- bullet 7C3H8O)

Quantity Value Units Method Reference Comment
Deltar46.0 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 71-Propanol) + 1-Propanol = (Chlorine anion bullet 81-Propanol)

By formula: (Cl- bullet 7C3H8O) + C3H8O = (Cl- bullet 8C3H8O)

Quantity Value Units Method Reference Comment
Deltar45.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + C3H9ClGe = C3H9Cl2Ge-

By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-

Quantity Value Units Method Reference Comment
Deltar92.9 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Silane, chlorotrimethyl- = C3H9Cl2Si-

By formula: Cl- + C3H9ClSi = C3H9Cl2Si-

Quantity Value Units Method Reference Comment
Deltar59.8 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Stannane, chlorotrimethyl- = C3H9Cl2Sn-

By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-

Quantity Value Units Method Reference Comment
Deltar131. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + C4H4F6O = (Chlorine anion bullet C4H4F6O)

By formula: Cl- + C4H4F6O = (Cl- bullet C4H4F6O)

Quantity Value Units Method Reference Comment
Deltar111.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar79.5kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M

Chlorine anion + Pyrrole = (Chlorine anion bullet Pyrrole)

By formula: Cl- + C4H5N = (Cl- bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar78.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B
Quantity Value Units Method Reference Comment
Deltar49.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B
Deltar58.58kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
48.5421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 2-Butyne-1,4-diol = (Chlorine anion bullet 2-Butyne-1,4-diol)

By formula: Cl- + C4H6O2 = (Cl- bullet C4H6O2)

Quantity Value Units Method Reference Comment
Deltar121. ± 4.6kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar75.3 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 2-Butyne-1,4-diol) + 2-Butyne-1,4-diol = (Chlorine anion bullet 22-Butyne-1,4-diol)

By formula: (Cl- bullet C4H6O2) + C4H6O2 = (Cl- bullet 2C4H6O2)

Quantity Value Units Method Reference Comment
Deltar93.3 ± 2.9kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + 2-Butanone = (Chlorine anion bullet 2-Butanone)

By formula: Cl- + C4H8O = (Cl- bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar61.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CH3)2CO, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar36. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2-Butene-1,4-diol, (Z)- = (Chlorine anion bullet 2-Butene-1,4-diol, (Z)-)

By formula: Cl- + C4H8O2 = (Cl- bullet C4H8O2)

Quantity Value Units Method Reference Comment
Deltar138. ± 6.3kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar82.4 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 2-Butene-1,4-diol, (Z)-) + 2-Butene-1,4-diol, (Z)- = (Chlorine anion bullet 22-Butene-1,4-diol, (Z)-)

By formula: (Cl- bullet C4H8O2) + C4H8O2 = (Cl- bullet 2C4H8O2)

Quantity Value Units Method Reference Comment
Deltar95.8 ± 1.7kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar49.0 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + Propane, 2-bromo-2-methyl- = (Chlorine anion bullet Propane, 2-bromo-2-methyl-)

By formula: Cl- + C4H9Br = (Cl- bullet C4H9Br)

Quantity Value Units Method Reference Comment
Deltar74.1 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar37.2 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 2-chloro-2-methyl- = (Chlorine anion bullet Propane, 2-chloro-2-methyl-)

By formula: Cl- + C4H9Cl = (Cl- bullet C4H9Cl)

Quantity Value Units Method Reference Comment
Deltar69.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar59.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar34.7 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Propane, 2-fluoro-2-methyl- = (Chlorine anion bullet Propane, 2-fluoro-2-methyl-)

By formula: Cl- + C4H9F = (Cl- bullet C4H9F)

Quantity Value Units Method Reference Comment
Deltar55.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar30. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl ether = C4H10ClO-

By formula: Cl- + C4H10O = C4H10ClO-

Quantity Value Units Method Reference Comment
Deltar37.7 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 1-Butanol = (Chlorine anion bullet 1-Butanol)

By formula: Cl- + C4H10O = (Cl- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2-Propanol, 2-methyl- = (Chlorine anion bullet 2-Propanol, 2-methyl-)

