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Cobalt ion (1+)


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar42.624cal/mol*KReviewChase, 1998Data last reviewed in June, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(Cobalt ion (1+) bullet 2Methane) + Methane = (Cobalt ion (1+) bullet 3Methane)

By formula: (Co+ bullet 2CH4) + CH4 = (Co+ bullet 3CH4)

Quantity Value Units Method Reference Comment
Deltar11.kcal/molSIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
9.8 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
0.7477.SIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Cobalt ion (1+) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen)

By formula: Co+ + H2 = (Co+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar20. ± 1.kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(O K)=18.2 kcal/mol, «DELTA»rS(300 K)=20.6 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(O K)=18.2 kcal/mol, «DELTA»rS(300 K)=20.6 cal/mol*K; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.5 (+2.3,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M

Cobalt ion (1+) + Methane = (Cobalt ion (1+) bullet Methane)

By formula: Co+ + CH4 = (Co+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar19.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
21.5 (+1.6,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M
21.5 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
22.5 (+0.5,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

(Cobalt ion (1+) bullet Benzene) + Benzene = (Cobalt ion (1+) bullet 2Benzene)

By formula: (Co+ bullet C6H6) + C6H6 = (Co+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar39.9 ± 3.3kcal/molCIDTMeyer, Khan, et al., 1995RCD
Quantity Value Units Method Reference Comment
Deltar27.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
39.9 (+3.2,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M
27.0 (+1.0,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Cobalt ion (1+) + Ethane = (Cobalt ion (1+) bullet Ethane)

By formula: Co+ + C2H6 = (Co+ bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
23.9 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
28.0 (+1.6,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

(Cobalt ion (1+) bullet 2helium) + helium = (Cobalt ion (1+) bullet 3helium)

By formula: (Co+ bullet 2He) + He = (Co+ bullet 3He)

Quantity Value Units Method Reference Comment
Deltar1.3 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 1.22 kcal/mol, «DELTA»rS(100 K) = 11.1 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar11.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 1.22 kcal/mol, «DELTA»rS(100 K) = 11.1 cal/mol*K; M

(Cobalt ion (1+) bullet neon) + neon = (Cobalt ion (1+) bullet 2neon)

By formula: (Co+ bullet Ne) + Ne = (Co+ bullet 2Ne)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH90 K) = 1.95 kcal/mol, «DELTA»rS(100 K) = 12.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar11.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH90 K) = 1.95 kcal/mol, «DELTA»rS(100 K) = 12.5 cal/mol*K; M

(Cobalt ion (1+) bullet helium) + helium = (Cobalt ion (1+) bullet 2helium)

By formula: (Co+ bullet He) + He = (Co+ bullet 2He)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.41 kcal/mol, «DELTA»rS(100 K) = 19.1 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.41 kcal/mol, «DELTA»rS(100 K) = 19.1 cal/mol*K; M

Cobalt ion (1+) + Carbon monoxide = (Cobalt ion (1+) bullet Carbon monoxide)

By formula: Co+ + CO = (Co+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar41.6 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar39. ± 3.kcal/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
41.5 (+1.6,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
39.0 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + neon = (Cobalt ion (1+) bullet neon)

By formula: Co+ + Ne = (Co+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar2.5 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 2.18 kcal/mol, «DELTA»rS(100 K) = 14.0 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar15.4cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 2.18 kcal/mol, «DELTA»rS(100 K) = 14.0 cal/mol*K; M

Cobalt ion (1+) + helium = (Cobalt ion (1+) bullet helium)

By formula: Co+ + He = (Co+ bullet He)

Quantity Value Units Method Reference Comment
Deltar3.6 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.02 kcal/mol, «DELTA»rS(100 K) = 14.7 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar17.1cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; «DELTA»rH(0 K) = 3.02 kcal/mol, «DELTA»rS(100 K) = 14.7 cal/mol*K; M

(Cobalt ion (1+) bullet Methane) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen bullet Methane)

By formula: (Co+ bullet CH4) + H2 = (Co+ bullet H2 bullet CH4)

Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
17.4 (+0.8,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) bullet Hydrogen) + Methane = (Cobalt ion (1+) bullet Methane bullet Hydrogen)

By formula: (Co+ bullet H2) + CH4 = (Co+ bullet CH4 bullet H2)

Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.6 (+1.2,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, «DELTA»rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) bullet Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 2Hydrogen)

By formula: (Co+ bullet H2) + H2 = (Co+ bullet 2H2)

Quantity Value Units Method Reference Comment
Deltar18.0 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=17.0 kcal/mol, «DELTA»rS(300 K)=24.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar24.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=17.0 kcal/mol, «DELTA»rS(300 K)=24.5 cal/mol*K; M

