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CO3-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CO3- + Sulfur dioxide = (CO3- bullet Sulfur dioxide)

By formula: CO3- + O2S = (CO3- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar14.kcal/molHPMSKeesee, Lee, et al., 1980gas phase; switching reaction(O-)CO2, Entropy change calculated or estimated; Fehsenfeld and Ferguson, 1974
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AKeesee, Lee, et al., 1980gas phase; switching reaction(O-)CO2, Entropy change calculated or estimated; Fehsenfeld and Ferguson, 1974

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.0296.HPMSKeesee, Lee, et al., 1980gas phase; switching reaction(O-)CO2, Entropy change calculated or estimated; Fehsenfeld and Ferguson, 1974

(CO3- bullet 6Carbon dioxide) + Carbon dioxide = (CO3- bullet 7Carbon dioxide)

By formula: (CO3- bullet 6CO2) + CO2 = (CO3- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar4.45kcal/molPHPMSHiraoka and Yamabe, 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka and Yamabe, 1992gas phase; Entropy change calculated or estimated

(CO3- bullet Water) + Water = (CO3- bullet 2Water)

By formula: (CO3- bullet H2O) + H2O = (CO3- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar13.6kcal/molHPMSKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar29.6cal/mol*KHPMSKeesee, Lee, et al., 1979gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.3296.FAFehsenfeld and Ferguson, 1974gas phase

CO3- + Water = (CO3- bullet Water)

By formula: CO3- + H2O = (CO3- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar14.1kcal/molHPMSKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KHPMSKeesee, Lee, et al., 1979gas phase

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.7296.FAFehsenfeld and Ferguson, 1974gas phase

(CO3- bullet 2Carbon dioxide) + Carbon dioxide = (CO3- bullet 3Carbon dioxide)

By formula: (CO3- bullet 2CO2) + CO2 = (CO3- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar5.5 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar21.9cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase

(CO3- bullet 3Carbon dioxide) + Carbon dioxide = (CO3- bullet 4Carbon dioxide)

By formula: (CO3- bullet 3CO2) + CO2 = (CO3- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar5.2 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase

(CO3- bullet 4Carbon dioxide) + Carbon dioxide = (CO3- bullet 5Carbon dioxide)

By formula: (CO3- bullet 4CO2) + CO2 = (CO3- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar4.8 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase

(CO3- bullet 5Carbon dioxide) + Carbon dioxide = (CO3- bullet 6Carbon dioxide)

By formula: (CO3- bullet 5CO2) + CO2 = (CO3- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar21.9cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase

(CO3- bullet Carbon dioxide) + Carbon dioxide = (CO3- bullet 2Carbon dioxide)

By formula: (CO3- bullet CO2) + CO2 = (CO3- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar5.7 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase

(CO3- bullet 2Water) + Water = (CO3- bullet 3Water)

By formula: (CO3- bullet 2H2O) + H2O = (CO3- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar13.1kcal/molHPMSKeesee, Lee, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar32.5cal/mol*KHPMSKeesee, Lee, et al., 1979gas phase

CO3- + Carbon dioxide = (CO3- bullet Carbon dioxide)

By formula: CO3- + CO2 = (CO3- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar5.9 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar16.3cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr., Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO3- and HCO3-, J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References