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Tetraphosphorus decaoxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.86 ± 0.24TDEqMavrin, Korobov, et al., 1991Adjusted to current value of EA(PO2-) from that used in ref.; value altered from reference due to change in acidity scale; B

Ionization energy determinations

IE (eV) Method Reference Comment
13.0 ± 0.5EISmoes and Drowart, 1973LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
PO+23.6 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
PO2+22.5 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P2O2+29.5 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
PO3+33.0 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P2O3+28.0 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P2O4+24.3 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P3O4+34.0 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P2O5+22.9 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P3O5+32.9 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P3O6+22.3 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P4O6+32.8 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P3O7+17.8 ± 0.5?EIMuenow, Uy, et al., 1970RDSH
P4O9+20.0 ± 0.5OEIMuenow, Uy, et al., 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mavrin, Korobov, et al., 1991
Mavrin, A.A.; Korobov, M.V.; Andreeva, T.E.; Sidorov, L.N., The Electron Affinity of P4O10, Zh. Fiz. Khim. SSSR, 1991, 65, 1711. [all data]

Smoes and Drowart, 1973
Smoes, S.; Drowart, J., Atomization energies of phosphorus oxides, Faraday Symp. Chem. Soc., 1973, 139. [all data]

Muenow, Uy, et al., 1970
Muenow, D.W.; Uy, O.M.; Margrave, J.L., Mass spectrometric studies of the vaporization of phosphorus oxides, J. Inorg. Nucl. Chem., 1970, 32, 3459. [all data]


Notes

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