By formula: Cl- + C4H10O = (Cl- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar77. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar100.J/mol*KPHPMSSieck, 1985gas phase; M
Deltar97.9J/mol*KN/ALarson and McMahon, 1984, 2gas phase; Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar110.J/mol*KPHPMSKebarle, 1977gas phase; M
Deltar43.1J/mol*KN/AYamdagni and Kebarle, 1971gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar48.45kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar51.5 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Deltar48.53kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar46.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar46.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

(Chlorine anion bullet 2-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 22-Propanol, 2-methyl-)

By formula: (Cl- bullet C4H10O) + C4H10O = (Cl- bullet 2C4H10O)

Quantity Value Units Method Reference Comment
Deltar70.71 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar62.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar30. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 22-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 32-Propanol, 2-methyl-)

By formula: (Cl- bullet 2C4H10O) + C4H10O = (Cl- bullet 3C4H10O)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar57.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar18. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 32-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 42-Propanol, 2-methyl-)

By formula: (Cl- bullet 3C4H10O) + C4H10O = (Cl- bullet 4C4H10O)

Quantity Value Units Method Reference Comment
Deltar53.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 42-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 52-Propanol, 2-methyl-)

By formula: (Cl- bullet 4C4H10O) + C4H10O = (Cl- bullet 5C4H10O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar135.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 52-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 62-Propanol, 2-methyl-)

By formula: (Cl- bullet 5C4H10O) + C4H10O = (Cl- bullet 6C4H10O)

Quantity Value Units Method Reference Comment
Deltar47.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + 1,4-Butanediol = (Chlorine anion bullet 1,4-Butanediol)

By formula: Cl- + C4H10O2 = (Cl- bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar126. ± 7.1kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar73.2 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 1,4-Butanediol) + 1,4-Butanediol = (Chlorine anion bullet 21,4-Butanediol)

By formula: (Cl- bullet C4H10O2) + C4H10O2 = (Cl- bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar88.7 ± 3.3kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar44.4 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + Cyclopentene, octafluoro- = C5ClF8-

By formula: Cl- + C5F8 = C5ClF8-

Quantity Value Units Method Reference Comment
Deltar57.74 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Quantity Value Units Method Reference Comment
Deltar34.1 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B

Chlorine anion + Iron pentacarbonyl = (Chlorine anion bullet Iron pentacarbonyl)

By formula: Cl- + C5FeO5 = (Cl- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar58. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar33. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase; B

Chlorine anion + Pyridine = (Chlorine anion bullet Pyridine)

By formula: Cl- + C5H5N = (Cl- bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar53.1 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar28. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

(Chlorine anion bullet Pyridine) + Pyridine = (Chlorine anion bullet 2Pyridine)

By formula: (Cl- bullet C5H5N) + C5H5N = (Cl- bullet 2C5H5N)

Quantity Value Units Method Reference Comment
Deltar49.0kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M

Chlorine anion + 1,3-Cyclopentadiene = (Chlorine anion bullet 1,3-Cyclopentadiene)

By formula: Cl- + C5H6 = (Cl- bullet C5H6)

Quantity Value Units Method Reference Comment
Deltar<10.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
10.300.PHPMSFrench, Ikuta, et al., 1982gas phase; DG<; M

Chlorine anion + Acetylacetone = (Chlorine anion bullet Acetylacetone)

By formula: Cl- + C5H8O2 = (Cl- bullet C5H8O2)

Quantity Value Units Method Reference Comment
Deltar56.07kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
46.0421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 1,4-Pentadiene = (Chlorine anion bullet 1,4-Pentadiene)

By formula: Cl- + C5H8 = (Cl- bullet C5H8)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 1,3-Pentadiene, (E)- = (Chlorine anion bullet 1,3-Pentadiene, (E)-)

By formula: Cl- + C5H8 = (Cl- bullet C5H8)

Quantity Value Units Method Reference Comment
Deltar15.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Propanenitrile, 2,2-dimethyl- = (Chlorine anion bullet Propanenitrile, 2,2-dimethyl-)

By formula: Cl- + C5H9N = (Cl- bullet C5H9N)

Quantity Value Units Method Reference Comment
Deltar77.4 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar46.23 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + 3-Pentanone = (Chlorine anion bullet 3-Pentanone)

By formula: Cl- + C5H10O = (Cl- bullet C5H10O)

