Chlorine anion
- Formula: Cl-
- Molecular weight: 35.454
- IUPAC Standard InChI:
- InChI=1S/ClH/h1H/p-1
- Download the identifier in a file.
- IUPAC Standard InChIKey: VEXZGXHMUGYJMC-UHFFFAOYSA-M
- CAS Registry Number: 16887-00-6
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 250, reactions 251 to 300, reactions 301 to 314
- Options:
Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 36.654 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1982 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: Cl- + H2O = (Cl- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 5. | kcal/mol | AVG | N/A | Average of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19. ± 3. | cal/mol*K | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9. ± 4. | kcal/mol | AVG | N/A | Average of 9 values; Individual data points |
By formula: Cl- + CH4O = (Cl- CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17. ± 3. | kcal/mol | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.6 | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
![]() | 24.1 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 22.0 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 22.9 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 14.8 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.1 ± 0.8 | kcal/mol | AVG | N/A | Average of 10 values; Individual data points |
By formula: Cl- + HCl = (Cl- HCl)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.6 ± 1.0 | kcal/mol | N/A | Metz, Kitsopoulos, et al., 1988 | gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B |
![]() | 23.8 ± 2.0 | kcal/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B,M |
![]() | 23.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 23.70 ± 0.20 | kcal/mol | TDAs | Yamdagni and Kebarle, 1974 | gas phase; B,M |
![]() | 20.4 | kcal/mol | HPMS | Upschulte, Evans, et al., 1986 | gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.3 | cal/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Cl-)SO2; M |
![]() | 23.5 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1974 | gas phase; M |
![]() | 23.5 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 22.8 | cal/mol*K | N/A | Upschulte, Evans, et al., 1986 | gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1987 | gas phase; K = 0.60 for HCl..Cl- + DCL <=> DCl..Cl- + HCl, anchored to Larson and McMahon, 1984, 32; B |
![]() | 17.1 ± 2.6 | kcal/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B |
![]() | 16.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 16.70 ± 0.30 | kcal/mol | TDAs | Yamdagni and Kebarle, 1974 | gas phase; B |
![]() | 13.6 | kcal/mol | HPMS | Upschulte, Evans, et al., 1986 | gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M |
By formula: Cl- + O2S = (Cl- O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.2 ± 2.0 | kcal/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B,M |
![]() | 20.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B |
![]() | 22.2 ± 2.2 | kcal/mol | TDEq | Bohringer, Fahey, et al., 1984 | gas phase; Relative to HOH..Cl- in Keesee, Lee, et al., 1980; B,M |
![]() | 21.80 ± 0.20 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
![]() | 20.9 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.6 | cal/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
![]() | 24.1 | cal/mol*K | N/A | Bohringer, Fahey, et al., 1984 | gas phase; switching reaction(Cl-)H2O), Entropy change calculated or estimated; Keesee and Castleman, 1980; M |
![]() | 20.8 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 23.2 | cal/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.7 ± 2.0 | kcal/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B |
![]() | 14.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B |
![]() | 15.0 ± 1.6 | kcal/mol | TDEq | Bohringer, Fahey, et al., 1984 | gas phase; Relative to HOH..Cl- in Keesee, Lee, et al., 1980; B,M |
![]() | 14.80 ± 0.30 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
![]() | 14.7 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
14.2 | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; switching reaction(Cl-)H2O; M |
By formula: Cl- + C6H6 = (Cl- C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.00 ± 0.46 | kcal/mol | N/A | Tschurl, Ueberfluss, et al., 2007 | gas phase; B |
![]() | 9.4 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 9.90 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 8.7 | kcal/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
![]() | 10.4 | kcal/mol | PHPMS | Sunner, Nishizawa, et al., 1981 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.9 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 17. | cal/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
![]() | 17.1 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 22. | cal/mol*K | N/A | Sunner, Nishizawa, et al., 1981 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.0 ± 2.6 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 3.8 ± 1.6 | kcal/mol | IMRE | Chowdhury and Kebarle, 1986 | gas phase; B |
![]() | 4.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 3.80 | kcal/mol | IMRE | French, Ikuta, et al., 1982 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
3.6 | 300. | PHPMS | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
3.8 | 300. | PHPMS | Chowdhury and Kebarle, 1986 | gas phase; M |
3.8 | 300. | PHPMS | Sunner, Nishizawa, et al., 1981 | gas phase; Entropy change calculated or estimated; M |
By formula: (Cl- 2H2O) + H2O = (Cl-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12. ± 2. | kcal/mol | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.3 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 22.4 | cal/mol*K | HPMS | Keesee and Castleman, 1980 | gas phase; M |
![]() | 23.2 | cal/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.0 ± 0.5 | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
By formula: Cl- + C2H3N = (Cl- C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 2. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.7 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 15.7 | cal/mol*K | PHPMS | Yamabe, Furumiya, et al., 1986 | gas phase; M |
![]() | 14.3 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 14.3 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
![]() | 21.4 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.20 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 9.2 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 8.9 ± 2.6 | kcal/mol | TDAs | Yamabe, Furumiya, et al., 1986 | gas phase; B |
![]() | 10.10 ± 0.20 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 9.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Cl- H2O) + H2O = (Cl-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13. ± 1. | kcal/mol | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.4 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 20.5 | cal/mol*K | HPMS | Keesee and Castleman, 1980 | gas phase; M |
![]() | 20.8 | cal/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 6.50 | kcal/mol | TDAs | Keesee and Castleman, 1980 | gas phase; B |
![]() | 6.5 ± 1.4 | kcal/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 6.50 | kcal/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 6.7 | kcal/mol | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
By formula: Cl- + C4H10O = (Cl- C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 19. ± 4. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.4 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 24.0 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 23.4 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 27. | cal/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
![]() | 10.3 | cal/mol*K | N/A | Yamdagni and Kebarle, 1971 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.58 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 12.30 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 11.60 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 11.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 11.1 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
By formula: Cl- + C7H5NO = (Cl- C7H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35.1 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M,M |
![]() | 35.3 | kcal/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25. | cal/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
![]() | 28. | cal/mol*K | N/A | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 26. | cal/mol*K | N/A | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.3 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
24.7 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
26.2 | 300. | PHPMS | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
25.8 | 300. | PHPMS | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
By formula: Cl- + C3H6O = (Cl- C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14. ± 2. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.2 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 19.6 | cal/mol*K | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
![]() | 17.1 | cal/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 19.7 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.08 ± 0.20 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 7.30 | kcal/mol | TDAs | Hiraoka, Morise, et al., 1986 | gas phase; B |
![]() | 8.80 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 8.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 7.9 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B |
By formula: Cl- + CHCl3 = (Cl- CHCl3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B,M |
![]() | 19.5 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 18.10 | kcal/mol | Mobl | Giles and Grimsrud, 1993 | gas phase; B |
![]() | 18.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 19.10 ± 0.70 | kcal/mol | TDEq | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
![]() | 24.5 | cal/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; M |
![]() | 14.8 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1971 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11. ± 1. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
By formula: Cl- + C6H6O = (Cl- C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.0 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B,M |
![]() | 26.0 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B |
