tris(1,1,1-trifluoropentane-2,4-dionato-O,O')ruthenium
- Formula: C15H12F9O6Ru
- Molecular weight: 560.31
- CAS Registry Number: 16702-38-8
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 31.05 ± 0.24 | kcal/mol | ME | Ribeiro da Silva, Monte, et al., 2001 |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
31.4 ± 1.1 | 346. to 467. | ME | Morozova, Zherikova, et al., 2009 | |
30.31 ± 0.24 | 360. | ME | Ribeiro da Silva, Monte, et al., 2001 | Based on data from 350. to 369. K. |
21.5 ± 0.72 | 383. to 423. | N/A | Bykov, Morozova, et al., 1996 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ribeiro da Silva, Monte, et al., 2001
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Giera, Edward,
Thermodynamic study of the sublimation of crystalline tris(1,1,1-trifluoro-2,4-pentanedionate)ruthenium(III) and tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionate)ruthenium(III),
The Journal of Chemical Thermodynamics, 2001, 33, 4, 369-376, https://doi.org/10.1006/jcht.2000.0734
. [all data]
Morozova, Zherikova, et al., 2009
Morozova, N.B.; Zherikova, K.V.; Semyannikov, P.P.; Trubin, S.V.; Igumenov, I.K.,
Study of temperature dependencies of saturated vapor pressure of ruthenium(III) beta-diketonate derivatives,
J Therm Anal Calorim, 2009, 98, 2, 395-399, https://doi.org/10.1007/s10973-009-0309-8
. [all data]
Bykov, Morozova, et al., 1996
Bykov, A.F.; Morozova, N.B.; Igumenov, I.K.; Sysoev, S.V.,
Investigation of thermal properties of ruthenium(III) Β-diketonate precursors for preparation of RuO2 films by CVD,
Journal of Thermal Analysis, 1996, 46, 6, 1551-1565, https://doi.org/10.1007/BF01980761
. [all data]
Notes
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- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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