Cobalt ion (1+)
- Formula: Co+
- Molecular weight: 58.932646
- IUPAC Standard InChIKey: BFVNPAKTAJENJQ-UHFFFAOYSA-N
- CAS Registry Number: 16610-75-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Cobalt cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 51 to 73
- Ion clustering data
- Options:
Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
By formula: (Co+ 2CH4) + CH4 = (Co+
3CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Kemper, Bushnell, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. (+5.0,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
3. | 477. | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
By formula: Co+ + H2 = (Co+ H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82. ± 4. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(O K)=76.1 kJ/mol, «DELTA»rS(300 K)=86.2 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(O K)=76.1 kJ/mol, «DELTA»rS(300 K)=86.2 J/mol*K; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
73.2 (+9.6,-0.) | CID | Haynes and Armentrout, 1996 | gas phase; guided ion beam CID; M |
By formula: Co+ + CH4 = (Co+ CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.8 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(530 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
90.0 (+6.7,-0.) | CID | Haynes and Armentrout, 1996 | gas phase; guided ion beam CID; M | |
90.0 (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
94. (+2.,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(530 K); M |
By formula: (Co+ C6H6) + C6H6 = (Co+
2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 167. ± 14. | kJ/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 116. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(490 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
167. (+13.,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M | |
113. (+4.2,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(490 K); M |
By formula: Co+ + C2H6 = (Co+ C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 93.3 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
100. (+5.0,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
117. (+6.7,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M |
By formula: (Co+ 2He) + He = (Co+
3He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.5 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 5.10 kJ/mol, «DELTA»rS(100 K) = 46.4 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 48.5 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 5.10 kJ/mol, «DELTA»rS(100 K) = 46.4 J/mol*K; M |
By formula: (Co+ Ne) + Ne = (Co+
2Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.2 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH90 K) = 8.16 kJ/mol, «DELTA»rS(100 K) = 52.3 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 48.5 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH90 K) = 8.16 kJ/mol, «DELTA»rS(100 K) = 52.3 J/mol*K; M |
By formula: (Co+ He) + He = (Co+
2He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.4 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 14.3 kJ/mol, «DELTA»rS(100 K) = 79.9 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.0 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 14.3 kJ/mol, «DELTA»rS(100 K) = 79.9 J/mol*K; M |
By formula: Co+ + CO = (Co+ CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 174. ± 7.1 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
![]() | 160. ± 10. | kJ/mol | MKER | Carpenter, van Koppen, et al., 1995 | gas phase; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
174. (+6.7,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M | |
163. (+20.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + Ne = (Co+ Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.5 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 9.12 kJ/mol, «DELTA»rS(100 K) = 58.6 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 64.4 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 9.12 kJ/mol, «DELTA»rS(100 K) = 58.6 J/mol*K; M |
By formula: Co+ + He = (Co+ He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.9 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 12.6 kJ/mol, «DELTA»rS(100 K) = 61.5 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.5 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; «DELTA»rH(0 K) = 12.6 kJ/mol, «DELTA»rS(100 K) = 61.5 J/mol*K; M |
By formula: (Co+ CH4) + H2 = (Co+
H2
CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 95.8 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
73. (+3.,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
By formula: (Co+ H2) + CH4 = (Co+
CH4
H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 91.2 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
94.6 (+5.0,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
By formula: (Co+ H2) + H2 = (Co+
2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 75. ± 3. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=71.1 kJ/mol, «DELTA»rS(300 K)=103. J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=71.1 kJ/mol, «DELTA»rS(300 K)=103. J/mol*K; M |
By formula: (Co+ 2H2) + H2 = (Co+
3H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44. ± 2. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=85.8 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.8 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=85.8 J/mol*K; M |
By formula: (Co+ 3H2) + H2 = (Co+
4H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 44. ± 3. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=105. J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 101. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=40. kJ/mol, «DELTA»rS(300 K)=105. J/mol*K; M |
By formula: (Co+ 4H2) + H2 = (Co+
5H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. ± 3. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=18. kJ/mol, «DELTA»rS(300 K)=91.6 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.1 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=18. kJ/mol, «DELTA»rS(300 K)=91.6 J/mol*K; M |
By formula: (Co+ 5H2) + H2 = (Co+
6H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 20. ± 3. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=17. kJ/mol, «DELTA»rS(300 K)=99.6 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 99.2 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=17. kJ/mol, «DELTA»rS(300 K)=99.6 J/mol*K; M |
By formula: (Co+ 6H2) + H2 = (Co+
7H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6. ± 3. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=3. kJ/mol; «DELTA»rS(300 K)=75.3 J/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 75.3 | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; «DELTA»rH(0 K)=3. kJ/mol; «DELTA»rS(300 K)=75.3 J/mol*K; M |
By formula: (Co+ CH4) + CH4 = (Co+
2CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 109. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(500 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
95.8 (+5.0,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
104. (+4.2,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(500 K); M |
By formula: Co+ + C2H4 = (Co+ C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 186. ± 9.2 | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
179. (+7.1,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
27. (+13.,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; «DELTA»rH>=, guided ion beam CID; M |
By formula: (Co+ CO) + CO = (Co+
2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 153. ± 9.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
152. (+8.8,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M | |
138. (+20.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ CH4) + C2H6 = (Co+
C2H6
CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 108. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
119. (+5.4,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M |
By formula: Co+ + H2O = (Co+ H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 160. ± 10. | kJ/mol | CID | Magnera, David, et al., 1989 | gas phase; M |