![]() | 27.4 | kcal/mol | PHPMS | Kebarle, 1977 | gas phase; M |
![]() | 26.5 | kcal/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
![]() | 19.4 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.0 | cal/mol*K | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
![]() | 25. | cal/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
![]() | 25. | cal/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
![]() | 15.5 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.2 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B |
![]() | 18.5 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B |
![]() | 14.8 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Cl- + C6H5Cl = (Cl- C6H5Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.00 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
![]() | 13.6 ± 1.0 | kcal/mol | IMRE | Larson and McMahon, 1984 | gas phase; B,B,M |
![]() | 12.6 | kcal/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. | cal/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
![]() | 16.5 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 22.4 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.10 ± 0.20 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 6.9 ± 1.0 | kcal/mol | IMRE | Larson and McMahon, 1984 | gas phase; B,B,M |
![]() | 6.50 | kcal/mol | TDEq | French, Ikuta, et al., 1982 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
6.6 | 300. | PHPMS | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
6.5 | 300. | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
By formula: (Cl- 3H2O) + H2O = (Cl-
4H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 9.70 | kcal/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 10.6 ± 0.3 | kcal/mol | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 10.90 ± 0.70 | kcal/mol | TDAs | Keesee and Castleman, 1980 | gas phase; B,M |
![]() | 11.1 ± 1.0 | kcal/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.7 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 24.8 | cal/mol*K | HPMS | Keesee and Castleman, 1980 | gas phase; M |
![]() | 25.8 | cal/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 3.50 | kcal/mol | TDAs | Keesee and Castleman, 1980 | gas phase; B |
![]() | 3.40 | kcal/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B |
![]() | 4.0 ± 2.0 | kcal/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: Cl- + CH3Cl = (Cl- CH3Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.4 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 11.7 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 12.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 8.60 ± 0.20 | kcal/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
![]() | 15.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.5 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 15.3 | cal/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.80 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 4.84 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 6.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 4.10 ± 0.50 | kcal/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B |
![]() | 10.8 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
By formula: Cl- + CH2O2 = (Cl- CH2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 27.4 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B,M |
![]() | 27.7 ± 2.1 | kcal/mol | CIDT | Walker and Sunderlin, 1999 | gas phase; B |
![]() | 25.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 37.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; In serious disagreement with other's values. Source of error not obvious.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.5 | cal/mol*K | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
![]() | 24.1 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 39.6 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.1 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B |
![]() | 18.4 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 25.4 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; In serious disagreement with other's values. Source of error not obvious.; B |
By formula: Cl- + C6H5ClO = (Cl- C6H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.6 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M |
![]() | 30.1 | kcal/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25. | cal/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
![]() | 26.3 | cal/mol*K | N/A | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.1 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
19.5 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
21.0 | 300. | PHPMS | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
By formula: Cl- + C6H5FO = (Cl- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 27.9 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M |
![]() | 28.6 | kcal/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25. | cal/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
![]() | 25.3 | cal/mol*K | N/A | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.6 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
18.0 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
19.3 | 300. | PHPMS | Cummings, French, et al., 1977 | gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
By formula: Cl- + C2H6O = (Cl- C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.90 ± 0.40 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 17.60 ± 0.50 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B,B,M |
![]() | 17.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.7 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 23.1 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.65 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 10.5 ± 2.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 10.5 ± 2.0 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B |
![]() | 10.4 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
10.0 | 295. | ICR | Riveros, 1974 | gas phase; switching reaction(Cl-)CH3OH; Riveros, Breda, et al., 1973; M |
By formula: (Cl- CH4O) + CH4O = (Cl-
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.10 ± 0.40 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 13.70 ± 0.20 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B,M |
![]() | 14.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 13.00 ± 0.70 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.2 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 22.0 | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
![]() | 19.4 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.30 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 7.10 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 6.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 7.20 ± 0.40 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
By formula: (Cl- 2CH4O) + CH4O = (Cl-
3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.50 ± 0.20 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 10.80 ± 0.30 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B,M |
![]() | 11.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 12.30 ± 0.60 | kcal/mol | N/A | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.9 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 22.7 | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
![]() | 23.6 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.06 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 4.00 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 4.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 5.20 ± 0.30 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
By formula: Cl- + C6H5NO2 = (Cl- C6H5NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.3 ± 1.0 | kcal/mol | TDAs | Chowdhury and Kebarle, 1986 | gas phase; B,M |
![]() | 16.5 | kcal/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. | cal/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
![]() | 19.4 | cal/mol*K | PHPMS | Chowdhury and Kebarle, 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.5 ± 1.6 | kcal/mol | TDAs | Chowdhury and Kebarle, 1986 | gas phase; B |
![]() | 7.10 | kcal/mol | TDEq | French, Ikuta, et al., 1982 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
10.5 | 300. | PHPMS | Paul and Kebarle, 1991 | gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M |
7.7 | 300. | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
By formula: Cl- + C6H15B = (Cl- C6H15B)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
![]() | 23.8 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M |
![]() | 22.0 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
![]() | 17.2 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 333.40 | kcal/mol | N/A | Martin and Hepburn, 1998 | gas phase; Given: «DELTA»Hacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol; B |
![]() | 333.6 ± 2.1 | kcal/mol | G+TS | Fujio, McIver, et al., 1981 | gas phase; value altered from reference due to change in acidity scale; B |
![]() | 329.10 | kcal/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeCC-(q); ; «DELTA»S(EA)=5.0; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 328.10 ± 0.10 | kcal/mol | H-TS | Martin and Hepburn, 1998 | gas phase; Given: «DELTA»Hacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol; B |
![]() | 328.3 ± 2.0 | kcal/mol | IMRE | Fujio, McIver, et al., 1981 | gas phase; value altered from reference due to change in acidity scale; B |
![]() | 323.70 | kcal/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeCC-(q); ; «DELTA»S(EA)=5.0; B |
By formula: Cl- + C2H4O2 = (Cl- C2H4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 24.40 ± 0.20 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
![]() | 21.6 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B,M |
![]() | 23.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.6 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 24.0 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 19.3 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.60 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 15.8 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
![]() | 16.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + H3N = (Cl- H3N)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | <7.30 ± 0.40 | kcal/mol | N/A | Tschurl and Boesl, 2008 | gas phase; B |