Quantity Value Units Method Reference Comment
Deltar59.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CH3)2CO, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar34. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Propanal, 2,2-dimethyl- = (Chlorine anion bullet Propanal, 2,2-dimethyl-)

By formula: Cl- + C5H10O = (Cl- bullet C5H10O)

Quantity Value Units Method Reference Comment
Deltar62.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar35. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + p-Benzoquinone, 2,3,5,6-tetrafluoro- = (Chlorine anion bullet p-Benzoquinone, 2,3,5,6-tetrafluoro-)

By formula: Cl- + C6F4O2 = (Cl- bullet C6F4O2)

Quantity Value Units Method Reference Comment
Deltar113. ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzene, hexafluoro- = (Chlorine anion bullet Benzene, hexafluoro-)

By formula: Cl- + C6F6 = (Cl- bullet C6F6)

Quantity Value Units Method Reference Comment
Deltar70.3 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Deltar64.9 ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Deltar113.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar37. ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B
Deltar36. ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Chlorine anion bullet Benzene, hexafluoro-) + Benzene, hexafluoro- = (Chlorine anion bullet 2Benzene, hexafluoro-)

By formula: (Cl- bullet C6F6) + C6F6 = (Cl- bullet 2C6F6)

Quantity Value Units Method Reference Comment
Deltar57.7kJ/molPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M

Chlorine anion + Benzene, 1-fluoro-3-nitro- = (Chlorine anion bullet Benzene, 1-fluoro-3-nitro-)

By formula: Cl- + C6H4FNO2 = (Cl- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar78.2 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar51.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzene, 1,2-difluoro- = (Chlorine anion bullet Benzene, 1,2-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- bullet C6H4F2)

Quantity Value Units Method Reference Comment
Deltar59.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.4J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Benzene, 1,3-difluoro- = (Chlorine anion bullet Benzene, 1,3-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- bullet C6H4F2)

Quantity Value Units Method Reference Comment
Deltar61.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar32. ± 4.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Benzene, 1,4-difluoro- = (Chlorine anion bullet Benzene, 1,4-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- bullet C6H4F2)

Quantity Value Units Method Reference Comment
Deltar57.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.4J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar31. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Benzene, bromo- = (Chlorine anion bullet Benzene, bromo-)

By formula: Cl- + C6H5Br = (Cl- bullet C6H5Br)

Quantity Value Units Method Reference Comment
Deltar28.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B,M

Chlorine anion + Phenol, 4-chloro- = (Chlorine anion bullet Phenol, 4-chloro-)

By formula: Cl- + C6H5ClO = (Cl- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar124. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Deltar126.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar92.5 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
81.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
87.9300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzene, chloro- = (Chlorine anion bullet Benzene, chloro-)

By formula: Cl- + C6H5Cl = (Cl- bullet C6H5Cl)

Quantity Value Units Method Reference Comment
Deltar50.21 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Deltar56.9 ± 4.2kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,B,M
Deltar52.7kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar69.0J/mol*KPHPMSSieck, 1985gas phase; M
Deltar93.7J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar29.7 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Deltar29. ± 4.2kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,B,M
Deltar27.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
27.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phenol, 4-fluoro- = (Chlorine anion bullet Phenol, 4-fluoro-)

By formula: Cl- + C6H5FO = (Cl- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar117. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Deltar120.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar106.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar86.2 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
75.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
80.8300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzene, fluoro- = (Chlorine anion bullet Benzene, fluoro-)

By formula: Cl- + C6H5F = (Cl- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar24.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, iodo- = (Chlorine anion bullet Benzene, iodo-)

By formula: Cl- + C6H5I = (Cl- bullet C6H5I)

Quantity Value Units Method Reference Comment
Deltar30.1kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, nitro- = (Chlorine anion bullet Benzene, nitro-)

By formula: Cl- + C6H5NO2 = (Cl- bullet C6H5NO2)

Quantity Value Units Method Reference Comment
Deltar68.2 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Deltar69.0kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar81.2J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar43.9 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B
Deltar29.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
43.9300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
32.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phenol = (Chlorine anion bullet Phenol)

