Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Cobalt ion (1+)


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(Cobalt ion (1+) bullet 2Methane) + Methane = (Cobalt ion (1+) bullet 3Methane)

By formula: (Co+ bullet 2CH4) + CH4 = (Co+ bullet 3CH4)

Quantity Value Units Method Reference Comment
Deltar11.kcal/molSIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
9.8 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
0.7477.SIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Cobalt ion (1+) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen)

By formula: Co+ + H2 = (Co+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar20. ± 1.kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(O K)=18.2 kcal/mol, «DELTA»rS(300 K)=20.6 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(O K)=18.2 kcal/mol, «DELTA»rS(300 K)=20.6 cal/mol*K; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.5 (+2.3,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M

Cobalt ion (1+) + Methane = (Cobalt ion (1+) bullet Methane)

By formula: Co+ + CH4 = (Co+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar19.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
21.5 (+1.6,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M
21.5 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
22.5 (+0.5,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

(Cobalt ion (1+) bullet Benzene) + Benzene = (Cobalt ion (1+) bullet 2Benzene)

By formula: (Co+ bullet C6H6) + C6H6 = (Co+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar39.9 ± 3.3kcal/molCIDTMeyer, Khan, et al., 1995RCD
Quantity Value Units Method Reference Comment
Deltar27.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
39.9 (+3.2,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M
27.0 (+1.0,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Cobalt ion (1+) + Ethane = (Cobalt ion (1+) bullet Ethane)

By formula: Co+ + C2H6 = (Co+ bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
23.9 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
28.0 (+1.6,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

(Cobalt ion (1+) bullet 2helium) + helium = (Cobalt ion (1+) bullet 3helium)

By formula: (Co+ bullet 2He) + He = (Co+ bullet 3He)

Quantity Value Units Method Reference Comment
Deltar1.3 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 1.22 kcal/mol, «DELTA»rS(100 K) = 11.1 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar11.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 1.22 kcal/mol, «DELTA»rS(100 K) = 11.1 cal/mol*K; M

(Cobalt ion (1+) bullet neon) + neon = (Cobalt ion (1+) bullet 2neon)

By formula: (Co+ bullet Ne) + Ne = (Co+ bullet 2Ne)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH90 K) = 1.95 kcal/mol, «DELTA»rS(100 K) = 12.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar11.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH90 K) = 1.95 kcal/mol, «DELTA»rS(100 K) = 12.5 cal/mol*K; M

(Cobalt ion (1+) bullet helium) + helium = (Cobalt ion (1+) bullet 2helium)

By formula: (Co+ bullet He) + He = (Co+ bullet 2He)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.41 kcal/mol, «DELTA»rS(100 K) = 19.1 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.41 kcal/mol, «DELTA»rS(100 K) = 19.1 cal/mol*K; M

Cobalt ion (1+) + Carbon monoxide = (Cobalt ion (1+) bullet Carbon monoxide)

By formula: Co+ + CO = (Co+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar41.6 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar39. ± 3.kcal/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
41.5 (+1.6,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
39.0 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + neon = (Cobalt ion (1+) bullet neon)

By formula: Co+ + Ne = (Co+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar2.5 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 2.18 kcal/mol, «DELTA»rS(100 K) = 14.0 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar15.4cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 2.18 kcal/mol, «DELTA»rS(100 K) = 14.0 cal/mol*K; M

Cobalt ion (1+) + helium = (Cobalt ion (1+) bullet helium)

By formula: Co+ + He = (Co+ bullet He)

Quantity Value Units Method Reference Comment
Deltar3.6 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.02 kcal/mol, «DELTA»rS(100 K) = 14.7 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar17.1cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.02 kcal/mol, «DELTA»rS(100 K) = 14.7 cal/mol*K; M

(Cobalt ion (1+) bullet Methane) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen bullet Methane)

By formula: (Co+ bullet CH4) + H2 = (Co+ bullet H2 bullet CH4)

Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.4 (+0.8,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) bullet Hydrogen) + Methane = (Cobalt ion (1+) bullet Methane bullet Hydrogen)

By formula: (Co+ bullet H2) + CH4 = (Co+ bullet CH4 bullet H2)

Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.6 (+1.2,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) bullet Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 2Hydrogen)

By formula: (Co+ bullet H2) + H2 = (Co+ bullet 2H2)

Quantity Value Units Method Reference Comment
Deltar18.0 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=17.0 kcal/mol, «DELTA»rS(300 K)=24.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar24.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=17.0 kcal/mol, «DELTA»rS(300 K)=24.5 cal/mol*K; M