![]() | 8.20 ± 0.10 | kcal/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B,M |
![]() | 8.9 ± 1.2 | kcal/mol | N/A | Markovich, Chesnovsky, et al., 1993 | gas phase; B |
![]() | 10.5 ± 4.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.4 | cal/mol*K | HPMS | Evans, Keesee, et al., 1987 | gas phase; M |
![]() | 19.9 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3F, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.60 ± 0.20 | kcal/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B |
![]() | 4.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C7H8O = (Cl- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 25.6 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M |
![]() | 25.9 | kcal/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25. | cal/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
![]() | 26.7 | cal/mol*K | PHPMS | Cummings, French, et al., 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.9 ± 2.0 | kcal/mol | TDEq | Cummings, French, et al., 1977 | gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15.3 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
16.6 | 300. | PHPMS | Cummings, French, et al., 1977 | gas phase; M |
By formula: Cl- + C3H8O = (Cl- C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 19.40 ± 0.20 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 18.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 17.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.7 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 23.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.32 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 10.90 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 10.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: (Cl- 6H2O) + H2O = (Cl-
7H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
![]() | 6.90 | kcal/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 8.1 | kcal/mol | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. | cal/mol*K | N/A | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
By formula: Cl- + CH2Cl2 = (Cl- CH2Cl2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 14.8 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 15.50 ± 0.30 | kcal/mol | TDEq | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.1 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M |
![]() | 22.0 | cal/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 8.84 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 8.90 ± 0.60 | kcal/mol | TDEq | Dougherty, Dalton, et al., 1974 | gas phase; B |
By formula: Cl- + F3P = (Cl- F3P)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B |
![]() | 15.5 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.0 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B |
![]() | 9.2 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
By formula: Cl- + C3H8O = (Cl- C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20.40 ± 0.50 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B,B,M |
![]() | 17.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.0 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 23.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.70 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 11.7 ± 2.0 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B |
![]() | 10.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + CHN = (Cl- CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21.8 ± 1.0 | kcal/mol | TDAs | Meot-ner, 1988 | gas phase; B,B,M |
![]() | 21.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.9 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
![]() | 23.7 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.2 ± 1.6 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
![]() | 16.1 ± 1.0 | kcal/mol | TDAs | Meot-ner, 1988 | gas phase; B |
![]() | 13.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + CO2 = (Cl- CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.80 ± 0.50 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B |
![]() | 7.60 | kcal/mol | TDEq | Hiraoka, Shoda, et al., 1986 | gas phase; B,M |
![]() | 8.00 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.2 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
![]() | 19.6 | cal/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.10 | kcal/mol | TDEq | Hiraoka, Shoda, et al., 1986 | gas phase; B |
![]() | 2.10 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: (Cl- 3CH4O) + CH4O = (Cl-
4CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 10.50 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 11.20 ± 0.60 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.9 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 26.4 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 3.70 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 3.30 ± 0.20 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
By formula: (Cl- 4H2O) + H2O = (Cl-
5H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 6.70 | kcal/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 9.5 ± 0.3 | kcal/mol | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.7 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 2.9 ± 2.0 | kcal/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: Cl- + C3F6O = (Cl- C3F6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.8 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 22.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.6 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 16.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
![]() | 16.3 | kcal/mol | ICR | Larson and McMahon, 1984, 3 | gas phase; switching reaction(Cl-)(C2H5)3B; M |
By formula: (Cl- 3C2H3N) + C2H3N = (Cl-
4C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.90 ± 0.30 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 9.00 ± 0.80 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 6.20 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.6 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 10.8 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.9 ± 1.2 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 3.00 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: Cl- + C3HF5O = (Cl- C3HF5O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.1 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 23.4 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.9 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.2 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 16.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 3 | gas phase; B,M,M |
By formula: Cl- + C3H2F6O = (Cl- C3H2F6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.5 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.0 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
By formula: (Cl- 2C2H3N) + C2H3N = (Cl-
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.20 ± 0.40 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 12.00 ± 0.70 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 10.60 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.6 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 20.1 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.3 ± 1.3 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 4.60 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: Cl- + CS2 = (Cl- CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.80 ± 0.20 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
![]() | 11.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13.9 | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
![]() | 20. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.6 ± 2.2 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
![]() | 5.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
By formula: (Cl- C2H3N) + C2H3N = (Cl-
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.50 ± 0.40 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 12.00 ± 0.70 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 12.20 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.3 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 18.9 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.6 ± 1.2 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 6.60 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: Cl- + C4H4F6O = (Cl- C4H4F6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.5 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.0 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
By formula: (Cl- 5H2O) + H2O = (Cl-
6H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 8.50 | kcal/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 8.8 ± 0.4 | kcal/mol | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.2 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: Cl- + CH3Br = (Cl- CH3Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.5 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 10.90 ± 0.50 | kcal/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B,M |
![]() | 12.2 ± 3.0 | kcal/mol | IMRB | Riveros, Breda, et al., 1973 | gas phase; Anchored: Larson and McMahon, 1984, 3; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 12.8 | cal/mol*K | HPMS | Dougherty and Roberts, 1974 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.80 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 7.1 ± 1.2 | kcal/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B |
By formula: (Cl- HCl) + HCl = (Cl-
2HCl)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.20 ± 0.20 | kcal/mol | TDAs | Yamdagni and Kebarle, 1974 | gas phase; B,M |
![]() | 14.0 | kcal/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Cl- HCl)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.4 | cal/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Cl- HCl)SO2; M |
![]() | 24.4 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.90 ± 0.20 | kcal/mol | TDAs | Yamdagni and Kebarle, 1974 | gas phase; B |
By formula: Cl- + Cl4Th = (Cl- Cl4Th)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 24.2 | kcal/mol | ICR | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.6 | kcal/mol | ICR | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M |