(Cobalt ion (1+) bullet 2Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 3Hydrogen)

By formula: (Co+ bullet 2H2) + H2 = (Co+ bullet 3H2)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 0.4kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=20.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar20.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=20.5 cal/mol*K; M

(Cobalt ion (1+) bullet 3Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 4Hydrogen)

By formula: (Co+ bullet 3H2) + H2 = (Co+ bullet 4H2)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=25.2 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=9.6 kcal/mol, «DELTA»rS(300 K)=25.2 cal/mol*K; M

(Cobalt ion (1+) bullet 4Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 5Hydrogen)

By formula: (Co+ bullet 4H2) + H2 = (Co+ bullet 5H2)

Quantity Value Units Method Reference Comment
Deltar5.2 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.3 kcal/mol, «DELTA»rS(300 K)=21.9 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.3 kcal/mol, «DELTA»rS(300 K)=21.9 cal/mol*K; M

(Cobalt ion (1+) bullet 5Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 6Hydrogen)

By formula: (Co+ bullet 5H2) + H2 = (Co+ bullet 6H2)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.0 kcal/mol, «DELTA»rS(300 K)=23.8 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar23.7cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=4.0 kcal/mol, «DELTA»rS(300 K)=23.8 cal/mol*K; M

(Cobalt ion (1+) bullet 6Hydrogen) + Hydrogen = (Cobalt ion (1+) bullet 7Hydrogen)

By formula: (Co+ bullet 6H2) + H2 = (Co+ bullet 7H2)

Quantity Value Units Method Reference Comment
Deltar1.5 ± 0.7kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=0.8 kcal/mol; «DELTA»rS(300 K)=18.0 cal/mol*K; M
Quantity Value Units Method Reference Comment
Deltar18.0cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; «DELTA»rH(0 K)=0.8 kcal/mol; «DELTA»rS(300 K)=18.0 cal/mol*K; M

(Cobalt ion (1+) bullet Methane) + Methane = (Cobalt ion (1+) bullet 2Methane)

By formula: (Co+ bullet CH4) + CH4 = (Co+ bullet 2CH4)

Quantity Value Units Method Reference Comment
Deltar26.1cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(500 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.9 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
24.8 (+1.0,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(500 K); M

Cobalt ion (1+) + Ethylene = (Cobalt ion (1+) bullet Ethylene)

By formula: Co+ + C2H4 = (Co+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar44.5 ± 2.2kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
42.8 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
6.5 (+3.0,-0.) CIDHaynes and Armentrout, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Cobalt ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 2Carbon monoxide)

By formula: (Co+ bullet CO) + CO = (Co+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar36.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
36.4 (+2.1,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
32.9 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Methane) + Ethane = (Cobalt ion (1+) bullet Ethane bullet Methane)

By formula: (Co+ bullet CH4) + C2H6 = (Co+ bullet C2H6 bullet CH4)

Quantity Value Units Method Reference Comment
Deltar25.9cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
28.4 (+1.3,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Cobalt ion (1+) + Water = (Cobalt ion (1+) bullet Water)

By formula: Co+ + H2O = (Co+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar37. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M
Deltar40.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
38.5 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Water) + Hydrogen = (Cobalt ion (1+) bullet Hydrogen bullet Water)

By formula: (Co+ bullet H2O) + H2 = (Co+ bullet H2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar24.7cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
19.8 (+0.6,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(530 K); M

(Cobalt ion (1+) bullet Water) + Methane = (Cobalt ion (1+) bullet Methane bullet Water)

By formula: (Co+ bullet H2O) + CH4 = (Co+ bullet CH4 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(525 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
25.9 (+0.7,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(525 K); M

(Cobalt ion (1+) bullet Ethane) + Methane = (Cobalt ion (1+) bullet Methane bullet Ethane)

By formula: (Co+ bullet C2H6) + CH4 = (Co+ bullet CH4 bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar26.4cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
24.4 (+1.1,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rS(490 K); M

Cobalt ion (1+) + Propene = (Cobalt ion (1+) bullet Propene)

By formula: Co+ + C3H6 = (Co+ bullet C3H6)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
43.0 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
43.1 (+1.6,-0.) CIDHaynes and Armentrout, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Water) + Water = (Cobalt ion (1+) bullet 2Water)

By formula: (Co+ bullet H2O) + H2O = (Co+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar41.9kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
38.7 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Acetylene = (Cobalt ion (1+) bullet Acetylene)

By formula: Co+ + C2H2 = (Co+ bullet C2H2)

Quantity Value Units Method Reference Comment
Deltar43.0 ± 1.9kcal/molIRMPDSurya, Ranatunga, et al., 1997RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
6.5 (+3.1,-0.) CIDArmentrout and Kickel, 1994gas phase; «DELTA»rH >=, guided ion beam CID; M

