Cobalt ion (1+)
- Formula: Co+
- Molecular weight: 58.932646
- IUPAC Standard InChIKey: BFVNPAKTAJENJQ-UHFFFAOYSA-N
- CAS Registry Number: 16610-75-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Cobalt cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 73
- Options:
Gas phase thermochemistry data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 42.624 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1984 |
Ion clustering data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Co+ + Ar = (Co+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.8 | kcal/mol | PDis | Asher, Bellert, et al., 1994 | RCD |
By formula: Co+ + CH2 = (Co+ • CH2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 75.9 ± 1.2 | kcal/mol | CIDT | Haynes and Armentrout, 1994 | RCD |
By formula: Co+ + CH3 = (Co+ • CH3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.8 ± 3.0 | kcal/mol | CIDT | Fisher, Sunderlin, et al., 1989 | RCD |
ΔrH° | 49.1 ± 3.5 | kcal/mol | CIDT | Georgiadis, Fisher, et al., 1989 | RCD |
By formula: Co+ + CH4O = (Co+ • CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35.4 ± 1.9 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Co+ + CH4 = (Co+ • CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 19.8 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(530 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
21.5 (+1.6,-0.) | CID | Haynes and Armentrout, 1996 | gas phase; guided ion beam CID; M | |
21.5 (+1.4,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
22.5 (+0.5,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(530 K); M |
By formula: (Co+ • CH4) + CH4 = (Co+ • 2CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 26.1 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(500 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
22.9 (+1.2,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
24.8 (+1.0,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(500 K); M |
By formula: (Co+ • 2CH4) + CH4 = (Co+ • 3CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11. | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20. | cal/mol*K | N/A | Kemper, Bushnell, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
9.8 (+1.2,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.7 | 477. | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
By formula: (Co+ • 3CH4) + CH4 = (Co+ • 4CH4)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
16.2 (+1.4,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • CH4) + C2H6 = (Co+ • C2H6 • CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 25.9 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2CH4, ΔrS(480 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
28.4 (+1.3,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2CH4, ΔrS(480 K); M |
By formula: (Co+ • CH4) + H2 = (Co+ • H2 • CH4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 22.9 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
17.4 (+0.8,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+).2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
By formula: Co+ + CO = (Co+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.6 ± 1.7 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 39. ± 3. | kcal/mol | MKER | Carpenter, van Koppen, et al., 1995 | gas phase; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
41.5 (+1.6,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M | |
39.0 (+4.8,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • CO) + CO = (Co+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 36.6 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
36.4 (+2.1,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M | |
32.9 (+4.8,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 2CO) + CO = (Co+ • 3CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.6 ± 2.9 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
19.6 (+2.8,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 3CO) + CO = (Co+ • 4CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.9 ± 1.4 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
18.0 (+1.4,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 4CO) + CO = (Co+ • 5CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.9 ± 1.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
18.0 (+1.2,-0.) | CID | Goebel, Haynes, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: Co+ + CS = (Co+ • CS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 61.7 ± 7.8 | kcal/mol | CIDT | Rue, Armentrout, et al., 2001 | RCD |
ΔrH° | 57.4 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Co+ + C2H2 = (Co+ • C2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 43.0 ± 1.9 | kcal/mol | IRMPD | Surya, Ranatunga, et al., 1997 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
6.5 (+3.1,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH >=, guided ion beam CID; M |
By formula: Co+ + C2H4 = (Co+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.5 ± 2.2 | kcal/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
42.8 (+1.7,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
6.5 (+3.0,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: (Co+ • C2H4) + C2H4 = (Co+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 36.3 ± 3.3 | kcal/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: Co+ + C2H6 = (Co+ • C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 22.3 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)CH4, ΔrS(500 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
23.9 (+1.2,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
28.0 (+1.6,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)CH4, ΔrS(500 K); M |
By formula: (Co+ • C2H6) + CH4 = (Co+ • CH4 • C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 26.4 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(490 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
24.4 (+1.1,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(490 K); M |
By formula: (Co+ • 2C2H6) + C2H6 = (Co+ • 3C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12. | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrH<; M |
By formula: Co+ + C3H4 = (Co+ • C3H4)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
18.9 (+2.1,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Co+ + C3H6 = (Co+ • C3H6)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
43.0 (+1.7,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
43.1 (+1.6,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + C3H8 = (Co+ • C3H8)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
30.8 (+1.4,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + C4H4N2 = (Co+ • C4H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 58.6 ± 3.2 | kcal/mol | CIDT | Amunugama and Rodgers, 2001 | RCD |
By formula: Co+ + C4H5N = (Co+ • C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >66. | kcal/mol | RAK | Gapeev and Yang, 2000 | RCD |
By formula: (Co+ • C4H5N) + C4H5N = (Co+ • 2C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 46.4 | kcal/mol | RAK | Gapeev and Yang, 2000 | RCD |