By formula: Cl- + C2H3ClO2 = (Cl- C2H3ClO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.1 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.0 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.8 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 333.40 | kcal/mol | N/A | Martin and Hepburn, 1998 | gas phase; Given: «DELTA»Hacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol |
![]() | 333.6 ± 2.1 | kcal/mol | G+TS | Fujio, McIver, et al., 1981 | gas phase; value altered from reference due to change in acidity scale |
![]() | 329.10 | kcal/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeCC-(q); ; «DELTA»S(EA)=5.0 |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 328.10 ± 0.10 | kcal/mol | H-TS | Martin and Hepburn, 1998 | gas phase; Given: «DELTA»Hacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol |
![]() | 328.3 ± 2.0 | kcal/mol | IMRE | Fujio, McIver, et al., 1981 | gas phase; value altered from reference due to change in acidity scale |
![]() | 323.70 | kcal/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeCC-(q); ; «DELTA»S(EA)=5.0 |
Ion clustering data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
= C4HClF9-
By formula: Cl- = C4HClF9-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.50 ± 0.30 | kcal/mol | IMRE | Guerrero, Herrero, et al., 2009 | gas phase; B |
= C5H10Cl-
By formula: Cl- = C5H10Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.51 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.61 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= C5H12Cl-
By formula: Cl- = C5H12Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.96 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.61 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= C6H12Cl-
By formula: Cl- = C6H12Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.56 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.00 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= C6H14Cl-
By formula: Cl- = C6H14Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.18 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.20 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= C7H14Cl-
By formula: Cl- = C7H14Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.52 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.54 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= C7H16Cl-
By formula: Cl- = C7H16Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.52 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.60 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= C8H8Cl-
By formula: Cl- = C8H8Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20.1 ± 1.6 | kcal/mol | CIDT | Hammad and Wenthold, 2000 | gas phase; B |
= C8H16Cl-
By formula: Cl- = C8H16Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.52 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.25 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= C8H18Cl-
By formula: Cl- = C8H18Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.74 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.47 | kcal/mol | N/A | Ziegler, Gamble, et al., 2013 | gas phase; B |
= ClN2O-
By formula: Cl- = ClN2O-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.50 ± 0.10 | kcal/mol | N/A | Boesl, Distelrath, et al., 2008 | gas phase; B |
By formula: Cl- + AlClF2 = (Cl- AlClF2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.3 ± 2.9 | kcal/mol | TDAs | Pervova, Korobov, et al., 1992 | gas phase; Thermo at 0K, experiments at 800-1100K. See also AlCl2F..F-; value altered from reference due to conversion from electron convention to ion convention; B |
By formula: Cl- + AlCl2F = (Cl- AlCl2F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 75.3 ± 2.9 | kcal/mol | TDAs | Pervova, Korobov, et al., 1992 | gas phase; Thermo at 0K, experiemnts at 800-1100K. See also AlCl3..F-; value altered from reference due to conversion from electron convention to ion convention; B |
By formula: Cl- + AlCl3 = (Cl- AlCl3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 76.7 ± 2.9 | kcal/mol | TDAs | Pervova, Korobov, et al., 1992 | gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B |
By formula: Cl- + AlF3 = (Cl- AlF3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.3 ± 2.9 | kcal/mol | TDAs | Pervova, Korobov, et al., 1992 | gas phase; Thermo at 0K, experiment at 800-1100 K. See also AlClF2..F-; value altered from reference due to conversion from electron convention to ion convention; B |
+
= AsCl4-
By formula: Cl- + AsCl3 = AsCl4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 27.5 ± 1.7 | kcal/mol | CIDT | Walker, Check, et al., 2002 | gas phase; B |
By formula: Cl- + AsF3 = (Cl- AsF3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 25.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
By formula: Cl- + BCl3 = (Cl- BCl3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 69.0 ± 2.0 | kcal/mol | Ther | Krivtsov, Titova, et al., 1977 | gas phase; Halide affinities from this reference are too high. G3MP2B3 calculations indicate an dHaff ca. 46 kcal/mol; value altered from reference due to conversion from electron convention to ion convention; B |
By formula: Cl- + BF3 = (Cl- BF3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
By formula: Cl- + BiCl3 = BiCl4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36.6 ± 3.6 | kcal/mol | CIDT | Walker, Check, et al., 2002 | gas phase; B |
+
= CBrClF3-
By formula: Cl- + CBrF3 = CBrClF3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.50 ± 0.20 | kcal/mol | TDAs | Bogdanov and McMahon, 2006 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.20 | kcal/mol | TDAs | Bogdanov and McMahon, 2006 | gas phase; B |
By formula: Cl- + CCl2O = (Cl- CCl2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
By formula: Cl- + CCl4 = (Cl- CCl4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.4 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 14.20 ± 0.70 | kcal/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.8 | cal/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.05 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 5.90 ± 0.90 | kcal/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B |
By formula: Cl- + CF2O = (Cl- CF2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
+
= CClF3I-
By formula: Cl- + CF3I = CClF3I-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23.60 ± 0.20 | kcal/mol | TDAs | Bogdanov and McMahon, 2006 | gas phase; B |
By formula: Cl- + CHClF2 = (Cl- CHClF2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + CHCl2F = (Cl- CHCl2F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.1 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + CHCl3 = (Cl- CHCl3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B,M |
![]() | 19.5 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 18.10 | kcal/mol | Mobl | Giles and Grimsrud, 1993 | gas phase; B |
![]() | 18.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 19.10 ± 0.70 | kcal/mol | TDEq | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
![]() | 24.5 | cal/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; M |
![]() | 14.8 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1971 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11. ± 1. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
By formula: Cl- + CHF3 = (Cl- CHF3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.7 ± 2.4 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.9 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + CHN = (Cl- CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21.8 ± 1.0 | kcal/mol | TDAs | Meot-ner, 1988 | gas phase; B,B,M |
![]() | 21.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.9 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
![]() | 23.7 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.2 ± 1.6 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
![]() | 16.1 ± 1.0 | kcal/mol | TDAs | Meot-ner, 1988 | gas phase; B |
![]() | 13.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: (Cl- CHN) + CHN = (Cl-
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.9 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.7 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.10 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Cl- 2CHN) + CHN = (Cl-
3CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.6 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.4 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.20 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Cl- 3CHN) + CHN = (Cl-
4CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.2 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.4 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.20 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Cl- 4CHN) + CHN = (Cl-
5CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.8 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.3 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.50 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Cl- 5CHN) + CHN = (Cl-
6CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.7 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.3 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.50 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Cl- 6CHN) + CHN = (Cl-
7CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.9 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.1 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.00 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Cl- 7CHN) + CHN = (Cl-
8CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.2 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.4 | cal/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.0 ± 2.2 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Cl- 8CHN) + CHN = (Cl-
9CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 1.0 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; Entropy estimated; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25. | cal/mol*K | N/A | Meot-ner, Cybulski, et al., 1988 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.10 | kcal/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; Entropy estimated; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
3.2 | 171. | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; Entropy change calculated or estimated; M |
By formula: Cl- + CH2Cl2 = (Cl- CH2Cl2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 14.8 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 15.50 ± 0.30 | kcal/mol | TDEq | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.1 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M |