![]() | 168. | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
161. (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ H2O) + H2 = (Co+
H2
H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 103. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(530 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
83. (+3.,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(530 K); M |
By formula: (Co+ H2O) + CH4 = (Co+
CH4
H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 113. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(525 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
108. (+3.,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(525 K); M |
By formula: (Co+ C2H6) + CH4 = (Co+
CH4
C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 110. | J/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(490 K); M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
102. (+4.6,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; «DELTA»rS(490 K); M |
By formula: Co+ + C3H6 = (Co+ C3H6)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
180. (+7.1,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
180. (+6.7,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ H2O) + H2O = (Co+
2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 175. | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
162. (+7.1,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + C2H2 = (Co+ C2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 180. ± 7.9 | kJ/mol | IRMPD | Surya, Ranatunga, et al., 1997 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
27. (+13.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; «DELTA»rH >=, guided ion beam CID; M |
By formula: (Co+ 2CO) + CO = (Co+
3CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82. ± 12. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
82. (+12.,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Co+ 3CO) + CO = (Co+
4CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.9 ± 5.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
75.3 (+5.9,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Co+ 4CO) + CO = (Co+
5CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 74.9 ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
75.3 (+5.0,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: Co+ + C6H6 = (Co+ C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 256. ± 11. | kJ/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
256. (+10.,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Co+ H3N) + H3N = (Co+
2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 248. ± 13. | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
![]() | 256. | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: Co+ + H3N = (Co+ H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 218. ± 15. | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
![]() | 246. | kJ/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: Co+ + CH3 = (Co+ CH3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 204. ± 13. | kJ/mol | CIDT | Fisher, Sunderlin, et al., 1989 | RCD |
![]() | 205. ± 15. | kJ/mol | CIDT | Georgiadis, Fisher, et al., 1989 | RCD |
By formula: Co+ + CS = (Co+ CS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 258. ± 33. | kJ/mol | CIDT | Rue, Armentrout, et al., 2001 | RCD |
![]() | 240. ± 9.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Co+ 2H2O) + H2O = (Co+
3H2O)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
64.9 (+5.0,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 3H2O) + H2O = (Co+
4H2O)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
58.2 (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + C3H4 = (Co+ C3H4)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
79.1 (+8.8,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; «DELTA»rH>=, guided ion beam CID; M |
By formula: (Co+ 3CH4) + CH4 = (Co+
4CH4)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.8 (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 10Co) + Co = (Co+
11Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
329. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 11Co) + Co = (Co+
12Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
351. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 12Co) + Co = (Co+
13Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
303. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 13Co) + Co = (Co+
14Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
380. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 14Co) + Co = (Co+
15Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
355. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 15Co) + Co = (Co+
16Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
346. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 16Co) + Co = (Co+
17Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
371. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ 9Co) + Co = (Co+
10Co)
Enthalpy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
314. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T.,
Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters,
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. [all data]
Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L.,
Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]
Kemper, Bushnell, et al., 1993, 2
Kemper, P.R.; Bushnell, J.; Von Helden, G.; Bowers, M.T.,
Co+(H2)n Clusters: Binding Energies and Molecular Parameters,
J. Chem Phys., 1993, 97, 1, 52, https://doi.org/10.1021/j100103a012
. [all data]
Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B.,
Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy,
Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7
. [all data]
Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B.,
Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu,
J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018
. [all data]
Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T.,
Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar),
J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T.,
Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone,
J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021
. [all data]
Goebel, Haynes, et al., 1995
Goebel, S.; Haynes, C.L.; Khan, F.A.; Armentrout, P.B.,
Collision-Induced Dissociation Studies of Co(CO)x, x = 1-5: Sequential Bond Energies and the Heat of Formation of Co(CO)4,
J. Am. Chem. Soc., 1995, 117, 26, 6994, https://doi.org/10.1021/ja00131a023
. [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B.,
Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes,
J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z
. [all data]
Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B.,
Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers,
Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022
. [all data]
Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J.,
Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051
. [all data]
Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R.,
Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052
. [all data]
Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S.,
Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4),
J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c
. [all data]
Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B.,
Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD,
J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c
. [all data]
Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B.,
Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies,
J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026
. [all data]
Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B.,
Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane,
J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016
. [all data]
Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H.,
Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS,
J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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