(Cobalt ion (1+) bullet 2Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 3Hydrogen)

By formula: (Co+ bullet 2H2) + H2 = (Co+ bullet 3H2)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 0.4kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=20.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar20.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=20.5 cal/mol*K; M

(Cobalt ion (1+) bullet 3Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 4Hydrogen)

By formula: (Co+ bullet 3H2) + H2 = (Co+ bullet 4H2)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=25.2 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=25.2 cal/mol*K; M

(Cobalt ion (1+) bullet 4Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 5Hydrogen)

By formula: (Co+ bullet 4H2) + H2 = (Co+ bullet 5H2)

Quantity Value Units Method Reference Comment
Deltar5.2 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.3 kcal/mol, «DELTA»rS(300 K)=21.9 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.3 kcal/mol, «DELTA»rS(300 K)=21.9 cal/mol*K; M

(Cobalt ion (1+) bullet 5Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 6Hydrogen)

By formula: (Co+ bullet 5H2) + H2 = (Co+ bullet 6H2)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.0 kcal/mol, «DELTA»rS(300 K)=23.8 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar23.7cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.0 kcal/mol, «DELTA»rS(300 K)=23.8 cal/mol*K; M

(Cobalt ion (1+) bullet 6Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 7Hydrogen)

By formula: (Co+ bullet 6H2) + H2 = (Co+ bullet 7H2)

Quantity Value Units Method Reference Comment
Deltar1.5 ± 0.7kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=0.8 kcal/mol; «DELTA»rS(300 K)=18.0 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar18.0cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=0.8 kcal/mol; «DELTA»rS(300 K)=18.0 cal/mol*K; M

(Cobalt ion (1+) bullet Methane) + Methane = (Cobalt ion (1+) bullet 2Methane)

By formula: (Co+ bullet CH4) + CH4 = (Co+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar26.1cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(500 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.9 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
24.8 (+1.0,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(500 K); M

Cobalt ion (1+) + Ethylene = (Cobalt ion (1+) bullet Ethylene)

By formula: Co+ + C2H4 = (Co+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar44.5 ± 2.2kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
42.8 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
6.5 (+3.0,-0.) CIDHaynes and Armentrout, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Cobalt ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 2Carbon monoxide)

By formula: (Co+ bullet CO) + CO = (Co+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar36.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
36.4 (+2.1,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
32.9 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Methane) + Ethane = (Cobalt ion (1+) bullet Ethane bullet Methane)

By formula: (Co+ bullet CH4) + C2H6 = (Co+ bullet C2H6 bullet CH4)

Quantity Value Units Method Reference Comment
Deltar25.9cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 (+1.3,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Cobalt ion (1+) + Water = (Cobalt ion (1+) bullet Water)

By formula: Co+ + H2O = (Co+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar37. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M
Deltar40.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
38.5 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Water) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen bullet Water)

By formula: (Co+ bullet H2O) + H2 = (Co+ bullet H2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar24.7cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
19.8 (+0.6,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

(Cobalt ion (1+) bullet Water) + Methane = (Cobalt ion (1+) bullet Methane bullet Water)

By formula: (Co+ bullet H2O) + CH4 = (Co+ bullet CH4 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(525 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
25.9 (+0.7,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(525 K); M

(Cobalt ion (1+) bullet Ethane) + Methane = (Cobalt ion (1+) bullet Methane bullet Ethane)

By formula: (Co+ bullet C2H6) + CH4 = (Co+ bullet CH4 bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar26.4cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
24.4 (+1.1,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Cobalt ion (1+) + Propene = (Cobalt ion (1+) bullet Propene)

By formula: Co+ + C3H6 = (Co+ bullet C3H6)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
43.0 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
43.1 (+1.6,-0.) CIDHaynes and Armentrout, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Water) + Water = (Cobalt ion (1+) bullet 2Water)

By formula: (Co+ bullet H2O) + H2O = (Co+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar41.9kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
38.7 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Acetylene = (Cobalt ion (1+) bullet Acetylene)

By formula: Co+ + C2H2 = (Co+ bullet C2H2)

Quantity Value Units Method Reference Comment
Deltar43.0 ± 1.9kcal/molIRMPDSurya, Ranatunga, et al., 1997RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
6.5 (+3.1,-0.) CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH >=, guided ion beam CID; M

(Cobalt ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 3Carbon monoxide)

