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Cyclohexane, propyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101DB-1DB-1OV-101OV-101
Column length (m) 50.10.10.20.20.
Carrier gas HeHeHe  
Substrate      
Column diameter (mm) 0.30.250.250.50.5
Phase thickness (mum) 0.40.250.25  
Temperature (C) 110.140.60.150.180.
I 938.951.926.952.3962.1
ReferenceZhuravleva, 2000Beens, Tijssen, et al., 1998Beens, Tijssen, et al., 1998Cha and Lee, 1994Cha and Lee, 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryPacked
Active phase OV-101OV-1SE-30SE-30Squalane
Column length (m) 50.55.100.100.1.
Carrier gas  N2  He
Substrate     Chromaton N-AW-HMDS
Column diameter (mm) 0.300.210.50.5 
Phase thickness (mum)  0.35   
Temperature (C) 100.100.130.80.100.
I 936.936.4947.931.937.
ReferenceEngewald, Topalova, et al., 1987Anders, Anders, et al., 1985Bredael, 1982Bredael, 1982Nabivach and Kirilenko, 1980
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPackedPackedPacked
Active phase SqualaneSE-30SE-30SE-30SE-30
Column length (m) 100.6.16.16.16.1
Carrier gas Nitrogen or heliumN2N2N2N2
Substrate  Chrom WChrom WChrom WChrom W
Column diameter (mm) 0.25    
Phase thickness (mum)      
Temperature (C) 100.110.120.130.140.
I 940.934.938.942.945.
ReferenceRang, Orav, et al., 1977Mitra, Mohan, et al., 1974Mitra, Mohan, et al., 1974Mitra, Mohan, et al., 1974Mitra, Mohan, et al., 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-30SE-30SE-30SE-30SE-30
Column length (m) 6.16.16.16.16.1
Carrier gas H2H2H2H2H2
Substrate      
Column diameter (mm) 3.183.183.183.183.18
Phase thickness (mum)      
Temperature (C) 130.140.150.160.170.
I 943.946.948.950.952.
ReferenceMitra, Mohan, et al., 1974, 2Mitra, Mohan, et al., 1974, 2Mitra, Mohan, et al., 1974, 2Mitra, Mohan, et al., 1974, 2Mitra, Mohan, et al., 1974, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneVacuum Grease Oil (VM-4)Vacuum Grease Oil (VM-4)Vacuum Grease Oil (VM-4)
Column length (m) 50.50.   
Carrier gas N2N2   
Substrate Celite 545Celite 545   
Column diameter (mm) 0.30.3   
Phase thickness (mum)      
Temperature (C) 120.86.35.45.50.
I 944.932.925.928.930.
ReferenceAgrawal, Tesarík, et al., 1972Agrawal, Tesarík, et al., 1972Sidorov, Petrova, et al., 1972Sidorov, Petrova, et al., 1972Sidorov, Petrova, et al., 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedPackedCapillary
Active phase Vacuum Grease Oil (VM-4)Vacuum Grease Oil (VM-4)Vacuum Grease Oil (VM-4)SE-30Squalane
Column length (m)      
Carrier gas    N2 
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 58.68.35.130.70.
I 933.937.925.944.931.
ReferenceSidorov, Petrova, et al., 1972Sidorov, Petrova, et al., 1972Sidorov, Ivanova, et al., 1971Mitra and Saha, 1970Schomburg, 1966
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase Methyl Silicone
Column length (m)  
Carrier gas  
Substrate  
Column diameter (mm)  
Phase thickness (mum)  
Temperature (C) 130.
I 944.
ReferenceAntheaume and Guiochon, 1965
Comment MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zhuravleva, 2000
Zhuravleva, I.L., Evaluation of the polarity and boiling points of nitrogen-containing heterocyclic compounds by gas chromatography, Russ. Chem. Bull. (Engl. Transl.), 2000, 49, 2, 325-328, https://doi.org/10.1007/BF02494682 . [all data]

Beens, Tijssen, et al., 1998
Beens, J.; Tijssen, R.; Blomberg, J., Prediction of comprehensive two-dimensional gas chromatographic separations. A theoretical and practical exercise, J. Chromatogr. A, 1998, 822, 2, 233-251, https://doi.org/10.1016/S0021-9673(98)00649-9 . [all data]