![]() | 22.0 | cal/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 8.84 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 8.90 ± 0.60 | kcal/mol | TDEq | Dougherty, Dalton, et al., 1974 | gas phase; B |
By formula: Cl- + CH2O2 = (Cl- CH2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 27.4 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B,M |
![]() | 27.7 ± 2.1 | kcal/mol | CIDT | Walker and Sunderlin, 1999 | gas phase; B |
![]() | 25.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 37.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; In serious disagreement with other's values. Source of error not obvious.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.5 | cal/mol*K | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
![]() | 24.1 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 39.6 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.1 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B |
![]() | 18.4 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 25.4 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; In serious disagreement with other's values. Source of error not obvious.; B |
By formula: (Cl- CH2O2) + CH2O2 = (Cl-
2CH2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.2 ± 2.1 | kcal/mol | CIDT | Walker and Sunderlin, 1999 | gas phase; B |
![]() | 34.1 ± 3.1 | kcal/mol | N/A | Luczynski, Wlodek, et al., 1978 | gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 55. | cal/mol*K | HPMS | Luczynski, Wlodek, et al., 1978 | gas phase; Entropy change is questionable; M |
By formula: (Cl- 2CH2O2) + CH2O2 = (Cl-
3CH2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.2 ± 2.7 | kcal/mol | N/A | Luczynski, Wlodek, et al., 1978 | gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 35. | cal/mol*K | HPMS | Luczynski, Wlodek, et al., 1978 | gas phase; Entropy change is questionable; M |
By formula: (Cl- 3CH2O2) + CH2O2 = (Cl-
4CH2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.1 ± 2.2 | kcal/mol | N/A | Luczynski, Wlodek, et al., 1978 | gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. | cal/mol*K | HPMS | Luczynski, Wlodek, et al., 1978 | gas phase; M |
By formula: (Cl- 4CH2O2) + CH2O2 = (Cl-
5CH2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.1 ± 2.0 | kcal/mol | N/A | Luczynski, Wlodek, et al., 1978 | gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.5 | cal/mol*K | HPMS | Luczynski, Wlodek, et al., 1978 | gas phase; Entropy change is questionable; M |
By formula: Cl- + CH3Br = (Cl- CH3Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.5 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 10.90 ± 0.50 | kcal/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B,M |
![]() | 12.2 ± 3.0 | kcal/mol | IMRB | Riveros, Breda, et al., 1973 | gas phase; Anchored: Larson and McMahon, 1984, 3; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 12.8 | cal/mol*K | HPMS | Dougherty and Roberts, 1974 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.80 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 7.1 ± 1.2 | kcal/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B |
By formula: Cl- + CH3Cl = (Cl- CH3Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.4 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 11.7 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 12.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 8.60 ± 0.20 | kcal/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
![]() | 15.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.5 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 15.3 | cal/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.80 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 4.84 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
![]() | 6.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 4.10 ± 0.50 | kcal/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B |
![]() | 10.8 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
By formula: Cl- + CH3F = (Cl- CH3F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.3 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.4 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
By formula: Cl- + CH3F3Si = (Cl- CH3F3Si)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
By formula: Cl- + CH3I = (Cl- CH3I)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.80 ± 0.20 | kcal/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.3 | cal/mol*K | HPMS | Dougherty and Roberts, 1974 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.0 ± 1.3 | kcal/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B |
By formula: Cl- + CH3NO2 = (Cl- CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.60 ± 0.60 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
![]() | 16.70 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
![]() | 16.3 ± 3.0 | kcal/mol | IMRB | Riveros, Breda, et al., 1973 | gas phase; Anchored: Larson and McMahon, 1984, 3; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.1 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.20 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
![]() | 11.60 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
By formula: (Cl- CH3NO2) + CH3NO2 = (Cl-
2CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.00 ± 0.50 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
![]() | 13.10 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.3 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.70 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
![]() | 7.60 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
By formula: Cl- + CH4O = (Cl- CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17. ± 3. | kcal/mol | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.6 | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
![]() | 24.1 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 22.0 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 22.9 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 14.8 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.1 ± 0.8 | kcal/mol | AVG | N/A | Average of 10 values; Individual data points |
By formula: (Cl- CH4O) + CH4O = (Cl-
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.10 ± 0.40 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 13.70 ± 0.20 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B,M |
![]() | 14.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 13.00 ± 0.70 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.2 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 22.0 | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
![]() | 19.4 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.30 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 7.10 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 6.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 7.20 ± 0.40 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
By formula: (Cl- 2CH4O) + CH4O = (Cl-
3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.50 ± 0.20 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 10.80 ± 0.30 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B,M |
![]() | 11.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 12.30 ± 0.60 | kcal/mol | N/A | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.9 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 22.7 | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
![]() | 23.6 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.06 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 4.00 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 4.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 5.20 ± 0.30 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
By formula: (Cl- 3CH4O) + CH4O = (Cl-
4CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 10.50 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 11.20 ± 0.60 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.9 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 26.4 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 3.70 | kcal/mol | TDAs | Evans and Keesee, 1991 | gas phase; B |
![]() | 3.30 ± 0.20 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
By formula: (Cl- 4CH4O) + CH4O = (Cl-
5CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 10.50 ± 0.50 | kcal/mol | N/A | Yamdagni, Payzant, et al., 1973 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.7 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 25.5 | cal/mol*K | PHPMS | Yamdagni, Payzant, et al., 1973 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 2.90 ± 0.10 | kcal/mol | TDAs | Yamdagni, Payzant, et al., 1973 | gas phase; B |
By formula: (Cl- 5CH4O) + CH4O = (Cl-
6CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.2 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 6CH4O) + CH4O = (Cl-
7CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.1 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 7CH4O) + CH4O = (Cl-
8CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.7 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 8CH4O) + CH4O = (Cl-
9CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.6 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 9CH4O) + CH4O = (Cl-
10CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.1 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 10CH4O) + CH4O = (Cl-
11CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20. | cal/mol*K | N/A | Hiraoka and Mizuse, 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
By formula: (Cl- CH4O) + H2O = (Cl-
H2O
CH4O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.9 | kcal/mol | HPMS | Evans and Keesee, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.9 | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
By formula: (Cl- 2CH4O) + H2O = (Cl-
H2O
2CH4O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.7 | kcal/mol | HPMS | Evans and Keesee, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11. | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
By formula: (Cl- CH4O
H2O) + CH4O = (Cl-
2CH4O
H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.8 | kcal/mol | HPMS | Evans and Keesee, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19. | cal/mol*K | HPMS | Evans and Keesee, 1991 | gas phase; M |