By formula: Cl- + C6H6O = (Cl- bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar109. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Deltar109. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Deltar115.kJ/molPHPMSKebarle, 1977gas phase; M
Deltar111.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar81.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Deltar100.J/mol*KPHPMSKebarle, 1977gas phase; M
Deltar100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar64.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar80.3 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Deltar77.4 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Deltar61.9 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
66.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Chlorine anion + Benzene = (Chlorine anion bullet Benzene)

By formula: Cl- + C6H6 = (Cl- bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar25.1 ± 1.9kJ/molN/ATschurl, Ueberfluss, et al., 2007gas phase; B
Deltar39. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Deltar41.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar36.kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar43.5kJ/molPHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Deltar71.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar71.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar92.J/mol*KN/ASunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Deltar16. ± 6.7kJ/molIMREChowdhury and Kebarle, 1986gas phase; B
Deltar20. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar15.9kJ/molIMREFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
16.300.PHPMSChowdhury and Kebarle, 1986gas phase; M
16.300.PHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Chlorine anion + L-Alanine, N-acetyl-, methyl ester = (Chlorine anion bullet L-Alanine, N-acetyl-, methyl ester)

By formula: Cl- + C6H11NO3 = (Cl- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar123.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar123.kJ/molPHPMSMeot-ner, 1988gas phase; CH3CO-Ala-OCH3; M
Quantity Value Units Method Reference Comment
Deltar118.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar118.J/mol*KPHPMSMeot-ner, 1988gas phase; CH3CO-Ala-OCH3; M

(Chlorine anion bullet L-Alanine, N-acetyl-, methyl ester) + L-Alanine, N-acetyl-, methyl ester = (Chlorine anion bullet 2L-Alanine, N-acetyl-, methyl ester)

By formula: (Cl- bullet C6H11NO3) + C6H11NO3 = (Cl- bullet 2C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar82.8kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar113.J/mol*KPHPMSMeot-ner, 1988gas phase; M

Chlorine anion + CH3CONHCH(CH3)COOCH3 = (Chlorine anion bullet CH3CONHCH(CH3)COOCH3)

By formula: Cl- + C6H11NO3 = (Cl- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar123. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar87.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

Chlorine anion + Borane, triethyl- = (Chlorine anion bullet Borane, triethyl-)

By formula: Cl- + C6H15B = (Cl- bullet C6H15B)

Quantity Value Units Method Reference Comment
Deltar99.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Deltar99.6kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Deltar92.0J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar72.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Deltar72.0kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzonitrile, pentafluoro- = (Chlorine anion bullet Benzonitrile, pentafluoro-)

By formula: Cl- + C7F5N = (Cl- bullet C7F5N)

Quantity Value Units Method Reference Comment
Deltar83.3J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar56.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Perfluoro(methylcyclohexane) = (Chlorine anion bullet Perfluoro(methylcyclohexane))

By formula: Cl- + C7F14 = (Cl- bullet C7F14)

Quantity Value Units Method Reference Comment
Deltar<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

Chlorine anion + Benzene, 1-nitro-3-(trifluoromethyl)- = (Chlorine anion bullet Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: Cl- + C7H4F3NO2 = (Cl- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar81.6 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.0 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzonitrile, 4-nitro- = (Chlorine anion bullet Benzonitrile, 4-nitro-)

By formula: Cl- + C7H4N2O2 = (Cl- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar83.7 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar58.6 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzonitrile, 4-hydroxy- = (Chlorine anion bullet Benzonitrile, 4-hydroxy-)

By formula: Cl- + C7H5NO = (Cl- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar147. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M,M
Deltar148.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar120.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar114. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
103.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
110.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
108.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzonitrile = (Chlorine anion bullet Benzonitrile)

By formula: Cl- + C7H5N = (Cl- bullet C7H5N)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
41.8300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M

Chlorine anion + Benzene, 1-methyl-4-nitro- = (Chlorine anion bullet Benzene, 1-methyl-4-nitro-)

By formula: Cl- + C7H7NO2 = (Cl- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar31.4kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Anisole = (Chlorine anion bullet Anisole)

By formula: Cl- + C7H8O = (Cl- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar30.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + p-Cresol = (Chlorine anion bullet p-Cresol)

