2-Cyclohexen-1-ol, 3-methyl-6-(1-methylethyl)-, trans-
- Formula: C10H18O
- Molecular weight: 154.2493
- IUPAC Standard InChI: InChI=1S/C10H18O/c1-7(2)9-5-4-8(3)6-10(9)11/h6-7,9-11H,4-5H2,1-3H3/t9-,10+/m0/s1
- IUPAC Standard InChIKey: HPOHAUWWDDPHRS-VHSXEESVSA-N
- CAS Registry Number: 16721-39-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: (1R,6R)-6-Isopropyl-3-methylcyclohex-2-enol, rel-; p-Menth-1-en-3-ol, trans-; trans-p-Menth-1-en-3-ol; trans-Piperitol; 6-Isopropyl-3-methyl-2-cyclohexen-1-ol, (E)-; E-Piperitol; trans-3-methyl-6-(1-methylethyl)-2-cyclohexen-1-ol; 2-Cyclohexen-1-ol, 3-methyl-6-(1-methylethyl)-, (1R,6R)-rel-; Piperitol, trans-; trans-Pipertiol (=trans-p-Menth-1-en-3-ol); (E)-Piperitol acetate; Piperitol isomer; trans-Piperitol (trans-p-menth-1-en-3-ol); trans-piperitol (= trans- pmenth-1-en-3-ol); trans-6-(isopropyl)-3-methylcyclohex-2-en-1-ol
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
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Van Den Dool and Kratz RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5MS | BP-1 | HP-5 | CP Sil 5 CB | BP-1 |
| Column length (m) | 30. | 50. | 30. | 30. | 50. |
| Carrier gas | He | He | He | N2 | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.22 | 0.25 | 0.25 | 0.22 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 50. | 50. | 60. |
| Tend (C) | 250. | 220. | 250. | 200. | 220. |
| Heat rate (K/min) | 2. | 2. | 4. | 5. | 2. |
| Initial hold (min) | 8. | 4. | |||
| Final hold (min) | 30. | 20. | 10. | 20. | |
| I | 1208. | 1189. | 1208. | 1196. | 1191. |
| Reference | Benkaci-Ali, Baaliouamer, et al., 2007 | Lesueur, de Rocca Serra, et al., 2007 | Quijano, Salamanca, et al., 2007 | Andrianoelisoa H.S., Menut C., et al., 2006 | Gonny, Cavaleiro, et al., 2006 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5MS | RTX-1 | RTX-5 | DB-5 | HP-5 |
| Column length (m) | 30. | 60. | 30. | 30. | 30. |
| Carrier gas | He | He | He | N2 | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.22 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 45. | 60. | 60. |
| Tend (C) | 280. | 230. | 300. | 240. | 260. |
| Heat rate (K/min) | 3. | 2. | 3. | 3. | 3. |
| Initial hold (min) | 6. | ||||
| Final hold (min) | 35. | 10. | |||
| I | 1186. | 1189. | 1208. | 1208. | 1205. |
| Reference | Pavlovic, Kovacevic, et al., 2006 | Paolini, Costa, et al., 2005 | Dugo, Mondello, et al., 2004 | Flamini, Cioni, et al., 2004 | Javidnia, Miri, et al., 2004 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5MS | HP-5MS | HP-5 | HP-5 | DB-5 |
| Column length (m) | 30. | 30. | 25. | 50. | 30. |
| Carrier gas | He | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.2 | 0.2 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.33 | 0.2 | 0.25 |
| Tstart (C) | 40. | 50. | 60. | 40. | 60. |
| Tend (C) | 280. | 250. | 240. | 250. | 240. |
| Heat rate (K/min) | 4. | 3. | 3. | 3. | 3. |
| Initial hold (min) | 2. | 15. | |||
| Final hold (min) | 7. | 40. | |||
| I | 1211. | 1209. | 1208. | 1209. | 1208. |
| Reference | Mardarowicz, Wianowska, et al., 2004 | Salido, Valenzuela, et al., 2004 | Sartoratto, Machado, et al., 2004 | Stashenko, Jaramillo, et al., 2004 | Bader, Flamini, et al., 2003 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | RTX-5 | HP-5 | HP-5 | CP Sil 5 CB | HP-5 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | He | He | N2 | H2 | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 45. | 60. | 60. | 60. | 60. |
| Tend (C) | 250. | 280. | 220. | 280. | 280. |
| Heat rate (K/min) | 3. | 3. | 5. | 2. | 3. |
| Initial hold (min) | 6. | 10. | 10. | 5. | |
| Final hold (min) | 40. | ||||
| I | 1201. | 1208. | 1207. | 1180. | 1205. |
| Reference | Shellie, Marriott, et al., 2003 | Tsiri, Kretsi, et al., 2003 | Flamini, Cioni, et al., 2002 | Pino, Marbot, et al., 2002 | Aligiannis, Kalpoutzakis, et al., 2001 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | BP-1 | HP-5MS | HP-5 | OV-1 | BP-1 |
| Column length (m) | 50. | 30. | 30. | 25. | 50. |
| Carrier gas | He | He | He | ||
| Substrate | |||||
| Column diameter (mm) | 0.22 | 0.25 | 0.20 | 0.25 | 0.22 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.3 | 0.25 |