By formula: Cl- + CH4S = (Cl- CH4S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.5 ± 3.0 | kcal/mol | IMRB | Staneke, Groothuis, et al., 1995 | gas phase; Chloride affinity comparable to that of CHCl3; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.8 ± 3.0 | kcal/mol | IMRB | Staneke, Groothuis, et al., 1995 | gas phase; Chloride affinity comparable to that of CHCl3; B |
+
= CH4Cl-
By formula: Cl- + CH4 = CH4Cl-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3.80 | kcal/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -2.16 | kcal/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
By formula: Cl- + CO2 = (Cl- CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.80 ± 0.50 | kcal/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B |
![]() | 7.60 | kcal/mol | TDEq | Hiraoka, Shoda, et al., 1986 | gas phase; B,M |
![]() | 8.00 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.2 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
![]() | 19.6 | cal/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.10 | kcal/mol | TDEq | Hiraoka, Shoda, et al., 1986 | gas phase; B |
![]() | 2.10 ± 0.10 | kcal/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: (Cl- CO2) + CO2 = (Cl-
2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.2 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
![]() | 7.20 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.8 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -1.4 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
![]() | 1.00 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B |
By formula: (Cl- 2CO2) + CO2 = (Cl-
3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.8 ± 1.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
![]() | 6.80 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.4 | cal/mol*K | PHPMS | Hiraoka, Shoda, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.1 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
![]() | 0.10 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; B |
By formula: (Cl- 3CO2) + CO2 = (Cl-
4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.40 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; entropy estimated.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24. | cal/mol*K | N/A | Hiraoka, Shoda, et al., 1986 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -0.80 | kcal/mol | TDAs | Hiraoka, Shoda, et al., 1986 | gas phase; entropy estimated.; B |
By formula: Cl- + CS2 = (Cl- CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.80 ± 0.20 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
![]() | 11.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13.9 | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
![]() | 20. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.6 ± 2.2 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
![]() | 5.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
By formula: (Cl- CS2) + CS2 = (Cl-
2CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.70 ± 0.20 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.8 | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.0 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
By formula: (Cl- 2CS2) + CS2 = (Cl-
3CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.20 ± 0.20 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.3 | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.8 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
By formula: (Cl- 3CS2) + CS2 = (Cl-
4CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.8 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; Estimated entropy; single temperature measurement; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -0.1 ± 1.0 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; Estimated entropy; single temperature measurement; B |
By formula: Cl- + C2ClF3O = (Cl- C2ClF3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
By formula: Cl- + C2F4O = (Cl- C2F4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
+
= C2ClF4-
By formula: Cl- + C2F4 = C2ClF4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | >10.00 | kcal/mol | TDAs | Hiraoka, Mochizuki, et al., 2008 | gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.55 | kcal/mol | TDAs | Hiraoka, Mochizuki, et al., 2008 | gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B |
By formula: Cl- + C2HF5O = (Cl- C2HF5O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.50 ± 0.40 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.3 ± 1.0 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
![]() | 12.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 3 | gas phase; B,M |
By formula: Cl- + C2HF5 = (Cl- C2HF5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.3 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H2F4O = (Cl- C2H2F4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.20 ± 0.40 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.8 ± 1.0 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
![]() | 17.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 3 | gas phase; B,M |
By formula: Cl- + C2H3ClO2 = (Cl- C2H3ClO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B |
By formula: Cl- + C2H3ClO2 = (Cl- C2H3ClO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.1 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.0 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.8 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
By formula: Cl- + C2H3F3O = (Cl- C2H3F3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 24.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H3F3 = (Cl- C2H3F3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.9 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.4 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
By formula: Cl- + C2H3N = (Cl- C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 2. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.7 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 15.7 | cal/mol*K | PHPMS | Yamabe, Furumiya, et al., 1986 | gas phase; M |
![]() | 14.3 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 14.3 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
![]() | 21.4 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.20 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 9.2 ± 2.0 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 8.9 ± 2.6 | kcal/mol | TDAs | Yamabe, Furumiya, et al., 1986 | gas phase; B |
![]() | 10.10 ± 0.20 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 9.2 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Cl- C2H3N) + C2H3N = (Cl-
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.50 ± 0.40 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 12.00 ± 0.70 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 12.20 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.3 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 18.9 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.6 ± 1.2 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 6.60 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Cl- 2C2H3N) + C2H3N = (Cl-
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.20 ± 0.40 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 12.00 ± 0.70 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 10.60 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.6 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 20.1 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.3 ± 1.3 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 4.60 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Cl- 3C2H3N) + C2H3N = (Cl-
4C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.90 ± 0.30 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 9.00 ± 0.80 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 6.20 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.6 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 10.8 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.9 ± 1.2 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 3.00 | kcal/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Cl- 4C2H3N) + C2H3N = (Cl-
5C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.80 ± 0.20 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 5.80 ± 0.90 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.1 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.70 ± 0.80 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: (Cl- 5C2H3N) + C2H3N = (Cl-
6C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.50 ± 0.20 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 5.8 ± 1.0 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.1 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.80 ± 0.80 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: (Cl- 6C2H3N) + C2H3N = (Cl-
7C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.40 ± 0.30 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 3.9 ± 1.1 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.7 | cal/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.2 ± 1.4 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: (Cl- 7C2H3N) + C2H3N = (Cl-
8C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.20 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy estimated; B,M |
![]() | 2.8 ± 1.2 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32. | cal/mol*K | N/A | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -0.40 | kcal/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy estimated; B |
By formula: (Cl- 8C2H3N) + C2H3N = (Cl-
9C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.4 ± 1.4 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Cl- 9C2H3N) + C2H3N = (Cl-
10C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2.1 ± 1.5 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Cl- 10C2H3N) + C2H3N = (Cl-
11C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 1.8 ± 1.6 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Cl- 11C2H3N) + C2H3N = (Cl-
12C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | -0.5 ± 1.7 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Cl- 12C2H3N) + C2H3N = (Cl-
13C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 0.9 ± 1.8 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (Cl- 13C2H3N) + C2H3N = (Cl-