(Cobalt ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 3Carbon monoxide)

By formula: (Co+ bullet 2CO) + CO = (Co+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar19.6 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
19.6 (+2.8,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 4Carbon monoxide)

By formula: (Co+ bullet 3CO) + CO = (Co+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar17.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.4,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) bullet 5Carbon monoxide)

By formula: (Co+ bullet 4CO) + CO = (Co+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar17.9 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.2,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

Cobalt ion (1+) + Benzene = (Cobalt ion (1+) bullet Benzene)

By formula: Co+ + C6H6 = (Co+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar61.2 ± 2.6kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
61.1 (+2.5,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet Ammonia) + Ammonia = (Cobalt ion (1+) bullet 2Ammonia)

By formula: (Co+ bullet H3N) + H3N = (Co+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar59.3 ± 3.1kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar61.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Ammonia = (Cobalt ion (1+) bullet Ammonia)

By formula: Co+ + H3N = (Co+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar52.1 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD
Deltar58.8kcal/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Methyl radical = (Cobalt ion (1+) bullet Methyl radical)

By formula: Co+ + CH3 = (Co+ bullet CH3)

Quantity Value Units Method Reference Comment
Deltar48.8 ± 3.0kcal/molCIDTFisher, Sunderlin, et al., 1989RCD
Deltar49.1 ± 3.5kcal/molCIDTGeorgiadis, Fisher, et al., 1989RCD

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) bullet Carbon monosulfide)

By formula: Co+ + CS = (Co+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001RCD
Deltar57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cobalt ion (1+) bullet 2Water) + Water = (Cobalt ion (1+) bullet 3Water)

By formula: (Co+ bullet 2H2O) + H2O = (Co+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
15.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 3Water) + Water = (Cobalt ion (1+) bullet 4Water)

By formula: (Co+ bullet 3H2O) + H2O = (Co+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
13.9 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Propyne = (Cobalt ion (1+) bullet Propyne)

By formula: Co+ + C3H4 = (Co+ bullet C3H4)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
18.9 (+2.1,-0.) CIDHaynes and Armentrout, 1994gas phase; «DELTA»rH>=, guided ion beam CID; M

(Cobalt ion (1+) bullet 3Methane) + Methane = (Cobalt ion (1+) bullet 4Methane)

By formula: (Co+ bullet 3CH4) + CH4 = (Co+ bullet 4CH4)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
16.2 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 10cobalt) + cobalt = (Cobalt ion (1+) bullet 11cobalt)

By formula: (Co+ bullet 10Co) + Co = (Co+ bullet 11Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
78.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 11cobalt) + cobalt = (Cobalt ion (1+) bullet 12cobalt)

By formula: (Co+ bullet 11Co) + Co = (Co+ bullet 12Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
83.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 12cobalt) + cobalt = (Cobalt ion (1+) bullet 13cobalt)

By formula: (Co+ bullet 12Co) + Co = (Co+ bullet 13Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
72.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 13cobalt) + cobalt = (Cobalt ion (1+) bullet 14cobalt)

By formula: (Co+ bullet 13Co) + Co = (Co+ bullet 14Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
90.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 14cobalt) + cobalt = (Cobalt ion (1+) bullet 15cobalt)

By formula: (Co+ bullet 14Co) + Co = (Co+ bullet 15Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
84.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 15cobalt) + cobalt = (Cobalt ion (1+) bullet 16cobalt)

By formula: (Co+ bullet 15Co) + Co = (Co+ bullet 16Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
82.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 16cobalt) + cobalt = (Cobalt ion (1+) bullet 17cobalt)

By formula: (Co+ bullet 16Co) + Co = (Co+ bullet 17Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
88.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) bullet 9cobalt) + cobalt = (Cobalt ion (1+) bullet 10cobalt)

By formula: (Co+ bullet 9Co) + Co = (Co+ bullet 10Co)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
75.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T., Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters, J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Kemper, Bushnell, et al., 1993, 2
Kemper, P.R.; Bushnell, J.; Von Helden, G.; Bowers, M.T., Co+(H2)n Clusters: Binding Energies and Molecular Parameters, J. Chem Phys., 1993, 97, 1, 52, https://doi.org/10.1021/j100103a012 . [all data]

Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B., Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy, Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T., Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar), J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Goebel, Haynes, et al., 1995
Goebel, S.; Haynes, C.L.; Khan, F.A.; Armentrout, P.B., Collision-Induced Dissociation Studies of Co(CO)x, x = 1-5: Sequential Bond Energies and the Heat of Formation of Co(CO)4, J. Am. Chem. Soc., 1995, 117, 26, 6994, https://doi.org/10.1021/ja00131a023 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B., Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies, J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026 . [all data]

Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B., Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane, J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016 . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References