By formula: Co+ + C5H5N = (Co+ • C5H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.0 ± 3.0 | kcal/mol | CIDT | Rodgers, Stanley, et al., 2000 | RCD |
By formula: Co+ + C5H5N5 = (Co+ • C5H5N5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 70.0 ± 2.5 | kcal/mol | CIDT | Rodgers and Armentrout, 2002 | RCD |
By formula: Co+ + C6H6 = (Co+ • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 61.2 ± 2.6 | kcal/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
61.1 (+2.5,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M |
By formula: (Co+ • C6H6) + C6H6 = (Co+ • 2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.9 ± 3.3 | kcal/mol | CIDT | Meyer, Khan, et al., 1995 | RCD |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 27.8 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(490 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
39.9 (+3.2,-0.) | CID | Meyer, Khan, et al., 1995 | gas phase; guided ion beam CID; M | |
27.0 (+1.0,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(490 K); M |
By formula: Co+ + Co = (Co+ • Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
63.8 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • Co) + Co = (Co+ • 2Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
48.1 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 2Co) + Co = (Co+ • 3Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
49.0 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 3Co) + Co = (Co+ • 4Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
65.5 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 4Co) + Co = (Co+ • 5Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
76.2 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 5Co) + Co = (Co+ • 6Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.6 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 6Co) + Co = (Co+ • 7Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
72.4 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 7Co) + Co = (Co+ • 8Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.6 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 8Co) + Co = (Co+ • 9Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
68.1 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 9Co) + Co = (Co+ • 10Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
75.0 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 10Co) + Co = (Co+ • 11Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
78.6 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 11Co) + Co = (Co+ • 12Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
83.9 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 12Co) + Co = (Co+ • 13Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
72.4 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 13Co) + Co = (Co+ • 14Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
90.8 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 14Co) + Co = (Co+ • 15Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
84.8 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 15Co) + Co = (Co+ • 16Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
82.7 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 16Co) + Co = (Co+ • 17Co)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
88.7 | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + D2 = (Co+ • D2)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
17.1 (+1.6,-0.) | CID | Haynes and Armentrout, 1996 | gas phase; guided ion beam CID; M |
By formula: Co+ + H2O = (Co+ • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 37. ± 3. | kcal/mol | CID | Magnera, David, et al., 1989 | gas phase; M |
ΔrH° | 40.1 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
38.5 (+1.4,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • H2O) + CH4 = (Co+ • CH4 • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 27.0 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(525 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
25.9 (+0.7,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(525 K); M |
By formula: (Co+ • H2O) + H2O = (Co+ • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.9 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
38.7 (+1.7,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 2H2O) + H2O = (Co+ • 3H2O)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
15.5 (+1.2,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 3H2O) + H2O = (Co+ • 4H2O)
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
13.9 (+1.4,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • H2O) + H2 = (Co+ • H2 • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 24.7 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(530 K); M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
19.8 (+0.6,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrS(530 K); M |
By formula: Co+ + H2 = (Co+ • H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. ± 1. | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(O K)=18.2 kcal/mol, ΔrS(300 K)=20.6 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.0 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(O K)=18.2 kcal/mol, ΔrS(300 K)=20.6 cal/mol*K; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
17.5 (+2.3,-0.) | CID | Haynes and Armentrout, 1996 | gas phase; guided ion beam CID; M |
By formula: (Co+ • H2) + CH4 = (Co+ • CH4 • H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrS° | 21.8 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
Enthalpy of reaction
ΔrH° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
22.6 (+1.2,-0.) | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; switching reaction(Co+)2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M |
By formula: (Co+ • H2) + H2 = (Co+ • 2H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.0 ± 0.6 | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=17.0 kcal/mol, ΔrS(300 K)=24.5 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24.5 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=17.0 kcal/mol, ΔrS(300 K)=24.5 cal/mol*K; M |
By formula: (Co+ • 2H2) + H2 = (Co+ • 3H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.6 ± 0.4 | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=20.5 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.5 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=20.5 cal/mol*K; M |
By formula: (Co+ • 3H2) + H2 = (Co+ • 4H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.4 ± 0.6 | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=25.2 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24.2 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=25.2 cal/mol*K; M |
By formula: (Co+ • 4H2) + H2 = (Co+ • 5H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.2 ± 0.6 | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=4.3 kcal/mol, ΔrS(300 K)=21.9 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.5 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=4.3 kcal/mol, ΔrS(300 K)=21.9 cal/mol*K; M |