By formula: Cl- + C7H8O = (Cl- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar107. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Deltar108.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar112.J/mol*KPHPMSCummings, French, et al., 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar74.9 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
64.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
69.5300.PHPMSCummings, French, et al., 1977gas phase; M

Chlorine anion + Toluene = (Chlorine anion bullet Toluene)

By formula: Cl- + C7H8 = (Cl- bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar16.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
17.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Acetophenone = (Chlorine anion bullet Acetophenone)

By formula: Cl- + C8H8O = (Cl- bullet C8H8O)

Quantity Value Units Method Reference Comment
Deltar39.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Ethylbenzene = (Chlorine anion bullet Ethylbenzene)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar20.9kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + p-Xylene = (Chlorine anion bullet p-Xylene)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar16.3kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
16.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, 1,3-dimethyl- = (Chlorine anion bullet Benzene, 1,3-dimethyl-)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar16.3kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzyl methyl ketone = (Chlorine anion bullet Benzyl methyl ketone)

By formula: Cl- + C9H10O = (Cl- bullet C9H10O)

Quantity Value Units Method Reference Comment
Deltar44.77kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
35.421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, (1-methylethyl)- = (Chlorine anion bullet Benzene, (1-methylethyl)-)

By formula: Cl- + C9H12 = (Cl- bullet C9H12)

Quantity Value Units Method Reference Comment
Deltar23.0kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, propyl- = (Chlorine anion bullet Benzene, propyl-)

By formula: Cl- + C9H12 = (Cl- bullet C9H12)

Quantity Value Units Method Reference Comment
Deltar20.9kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Mesitylene = (Chlorine anion bullet Mesitylene)

By formula: Cl- + C9H12 = (Cl- bullet C9H12)

Quantity Value Units Method Reference Comment
Deltar18.8kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Diphenylmethane = (Chlorine anion bullet Diphenylmethane)

By formula: Cl- + C13H12 = (Cl- bullet C13H12)

Quantity Value Units Method Reference Comment
Deltar31.0kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Triphenylmethane = (Chlorine anion bullet Triphenylmethane)

By formula: Cl- + C19H16 = (Cl- bullet C19H16)

Quantity Value Units Method Reference Comment
Deltar17.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
17.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phosphorus difluoride monochloride = Cl2F2P-

By formula: Cl- + ClF2P = Cl2F2P-

Quantity Value Units Method Reference Comment
Deltar98.99kJ/molN/ACheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Cl2Nd = (Chlorine anion bullet Cl2Nd)

By formula: Cl- + Cl2Nd = (Cl- bullet Cl2Nd)

Quantity Value Units Method Reference Comment
Deltar274. ± 15.kJ/molTDAsKudin, Pogrebnoi, et al., 1993gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Thionyl chloride = Cl3OS-

By formula: Cl- + Cl2OS = Cl3OS-

Quantity Value Units Method Reference Comment
Deltar85.4 ± 7.5kJ/molCIDTBachrach, Hayes, et al., 2001gas phase; B

Chlorine anion + seleninyl dichloride = Cl3OSe-

By formula: Cl- + Cl2OSe = Cl3OSe-

Quantity Value Units Method Reference Comment
Deltar149.8kJ/molN/ALobring, Hao, et al., 2003gas phase; B

Chlorine anion + Sulfur dichloride = Cl3S-

By formula: Cl- + Cl2S = Cl3S-

Quantity Value Units Method Reference Comment
Deltar84.9 ± 7.9kJ/molCIDTGailbreath, Pommerening, et al., 2000gas phase; B

Chlorine anion + Selenium dichloride = Cl3Se-

By formula: Cl- + Cl2Se = Cl3Se-

Quantity Value Units Method Reference Comment
Deltar133. ± 9.2kJ/molCIDTLobring, Hao, et al., 2003gas phase; B

Chlorine anion + Cl2Yb = (Chlorine anion bullet Cl2Yb)

By formula: Cl- + Cl2Yb = (Cl- bullet Cl2Yb)

Quantity Value Units Method Reference Comment
Deltar>236.0kJ/molN/AKuznetsov, Kudin, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Chlorine = (Chlorine anion bullet Chlorine)

By formula: Cl- + Cl2 = (Cl- bullet Cl2)

