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Vanadium anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

V- + Hydrogen cation = HV

By formula: V- + H+ = HV

Quantity Value Units Method Reference Comment
Deltar1421. ± 14.kJ/molG+TSSallans, Lane, et al., 1985gas phase
Deltar1426. ± 15.kJ/molAcidFeigerle, Corderman, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar1389. ± 13.kJ/molIMRBSallans, Lane, et al., 1985gas phase
Deltar1394. ± 22.kJ/molH-TSFeigerle, Corderman, et al., 1981gas phase

(V- bullet Benzene, fluoro-) + Benzene = (V- bullet Benzene bullet Benzene, fluoro-)

By formula: (V- bullet C6H5F) + C6H6 = (V- bullet C6H6 bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar10. ± 63.kJ/molN/AJudai, Hirano, et al., 1997gas phase

V- + Benzene, fluoro- = (V- bullet Benzene, fluoro-)

By formula: V- + C6H5F = (V- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar60. ± 16.kJ/molN/AJudai, Hirano, et al., 1997gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S., Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH, J. Am. Chem. Soc., 1985, 107, 4379. [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C., Binding Energies and Structure of Transition Metal Negative Ions, J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289 . [all data]

Judai, Hirano, et al., 1997
Judai, K.; Hirano, M.; Kawamata, H.; Yabushita, S.; Nakajima, A.; Kaya, K., Formation of Vanadium-Arene Complex Anions and Their Photoelectron Spectroscopy, Chem. Phys. Lett., 1997, 270, 1-2, 23, https://doi.org/10.1016/S0009-2614(97)00336-9 . [all data]


Notes

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