14C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | -0.5 ± 1.9 | kcal/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: Cl- + C2H4F2 = (Cl- C2H4F2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.7 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H4F3N = (Cl- C2H4F3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H4O = (Cl- C2H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.4 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.7 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H4O2 = (Cl- C2H4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 24.40 ± 0.20 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
![]() | 21.6 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B,M |
![]() | 23.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.6 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 24.0 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 19.3 | cal/mol*K | PHPMS | Yamdagni and Kebarle, 1971 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.60 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 15.8 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
![]() | 16.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H5Br = (Cl- C2H5Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.6 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.92 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Cl- + C2H5ClO = (Cl- C2H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)FCH2CH2OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H5Cl = (Cl- C2H5Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.4 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 14.5 ± 4.5 | kcal/mol | IMRB | Riveros, Breda, et al., 1973 | gas phase; Anchored: Larson and McMahon, 1984, 3; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.80 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Cl- + C2H5FO = (Cl- C2H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C2H6OS = (Cl- C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.60 | kcal/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.4 | cal/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 12.50 | kcal/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B |
By formula: (Cl- C2H6OS) + C2H6OS = (Cl-
2C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.0 | kcal/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.8 | cal/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
By formula: (Cl- 2C2H6OS) + C2H6OS = (Cl-
3C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.9 | kcal/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.8 | cal/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
By formula: (Cl- 3C2H6OS) + C2H6OS = (Cl-
4C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.6 | kcal/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 37.2 | cal/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
By formula: (Cl- 4C2H6OS) + C2H6OS = (Cl-
5C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.8 | kcal/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 40.2 | cal/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
By formula: Cl- + C2H6O = (Cl- C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.90 ± 0.40 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 17.60 ± 0.50 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B,B,M |
![]() | 17.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.7 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 23.1 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.65 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 10.5 ± 2.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 10.5 ± 2.0 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B |
![]() | 10.4 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
10.0 | 295. | ICR | Riveros, 1974 | gas phase; switching reaction(Cl-)CH3OH; Riveros, Breda, et al., 1973; M |
By formula: (Cl- C2H6O) + C2H6O = (Cl-
2C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.30 ± 0.20 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 16.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.9 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.34 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 8.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 2C2H6O) + C2H6O = (Cl-
3C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.90 ± 0.70 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 12.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.8 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.16 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 5.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 3C2H6O) + C2H6O = (Cl-
4C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.5 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 4C2H6O) + C2H6O = (Cl-
5C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.6 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 5C2H6O) + C2H6O = (Cl-
6C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.0 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 6C2H6O) + C2H6O = (Cl-
7C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.9 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 7C2H6O) + C2H6O = (Cl-
8C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.2 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 8C2H6O) + C2H6O = (Cl-
9C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25. | cal/mol*K | N/A | Hiraoka and Mizuse, 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
By formula: (Cl- 9C2H6O) + C2H6O = (Cl-
10C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25. | cal/mol*K | N/A | Hiraoka and Mizuse, 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
+
= C2H6ClO-
By formula: Cl- + C2H6O = C2H6ClO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.50 ± 0.40 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.9 ± 1.0 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
By formula: Cl- + C2H6O2 = (Cl- C2H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 25.3 ± 1.0 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.6 ± 1.0 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
By formula: (Cl- C2H6O2) + C2H6O2 = (Cl-
2C2H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.9 ± 1.2 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.3 ± 1.0 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
By formula: Cl- + C3F6O = (Cl- C3F6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.8 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 22.9 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Larson and McMahon, 1985 | gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.6 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 16.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1985 | gas phase; B,M |
![]() | 16.3 | kcal/mol | ICR | Larson and McMahon, 1984, 3 | gas phase; switching reaction(Cl-)(C2H5)3B; M |
+
= C3ClF6-
By formula: Cl- + C3F6 = C3ClF6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.60 ± 0.30 | kcal/mol | TDAs | Hiraoka, Takao, et al., 2002 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.15 ± 0.30 | kcal/mol | TDAs | Hiraoka, Takao, et al., 2002 | gas phase; B |
By formula: Cl- + C3HF5O = (Cl- C3HF5O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.1 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 23.4 | kcal/mol | ICR | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.9 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.2 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 16.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 3 | gas phase; B,M,M |
By formula: Cl- + C3H2F4O = (Cl- C3H2F4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 3 | gas phase; B,M |
By formula: Cl- + C3H2F6O = (Cl- C3H2F6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.5 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.0 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
+ C3H3F3O- = C2H3ClF3O-
By formula: Cl- + C3H3F3O- = C2H3ClF3O-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.60 ± 0.40 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.7 ± 1.0 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
+
= C3H3ClF3O-
By formula: Cl- + C3H3F3O = C3H3ClF3O-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.7 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.2 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
+
= C3H5ClFO-
By formula: Cl- + C3H5FO = C3H5ClFO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.4 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.1 ± 1.0 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
By formula: Cl- + C3H6F2O = (Cl- C3H6F2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 23.6 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.1 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
By formula: Cl- + C3H6O = (Cl- C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14. ± 2. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.2 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 19.6 | cal/mol*K | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
![]() | 17.1 | cal/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
![]() | 19.7 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.08 ± 0.20 | kcal/mol | TDAs | Bofdanov and McMahon, 2002 | gas phase; B |
![]() | 7.30 | kcal/mol | TDAs | Hiraoka, Morise, et al., 1986 | gas phase; B |
![]() | 8.80 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 8.2 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 7.9 ± 2.0 | kcal/mol | TDAs | French, Ikuta, et al., 1982 | gas phase; B |
By formula: (Cl- C3H6O) + C3H6O = (Cl-
2C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.5 ± 1.0 | kcal/mol | TDAs | Hiraoka, Takimoto, et al., 1986 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.3 | cal/mol*K | PHPMS | Hiraoka, Takimoto, et al., 1986 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.4 ± 2.2 | kcal/mol | TDAs | Hiraoka, Takimoto, et al., 1986 | gas phase; B |
By formula: (Cl- 2C3H6O) + C3H6O = (Cl-
3C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.4 ± 2.0 | kcal/mol | TDAs | Hiraoka, Takimoto, et al., 1986 | gas phase; Entropy estimated; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. | cal/mol*K | N/A | Hiraoka, Takimoto, et al., 1986 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.8 ± 4.5 | kcal/mol | TDAs | Hiraoka, Takimoto, et al., 1986 | gas phase; Entropy estimated; B |