Quantity Value Units Method Reference Comment
Deltar71.1kJ/molSAMSRobbiani and Franklin, 1979gas phase; based on Cl- + SO2Cl2 <--> Cl3- + SO2; National Bureau of Standards, 1968; M

Chlorine anion + Chlorine = Cl3-

By formula: Cl- + Cl2 = Cl3-

Quantity Value Units Method Reference Comment
Deltar99.2 ± 5.0kJ/molCIDTNizzi, Pommerening, et al., 1998gas phase; B
Deltar69.87kJ/molTherRobbiani and Franklin, 1979, 2gas phase; «DELTA»G~=+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2; B
Deltar<182.4kJ/molPDisLee, Smith, et al., 1979gas phase; B

Chlorine anion + Cl3Er = Cl4Er-

By formula: Cl- + Cl3Er = Cl4Er-

Quantity Value Units Method Reference Comment
Deltar344. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar327. ± 16.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Cl3Er = Cl7Er2-

By formula: Cl- + Cl3Er = Cl7Er2-

Quantity Value Units Method Reference Comment
Deltar239. ± 37.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar340. ± 37.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Cl3Er = Cl10Er3-

By formula: Cl- + Cl3Er = Cl10Er3-

Quantity Value Units Method Reference Comment
Deltar330. ± 59.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Trichlorofluorosilane = Cl4FSi-

By formula: Cl- + Cl3FSi = Cl4FSi-

Quantity Value Units Method Reference Comment
Deltar115. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Cl3La = (Chlorine anion bullet Cl3La)

By formula: Cl- + Cl3La = (Cl- bullet Cl3La)

Quantity Value Units Method Reference Comment
Deltar332. ± 17.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion bullet Cl3La) + Cl3La = (Chlorine anion bullet 2Cl3La)

By formula: (Cl- bullet Cl3La) + Cl3La = (Cl- bullet 2Cl3La)

Quantity Value Units Method Reference Comment
Deltar136. ± 15.kJ/molMSButman, Kudin, et al., 1987gas phase; Knudsen cell; M

Chlorine anion + Cl3Lu = (Chlorine anion bullet Cl3Lu)

By formula: Cl- + Cl3Lu = (Cl- bullet Cl3Lu)

Quantity Value Units Method Reference Comment
Deltar297. ± 15.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; EA estimated as 3.7±1.0 eV; value altered from reference due to conversion from electron convention to ion convention; B
Deltar359. ± 10.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Phosphorus oxychloride = Cl4OP-

By formula: Cl- + Cl3OP = Cl4OP-

Quantity Value Units Method Reference Comment
Deltar43.1 ± 5.0kJ/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Thiophosphoryl chloride = Cl4PS-

By formula: Cl- + Cl3PS = Cl4PS-

Quantity Value Units Method Reference Comment
Deltar41.0 ± 4.0kJ/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Phosphorus trichloride = Cl4P-

By formula: Cl- + Cl3P = Cl4P-

Quantity Value Units Method Reference Comment
Deltar90.0 ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Deltar160. ± 7.9kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Cl3Sm = Cl4Sm-

By formula: Cl- + Cl3Sm = Cl4Sm-

Quantity Value Units Method Reference Comment
Deltar289. ± 16.kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar362. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Cl3Tb = Cl4Tb-

By formula: Cl- + Cl3Tb = Cl4Tb-

Quantity Value Units Method Reference Comment
Deltar353. ± 18.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar304. ± 6.7kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Cl3Yb = (Chlorine anion bullet Cl3Yb)

By formula: Cl- + Cl3Yb = (Cl- bullet Cl3Yb)

Quantity Value Units Method Reference Comment
Deltar311. ± 30.kJ/molTDAsKuznetsov, Kudin, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar348. ± 19.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Germanium tetrachloride = Cl5Ge-

By formula: Cl- + Cl4Ge = Cl5Ge-

Quantity Value Units Method Reference Comment
Deltar141. ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Silicon tetrachloride = (Chlorine anion bullet Silicon tetrachloride)

By formula: Cl- + Cl4Si = (Cl- bullet Cl4Si)

Quantity Value Units Method Reference Comment
Deltar105. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B
Deltar101. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar73.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B