By formula: (Co+ • 5H2) + H2 = (Co+ • 6H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.7 ± 0.6 | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=4.0 kcal/mol, ΔrS(300 K)=23.8 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.7 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=4.0 kcal/mol, ΔrS(300 K)=23.8 cal/mol*K; M |
By formula: (Co+ • 6H2) + H2 = (Co+ • 7H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.5 ± 0.7 | kcal/mol | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=0.8 kcal/mol; ΔrS(300 K)=18.0 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.0 | cal/mol*K | SIDT | Kemper, Bushnell, et al., 1993, 2 | gas phase; ΔrH(0 K)=0.8 kcal/mol; ΔrS(300 K)=18.0 cal/mol*K; M |
By formula: Co+ + H3N = (Co+ • H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 52.1 ± 3.6 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
ΔrH° | 58.8 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: (Co+ • H3N) + H3N = (Co+ • 2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.3 ± 3.1 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
ΔrH° | 61.1 | kcal/mol | CID | Marinelli and Squires, 1989 | gas phase; M |
By formula: (Co+ • 2H3N) + H3N = (Co+ • 3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.3 ± 1.4 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Co+ • 3H3N) + H3N = (Co+ • 4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.7 ± 1.4 | kcal/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: Co+ + He = (Co+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.6 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 3.02 kcal/mol, ΔrS(100 K) = 14.7 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.1 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 3.02 kcal/mol, ΔrS(100 K) = 14.7 cal/mol*K; M |
By formula: (Co+ • He) + He = (Co+ • 2He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.7 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 3.41 kcal/mol, ΔrS(100 K) = 19.1 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.6 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 3.41 kcal/mol, ΔrS(100 K) = 19.1 cal/mol*K; M |
By formula: (Co+ • 2He) + He = (Co+ • 3He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.3 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 1.22 kcal/mol, ΔrS(100 K) = 11.1 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 11.6 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 1.22 kcal/mol, ΔrS(100 K) = 11.1 cal/mol*K; M |
By formula: Co+ + Ne = (Co+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.5 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 2.18 kcal/mol, ΔrS(100 K) = 14.0 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 15.4 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 2.18 kcal/mol, ΔrS(100 K) = 14.0 cal/mol*K; M |
By formula: (Co+ • Ne) + Ne = (Co+ • 2Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.0 ± 0.1 | kcal/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH90 K) = 1.95 kcal/mol, ΔrS(100 K) = 12.5 cal/mol*K; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 11.6 | cal/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH90 K) = 1.95 kcal/mol, ΔrS(100 K) = 12.5 cal/mol*K; M |
References
Go To: Top, Gas phase thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Asher, Bellert, et al., 1994
Asher, R.L.; Bellert, D.; Buthelezi, T.; Brucat, P.J.,
The Bond Strength of Ni2+,
Chem. Phys. Lett., 1994, 224, 5-6, 529, https://doi.org/10.1016/0009-2614(94)00574-5
. [all data]
Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B.,
Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers,
Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022
. [all data]
Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B.,
Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies,
J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026
. [all data]
Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B.,
Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane,
J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T.,
Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters,
J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016
. [all data]
Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B.,
Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy,
Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7
. [all data]
Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L.,
Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]
Kemper, Bushnell, et al., 1993, 2
Kemper, P.R.; Bushnell, J.; Von Helden, G.; Bowers, M.T.,
Co+(H2)n Clusters: Binding Energies and Molecular Parameters,
J. Chem Phys., 1993, 97, 1, 52, https://doi.org/10.1021/j100103a012
. [all data]
Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T.,
Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone,
J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021
. [all data]
Goebel, Haynes, et al., 1995
Goebel, S.; Haynes, C.L.; Khan, F.A.; Armentrout, P.B.,
Collision-Induced Dissociation Studies of Co(CO)x, x = 1-5: Sequential Bond Energies and the Heat of Formation of Co(CO)4,
J. Am. Chem. Soc., 1995, 117, 26, 6994, https://doi.org/10.1021/ja00131a023
. [all data]
Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H.,
Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS,
J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716
. [all data]
Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S.,
Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4),
J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c
. [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B.,
Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes,
J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z
. [all data]
Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T.,
Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i
. [all data]
Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N.,
Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results,
J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d
. [all data]
Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R.,
Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923
. [all data]
Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B.,
Influence of d orbital occupation on the binding of metal ions to adenine,
J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+
. [all data]
Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B.,
Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu,
J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018
. [all data]
Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J.,
Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051
. [all data]
Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R.,
Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First,
J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052
. [all data]
Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B.,
Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD,
J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c
. [all data]
Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T.,
Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar),
J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Ion clustering data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.