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Chlorine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 301 to 314

Chlorine anion + C3H9ClGe = C3H9Cl2Ge-

By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-

Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.4kcal/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Tin(IV) chloride = Cl5Sn-

By formula: Cl- + Cl4Sn = Cl5Sn-

Quantity Value Units Method Reference Comment
Deltar56.2 ± 1.9kcal/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Thionyl chloride = Cl3OS-

By formula: Cl- + Cl2OS = Cl3OS-

Quantity Value Units Method Reference Comment
Deltar20.4 ± 1.8kcal/molCIDTBachrach, Hayes, et al., 2001gas phase

Chlorine anion + Silane, chlorotrimethyl- = C3H9Cl2Si-

By formula: Cl- + C3H9ClSi = C3H9Cl2Si-

Quantity Value Units Method Reference Comment
Deltar14.3 ± 1.4kcal/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Sulfur dichloride = Cl3S-

By formula: Cl- + Cl2S = Cl3S-

Quantity Value Units Method Reference Comment
Deltar20.3 ± 1.9kcal/molCIDTGailbreath, Pommerening, et al., 2000gas phase

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Deltar38.2 ± 1.9kcal/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + Phosphorus trichloride = Cl4P-

By formula: Cl- + Cl3P = Cl4P-

Quantity Value Units Method Reference Comment
Deltar21.5 ± 1.7kcal/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Deltar27.5 ± 1.7kcal/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Deltar36.6 ± 3.6kcal/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Deltar20.1 ± 1.6kcal/molCIDTHammad and Wenthold, 2000gas phase

Chlorine anion = C4HClF9-

By formula: Cl- = C4HClF9-

Quantity Value Units Method Reference Comment
Deltar15.50 ± 0.30kcal/molIMREGuerrero, Herrero, et al., 2009gas phase

Chlorine anion + seleninyl dichloride = Cl3OSe-

By formula: Cl- + Cl2OSe = Cl3OSe-

Quantity Value Units Method Reference Comment
Deltar35.80kcal/molN/ALobring, Hao, et al., 2003gas phase

Chlorine anion + Phosphorus difluoride monochloride = Cl2F2P-

By formula: Cl- + ClF2P = Cl2F2P-

Quantity Value Units Method Reference Comment
Deltar23.66kcal/molN/ACheck, Lobring, et al., 2003gas phase

Chlorine anion = ClN2O-

By formula: Cl- = ClN2O-

Quantity Value Units Method Reference Comment
Deltar4.50 ± 0.10kcal/molN/ABoesl, Distelrath, et al., 2008gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]

Bachrach, Hayes, et al., 2001
Bachrach, S.M.; Hayes, J.M.; Check, C.E.; Sunderlin, L.S., Potential energy surface of SOCl3-, J. Phys. Chem. A, 2001, 105, 41, 9595-9597, https://doi.org/10.1021/jp012412f . [all data]

Gailbreath, Pommerening, et al., 2000
Gailbreath, B.D.; Pommerening, C.A.; Bachrach, S.M.; Sunderlin, L.S., Potential Energy Surface of SCl3-, J. Phys. Chem., 2000, 104, 13, 2958, https://doi.org/10.1021/jp993671w . [all data]

Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S., The Thermochemistry of Group 15 Tetrachloride Anions, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0 . [all data]

Hammad and Wenthold, 2000
Hammad, L.A.; Wenthold, P.G., Synthesis, characterization, and reactivity of the m-xylylene anion in the gas phase. The enthalpy of formation of m-xylylene, J. Am. Chem. Soc., 2000, 122, 45, 11203-11211, https://doi.org/10.1021/ja002138n . [all data]

Guerrero, Herrero, et al., 2009
Guerrero, A.; Herrero, R.; Davalos, J.Z.; Koppel, I.; Abboud, J.L.M.; Chana, A.; Koppel, I.A., Hydrogen-Bonding Interactions of (CF3)(3)CH and (CF3)(3)C- in the Gas Phase. An Experimental (FT-ICR) and Computational Study, J. Phys. Chem. A, 2009, 113, 23, 6422-6429, https://doi.org/10.1021/jp811057m . [all data]

Lobring, Hao, et al., 2003
Lobring, K.C.; Hao, C.T.; Forbes, J.K.; Ivanov, M.R.J.; Bachrach, S.M.; Sunderlin, L.S., Bond strengths in ChCl(3)(-) and ChOCl(3)(-) (Ch = S, Se, Te): Experiment and theory, J. Phys. Chem. A, 2003, 107, 50, 11153-11160, https://doi.org/10.1021/jp030388v . [all data]

Check, Lobring, et al., 2003
Check, C.E.; Lobring, K.C.; Keating, P.R.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of hypervalent phosphorus-halogen bonds, J. Phys. Chem. A, 2003, 107, 42, 8961-8967, https://doi.org/10.1021/jp030287x . [all data]

Boesl, Distelrath, et al., 2008
Boesl, U.; Distelrath, V.; Selzle, H., The weakly-bound complex Cl center dot N2O studied by high resolution photodetachment photoelectron spectroscopy, Phys. Chem. Chem. Phys., 2008, 10, 41, 6252-6257, https://doi.org/10.1039/b807992g . [all data]


Notes

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