Chlorine anion + Tin(IV) chloride = Cl5Sn-

By formula: Cl- + Cl4Sn = Cl5Sn-

Quantity Value Units Method Reference Comment
Deltar235. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Cl4Th = (Chlorine anion bullet Cl4Th)

By formula: Cl- + Cl4Th = (Cl- bullet Cl4Th)

Quantity Value Units Method Reference Comment
Deltar101.kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar73.6kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M

Chlorine anion + Hydrochloric acid-d = (Chlorine anion bullet Hydrochloric acid-d)

By formula: Cl- + DCl = (Cl- bullet DCl)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
70.3300.ICRLarson and McMahon, 1987gas phase; switching reaction(Cl-)HCl; Caldwell and Kebarle, 1985; M

Chlorine anion + Deuterium oxide = (Chlorine anion bullet Deuterium oxide)

By formula: Cl- + D2O = (Cl- bullet D2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.50 ± 0.84kJ/molIMRELarson and McMahon, 1988gas phase; Anchored to Keesee and Castleman, 19802: HOH..Cl- + DOD <=> DOD..Cl- + HOH, Keq=0.77; B

Chlorine anion + Thionyl fluoride = (Chlorine anion bullet Thionyl fluoride)

By formula: Cl- + F2OS = (Cl- bullet F2OS)

Quantity Value Units Method Reference Comment
Deltar71.5 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar42.7 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Phosphoryl fluoride = (Chlorine anion bullet Phosphoryl fluoride)

By formula: Cl- + F3OP = (Cl- bullet F3OP)

Quantity Value Units Method Reference Comment
Deltar58.2 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar32. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Phosphorus trifluoride = (Chlorine anion bullet Phosphorus trifluoride)

By formula: Cl- + F3P = (Cl- bullet F3P)

Quantity Value Units Method Reference Comment
Deltar64.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Deltar64.9kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar38. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Deltar38.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Silicon tetrafluoride = (Chlorine anion bullet Silicon tetrafluoride)

By formula: Cl- + F4Si = (Cl- bullet F4Si)

Quantity Value Units Method Reference Comment
Deltar97.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar70.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + F6S- = (Chlorine anion bullet F6S-)

By formula: Cl- + F6S- = (Cl- bullet F6S-)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

Chlorine anion + Sulfur hexafluoride = (Chlorine anion bullet Sulfur hexafluoride)

By formula: Cl- + F6S = (Cl- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Hydrogen chloride = (Chlorine anion bullet Hydrogen chloride)

By formula: Cl- + HCl = (Cl- bullet HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar124. ± 4.2kJ/molN/AMetz, Kitsopoulos, et al., 1988gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Deltar99.6 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Deltar96.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar99.16 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Deltar85.4kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl-)SO2; M
Deltar98.3J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Deltar98.3J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar95.4J/mol*KN/AUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M
Quantity Value Units Method Reference Comment
Deltar68.2 ± 8.4kJ/molIMRELarson and McMahon, 1987gas phase; K = 0.60 for HCl..Cl- + DCL <=> DCl..Cl- + HCl, anchored to Larson and McMahon, 1984, 32; B
Deltar72. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B
Deltar66.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar69.9 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B
Deltar56.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M

(Chlorine anion bullet Hydrogen chloride) + Hydrogen chloride = (Chlorine anion bullet 2Hydrogen chloride)

By formula: (Cl- bullet HCl) + HCl = (Cl- bullet 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar63.60 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Deltar58.6kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Deltar102.J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar33.1 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion bullet 2Hydrogen chloride) + Hydrogen chloride = (Chlorine anion bullet 3Hydrogen chloride)

By formula: (Cl- bullet 2HCl) + HCl = (Cl- bullet 3HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar49.0 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.9J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.7 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion bullet 3Hydrogen chloride) + Hydrogen chloride = (Chlorine anion bullet 4Hydrogen chloride)

By formula: (Cl- bullet 3HCl) + HCl = (Cl- bullet 4HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1 ± 2.9kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 4.2kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion bullet Hydrogen chloride) + Water = (Chlorine anion bullet Water bullet Hydrogen chloride)

By formula: (Cl- bullet HCl) + H2O = (Cl- bullet H2O bullet HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar78.2J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M

(Chlorine anion bullet 2Hydrogen chloride) + <