| Tstart (C) | 60. | 50. | 60. | 50. | 60. |
| Tend (C) | 220. | 250. | 180. | 200. | 230. |
| Heat rate (K/min) | 2. | 3. | 4. | 3. | 2. |
| Initial hold (min) | 8. | 1. | |||
| Final hold (min) | 20. | 2. | 20. | 35. | |
| I | 1187. | 1209. | 1193. | 1187. | 1183. |
| Reference | Rezzi, Cavaleiro, et al., 2001 | Salido, Altarejos, et al., 2001 | Alonzo, Bosco, et al., 2000 | Bicchi, Rubiolo, et al., 1998 | Mariotti, Costa, et al., 1997 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary |
|---|---|---|---|
| Active phase | Methyl Silicone | HP-101 | DB-5 |
| Column length (m) | 25. | 50. | 60. |
| Carrier gas | He | N2 | He |
| Substrate | |||
| Column diameter (mm) | 0.2 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.3 | 1. | |
| Tstart (C) | 40. | 70. | 40. |
| Tend (C) | 200. | 200. | 220. |
| Heat rate (K/min) | 2. | 3. | 3. |
| Initial hold (min) | |||
| Final hold (min) | |||
| I | 1203. | 1216. | 1202. |
| Reference | Píry, Príbela, et al., 1995 | Chung, Eiserich, et al., 1993 | Le Quere and Latrasse, 1990 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Benkaci-Ali, Baaliouamer, et al., 2007
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Chemical composition and antibacterial activity of the essential oil of Michelia foveolata Merryll ex Dandy from Vietnam,
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Quijano, Salamanca, et al., 2007
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Aroma volatile constituents of Colombian varieties of mango (Mangifera indica L.),
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Intraspecific chemical variability and highlighting of chemotypes of leaf essential oils from Ravensara aromatica Sonnerat a tree endemic to Madagascar,
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Gonny, Cavaleiro, et al., 2006
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Analysis of Juniperus communis subsp. alpina needle, berry, wood and root oils by combination of GC, GC/MS and 13C-NMR,
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Essential oil composition of Anthemis triumfetti (L.) DC.,
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Paolini, Costa, et al., 2005
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Analysis of the essential oil from aerial parts of Eupatorium cannabinum subsp. corsicum (L.) by gas chromatography with electron impact and chemical ionization mass spectrometry,
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The composition of the volatile fraction and the enantiomeric distribution of five volatile components of faustrime oil (Monocitrus australatica x Fortunella sp. x Citrus aurantifolia),
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Phytochemical typologies in some populations of Myrtus communis L. on Caprione Promontory (East Liguria, Italy),
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Javidnia, Miri, et al., 2004
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Analysis of the volatile constituents of Nepeta macrosiphon Boiss. grown in Iran,
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Sartoratto, Machado, et al., 2004
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Shellie, Marriott, et al., 2003
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Interactive use of linear retention indices on polar and apolar columns with an MS-Library for reliable characterization of Australian tea tree and other Melaleuca sp. oils,
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Tsiri, Kretsi, et al., 2003
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Composition of fruit volatiles and annual changes in the volatiles of leaves of Eucalyptus camaldulensis Dehn. growing in Greece,
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Flamini, Cioni, et al., 2002
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Chemical composition of the essential oil of Artemisia herba-alba Asso ssp. valentina (Lam.) Marcl.,
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Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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