By formula: (Co+ bullet 2CO) + CO = (Co+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar19.6 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
19.6 (+2.8,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 4Carbon monoxide)

By formula: (Co+ bullet 3CO) + CO = (Co+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar17.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.4,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 5Carbon monoxide)

By formula: (Co+ bullet 4CO) + CO = (Co+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar17.9 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.2,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

Cobalt ion (1+) + Benzene = (Cobalt ion (1+) bullet Benzene)

By formula: Co+ + C6H6 = (Co+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar61.2 ± 2.6kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
61.1 (+2.5,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Ammonia) + Ammonia = (Cobalt ion (1+) bullet 2Ammonia)

By formula: (Co+ bullet H3N) + H3N = (Co+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar59.3 ± 3.1kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar61.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Ammonia = (Cobalt ion (1+) bullet Ammonia)

By formula: Co+ + H3N = (Co+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar52.1 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar58.8kcal/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Methyl radical = (Cobalt ion (1+) bullet Methyl radical)

By formula: Co+ + CH3 = (Co+ bullet CH3)

Quantity Value Units Method Reference Comment
Deltar48.8 ± 3.0kcal/molCIDTFisher, Sunderlin, et al., 1989RCD
Deltar49.1 ± 3.5kcal/molCIDTGeorgiadis, Fisher, et al., 1989RCD

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) bullet Carbon monosulfide)

By formula: Co+ + CS = (Co+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001RCD
Deltar57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cobalt ion (1+) bullet 2Water) + Water = (Cobalt ion (1+) bullet 3Water)

By formula: (Co+ bullet 2H2O) + H2O = (Co+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
15.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 3Water) + Water = (Cobalt ion (1+) bullet 4Water)

By formula: (Co+ bullet 3H2O) + H2O = (Co+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
13.9 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Propyne = (Cobalt ion (1+) bullet Propyne)

By formula: Co+ + C3H4 = (Co+ bullet C3H4)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
18.9 (+2.1,-0.) CIDHaynes and Armentrout, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Cobalt ion (1+) bullet 3Methane) + Methane = (Cobalt ion (1+) bullet 4Methane)

By formula: (Co+ bullet 3CH4) + CH4 = (Co+ bullet 4CH4)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
16.2 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 10cobalt) + cobalt = (Cobalt ion (1+) bullet 11cobalt)

By formula: (Co+ bullet 10Co) + Co = (Co+ bullet 11Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
78.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 11cobalt) + cobalt = (Cobalt ion (1+) bullet 12cobalt)

By formula: (Co+ bullet 11Co) + Co = (Co+ bullet 12Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
83.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 12cobalt) + cobalt = (Cobalt ion (1+) bullet 13cobalt)

By formula: (Co+ bullet 12Co) + Co = (Co+ bullet 13Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
72.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 13cobalt) + cobalt = (Cobalt ion (1+) bullet 14cobalt)

By formula: (Co+ bullet 13Co) + Co = (Co+ bullet 14Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
90.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 14cobalt) + cobalt = (Cobalt ion (1+) bullet 15cobalt)

By formula: (Co+ bullet 14Co) + Co = (Co+ bullet 15Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
84.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 15cobalt) + cobalt = (Cobalt ion (1+) bullet 16cobalt)

By formula: (Co+ bullet 15Co) + Co = (Co+ bullet 16Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 16cobalt) + cobalt = (Cobalt ion (1+) bullet 17cobalt)

By formula: (Co+ bullet 16Co) + Co = (Co+ bullet 17Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
88.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 9cobalt) + cobalt = (Cobalt ion (1+) bullet 10cobalt)

By formula: (Co+ bullet 9Co) + Co = (Co+ bullet 10Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
75.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T., Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters, J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Kemper, Bushnell, et al., 1993, 2
Kemper, P.R.; Bushnell, J.; Von Helden, G.; Bowers, M.T., Co+(H2)n Clusters: Binding Energies and Molecular Parameters, J. Chem Phys., 1993, 97, 1, 52, https://doi.org/10.1021/j100103a012 . [all data]

Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B., Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy, Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T., Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar), J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Goebel, Haynes, et al., 1995
Goebel, S.; Haynes, C.L.; Khan, F.A.; Armentrout, P.B., Collision-Induced Dissociation Studies of Co(CO)x, x = 1-5: Sequential Bond Energies and the Heat of Formation of Co(CO)4, J. Am. Chem. Soc., 1995, 117, 26, 6994, https://doi.org/10.1021/ja00131a023 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B., Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies, J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026 . [all data]

Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B., Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane, J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016 . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References