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Vanadium anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas110.77 ± 0.57kcal/molR-EAFeigerle, Corderman, et al., 1981B
Quantity Value Units Method Reference Comment
gas,1 bar43.843cal/mol*KReviewChase, 1998Data last reviewed in March, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

V- + Hydrogen cation = HV

By formula: V- + H+ = HV

Quantity Value Units Method Reference Comment
Deltar339.7 ± 3.4kcal/molG+TSSallans, Lane, et al., 1985gas phase
Deltar340.9 ± 3.7kcal/molAcidFeigerle, Corderman, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar332.0 ± 3.0kcal/molIMRBSallans, Lane, et al., 1985gas phase
Deltar333.1 ± 5.2kcal/molH-TSFeigerle, Corderman, et al., 1981gas phase

(V- bullet Benzene, fluoro-) + Benzene = (V- bullet Benzene bullet Benzene, fluoro-)

By formula: (V- bullet C6H5F) + C6H6 = (V- bullet C6H6 bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar3. ± 15.kcal/molN/AJudai, Hirano, et al., 1997gas phase

V- + Benzene, fluoro- = (V- bullet Benzene, fluoro-)

By formula: V- + C6H5F = (V- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar14.4 ± 3.8kcal/molN/AJudai, Hirano, et al., 1997gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

V- + Hydrogen cation = HV

By formula: V- + H+ = HV

Quantity Value Units Method Reference Comment
Deltar339.7 ± 3.4kcal/molG+TSSallans, Lane, et al., 1985gas phase
Deltar340.9 ± 3.7kcal/molAcidFeigerle, Corderman, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar332.0 ± 3.0kcal/molIMRBSallans, Lane, et al., 1985gas phase
Deltar333.1 ± 5.2kcal/molH-TSFeigerle, Corderman, et al., 1981gas phase

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

V- + Benzene, fluoro- = (V- bullet Benzene, fluoro-)

By formula: V- + C6H5F = (V- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar14.4 ± 3.8kcal/molN/AJudai, Hirano, et al., 1997gas phase

(V- bullet Benzene, fluoro-) + Benzene = (V- bullet Benzene bullet Benzene, fluoro-)

By formula: (V- bullet C6H5F) + C6H6 = (V- bullet C6H6 bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar3. ± 15.kcal/molN/AJudai, Hirano, et al., 1997gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C., Binding Energies and Structure of Transition Metal Negative Ions, J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289 . [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S., Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH, J. Am. Chem. Soc., 1985, 107, 4379. [all data]

Judai, Hirano, et al., 1997
Judai, K.; Hirano, M.; Kawamata, H.; Yabushita, S.; Nakajima, A.; Kaya, K., Formation of Vanadium-Arene Complex Anions and Their Photoelectron Spectroscopy, Chem. Phys. Lett., 1997, 270, 1-2, 23, https://doi.org/10.1016/S0009-2614(97)00336-9 . [all data]


Notes

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