By formula: Cl- + C3H7Br = (Cl- C3H7Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.2 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.52 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Cl- + C3H7Br = (Cl- C3H7Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.2 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.24 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Cl- + C3H7Cl = (Cl- C3H7Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.7 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.80 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Cl- + C3H8O = (Cl- C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 19.40 ± 0.20 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 18.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
![]() | 17.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.7 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 23.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.32 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 10.90 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 10.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: (Cl- C3H8O) + C3H8O = (Cl-
2C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.70 ± 0.30 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 15.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.67 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 8.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 2C3H8O) + C3H8O = (Cl-
3C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.90 ± 0.50 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 12.5 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.1 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.30 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 4.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 3C3H8O) + C3H8O = (Cl-
4C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.7 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 4C3H8O) + C3H8O = (Cl-
5C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.5 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 5C3H8O) + C3H8O = (Cl-
6C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.1 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 6C3H8O) + C3H8O = (Cl-
7C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.1 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.3 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 7C3H8O) + C3H8O = (Cl-
8C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31. | cal/mol*K | N/A | Hiraoka and Mizuse, 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
By formula: Cl- + C3H8O = (Cl- C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20.40 ± 0.50 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B,B,M |
![]() | 17.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.0 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 23.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.70 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 11.7 ± 2.0 | kcal/mol | TDAs | Hiraoka, 1987 | gas phase; B |
![]() | 10.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: (Cl- C3H8O) + C3H8O = (Cl-
2C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.4 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 2C3H8O) + C3H8O = (Cl-
3C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.2 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 3C3H8O) + C3H8O = (Cl-
4C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32.1 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 4C3H8O) + C3H8O = (Cl-
5C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32.9 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 5C3H8O) + C3H8O = (Cl-
6C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.6 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.0 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 6C3H8O) + C3H8O = (Cl-
7C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.0 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.2 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 7C3H8O) + C3H8O = (Cl-
8C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30. | cal/mol*K | N/A | Hiraoka and Mizuse, 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
+ C3H9ClGe = C3H9Cl2Ge-
By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.2 ± 1.4 | kcal/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase; B |
+
= C3H9Cl2Si-
By formula: Cl- + C3H9ClSi = C3H9Cl2Si-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.3 ± 1.4 | kcal/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase; B |
+
= C3H9Cl2Sn-
By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31.3 ± 1.7 | kcal/mol | CIDT | Hao, Kaspar, et al., 2005 | gas phase; B |
By formula: Cl- + C4H4F6O = (Cl- C4H4F6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26.5 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.0 | kcal/mol | ICR | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984; M |
By formula: Cl- + C4H5N = (Cl- C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B |
![]() | 14.00 | kcal/mol | TDEq | French, Ikuta, et al., 1982 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
11.6 | 421. | PHPMS | French, Ikuta, et al., 1982 | gas phase; M |
By formula: Cl- + C4H6O2 = (Cl- C4H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.9 ± 1.1 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.0 ± 1.0 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
By formula: (Cl- C4H6O2) + C4H6O2 = (Cl-
2C4H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.30 ± 0.70 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.9 ± 1.0 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
By formula: Cl- + C4H8O = (Cl- C4H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.8 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.0 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)(CH3)2CO, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.5 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C4H8O2 = (Cl- C4H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.9 ± 1.5 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.7 ± 1.0 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
By formula: (Cl- C4H8O2) + C4H8O2 = (Cl-
2C4H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22.90 ± 0.40 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.7 ± 1.0 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
By formula: Cl- + C4H9Br = (Cl- C4H9Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.7 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.90 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Cl- + C4H9Cl = (Cl- C4H9Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.6 ± 1.0 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 14.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 21.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.30 ± 0.20 | kcal/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 8.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C4H9F = (Cl- C4H9F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13.3 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.8 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
+
= C4H10ClO-
By formula: Cl- + C4H10O = C4H10ClO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.00 ± 0.40 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.3 ± 1.0 | kcal/mol | TDAs | Bogdanov, Lee, et al., 2001 | gas phase; B |
By formula: Cl- + C4H10O = (Cl- C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.2 | cal/mol*K | N/A | Larson and McMahon, 1984, 2 | gas phase; switching reaction(Cl-)CH3OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.7 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
By formula: Cl- + C4H10O = (Cl- C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 19. ± 4. | kcal/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.4 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
![]() | 24.0 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
![]() | 23.4 | cal/mol*K | N/A | Larson and McMahon, 1984 | gas phase; Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
![]() | 27. | cal/mol*K | PHPMS | Kebarle, 1977 | gas phase; M |
![]() | 10.3 | cal/mol*K | N/A | Yamdagni and Kebarle, 1971 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.58 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 12.30 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
![]() | 11.60 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
![]() | 11.1 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1984, 2 | gas phase; B,M |
![]() | 11.1 ± 2.0 | kcal/mol | TDAs | Yamdagni and Kebarle, 1971 | gas phase; B |
By formula: (Cl- C4H10O) + C4H10O = (Cl-
2C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.90 ± 0.20 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 14.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.8 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.36 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 7.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 2C4H10O) + C4H10O = (Cl-
3C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.80 ± 0.30 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 13.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.0 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.07 | kcal/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 4.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 3C4H10O) + C4H10O = (Cl-
4C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12.7 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31.3 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3.3 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 4C4H10O) + C4H10O = (Cl-
5C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.9 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32.3 | cal/mol*K | PHPMS | Hiraoka and Mizuse, 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.2 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; B |
By formula: (Cl- 5C4H10O) + C4H10O = (Cl-
6C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11.4 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 32. | cal/mol*K | N/A | Hiraoka and Mizuse, 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1.8 ± 1.0 | kcal/mol | TDAs | Hiraoka and Mizuse, 1987 | gas phase; Estimated entropy; single temperature measurement; B |
By formula: Cl- + C4H10O2 = (Cl- C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 30.2 ± 1.7 | kcal/mol | TDAs | Zhang, Beglinger, et al., 1995 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.5 ± 1.0 | kcal/mol |