Cha and Lee, 1994
Cha, K.-W.; Lee, D.-J., Prediction of retention indices of various compounds in gas-liquid chromatography, J. Korean Chem. Soc., 1994, 38, 2, 108-120, retrieved from http://journal.kcsnet.or.kr/publi/dh/dh94n2/108.pdf. [all data]

Engewald, Topalova, et al., 1987
Engewald, W.; Topalova, I.; Petsev, N.; Dimitrov, Chr., Structure-Retention Correlations of Hydrocarbons in GLC and GSC. Alkenylbenzenes, Chromatographia, 1987, 23, 8, 561-565, https://doi.org/10.1007/BF02324864 . [all data]

Anders, Anders, et al., 1985
Anders, G.; Anders, K.; Engewald, W., Identification of non-branched alkenylcycloalkanes with a terminal double bond from retention index increments, Chromatographia, 1985, 20, 2, 83-86, https://doi.org/10.1007/BF02280602 . [all data]

Bredael, 1982
Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610 . [all data]

Nabivach and Kirilenko, 1980
Nabivach, V.M.; Kirilenko, A.V., Relationship between the gas chromatographic behaviour and the molecular structure of hydrocarbon samples and various stationary phases. Part II. Correlation between the retention index, physicochemical properties and molecular structure, Chromatographia, 1980, 13, 2, 93-100, https://doi.org/10.1007/BF02263060 . [all data]

Rang, Orav, et al., 1977
Rang, S.; Orav, A.; Kuningas, K.; Eisen, O., Capillary Gas Chromatography of Monosubstituted Cyclopentenes and Cyclohexenes, Chromatographia, 1977, 10, 3, 115-122, https://doi.org/10.1007/BF02297862 . [all data]

Mitra, Mohan, et al., 1974
Mitra, G.D.; Mohan, G.; Sinha, A., Advances in the utilization of the retention index system for characterizing hydrocarbons in complex mixtures by gas chromatography, J. Chromatogr., 1974, 99, 215-230, https://doi.org/10.1016/S0021-9673(00)90857-4 . [all data]

Mitra, Mohan, et al., 1974, 2
Mitra, G.D.; Mohan, G.; Sinha, A., Gas chromatographic analysis of complex hydrocarbon mixtures, J. Chromatogr. A, 1974, 91, 633-648, https://doi.org/10.1016/S0021-9673(01)97944-0 . [all data]

Agrawal, Tesarík, et al., 1972
Agrawal, B.B.; Tesarík, K.; Janák, J., Gas chromatographic characterization of sulphur compounds in the 93-162° gasoline cut from Romashkino crude oil using Kováts retention indices, J. Chromatogr., 1972, 65, 1, 207-215, https://doi.org/10.1016/S0021-9673(00)86933-2 . [all data]

Sidorov, Petrova, et al., 1972
Sidorov, R.I.; Petrova, V.I.; Ivanova, M.P., Qualitative analysis of wide-boiling fraction C5-C10 with capillary chromatography in Processes in chromatographic columns. Vol.17, 1972, 14-25. [all data]

Sidorov, Ivanova, et al., 1971
Sidorov, R.I.; Ivanova, M.P.; Petrova, V.I., Temperature dependence of cycloalkane's retention and its using in identification of structure, Gazovaya Khromatografiya, 1971, 15, 18-26. [all data]

Mitra and Saha, 1970
Mitra, G.D.; Saha, N.C., Determination of Retention Indices of Saturated Hydrocarbons by Graphical Methods, J. Chromatogr. Sci., 1970, 8, 2, 95-102, https://doi.org/10.1093/chromsci/8.2.95 . [all data]

Schomburg, 1966
Schomburg, G., Gaschromatographische Retentionsdaten und struktur chemischer verbindungen. III. Alkylverzweigte und ungesättigte cyclische Kohlenwasserstoffe, J. Chromatogr., 1966, 23, 18-41, https://doi.org/10.1016/S0021-9673(01)98653-4 . [all data]

Antheaume and Guiochon, 1965
Antheaume, J.; Guiochon, G., Application de la chromatographie en phase gazeuse à l'étude de la composition des fractions moyennes d'un brut pétrolier, Bull. Soc. Chim. Fr., 1965, 2, 298-307. [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References