Butanoic acid, 3-hexenyl ester, (Z)-
- Formula: C10H18O2
- Molecular weight: 170.2487
- IUPAC Standard InChIKey: ZCHOPXVYTWUHDS-WAYWQWQTSA-N
- CAS Registry Number: 16491-36-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Stereoisomers:
- Other names: Butyric acid, 3-hexenyl ester, (Z)-; cis-Butyric acid, 3-hexenyl ester; cis-3-Hexen-1-yl butyrate; cis-3-Hexenyl butyrate; cis-3-Hexenyl n-butyrate; (3Z)-3-Hexenyl butyrate; 3-Hexen-1-ol, butanoate, (Z)-; 3(Z)-Hexenyl butanoate; Butanoic acid, (Z)-3-hexenyl ester; cis-3-Hexenyl butanoate; cis-Hex-3-enyl butanoate; cis-Hex-3-enyl butyrate; Hex-3(Z)-enyl butanoate; Hexenyl butanoate (3Z); (Z)-3-Hexen-1-ol, butanoate; (Z)-3-Hexen-1-yl butanoate; (Z)-3-Hexenyl butanoate; (Z)-3-Hexenyl butyrate; (Z)-Hex-3-enyl butanoate; (Z)-Hex-3-enyl butyrate
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | HP-5 | HP-5 MS | SLB-5 MS | HP-5 MS |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | Helium | Helium | Helium | Helium | Helium |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 50. | 50. | 50. |
Tend (C) | 240. | 240. | 230. | 250. | 250. |
Heat rate (K/min) | 3. | 3. | 4. | 3. | 10. |
Initial hold (min) | 4. | 2. | 2. | ||
Final hold (min) | 10. | 10. | 5. | ||
I | 1186. | 1185. | 1187. | 1189. | 1187. |
Reference | Rodriques, Amorim, et al., 2013 | Bertoli, Lepnardi, et al., 2011 | Forero, Quijano, et al., 2008 | Lo Presti, Sciarrone, et al., 2008 | Yasuda, Shigehisa, et al., 2008 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5 | HP-5MS | RTX-1 | DB-5 | DB-5 |
Column length (m) | 30. | 30. | 30. | 50. | 30. |
Carrier gas | H2 | He | N2 | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.2 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 50. | 50. | 60. | 50. | 60. |
Tend (C) | 280. | 240. | 300. | 220. | 240. |
Heat rate (K/min) | 4. | 3. | 4. | 3. | 3. |
Initial hold (min) | 2. | 3. | 2. | ||
Final hold (min) | 10. | 10. | |||
I | 1187. | 1212. | 1173. | 1186. | 1188. |
Reference | Pino, Sauri-Duch, et al., 2006 | Tepe B., Sokmen M., et al., 2005 | Lis, Boczek, et al., 2004 | Juteau, Jerkovic, et al., 2003 | da Silva, Luz, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | DB-5 | RSL-200 | DB-5 | HP-5 |
Column length (m) | 50. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | H2 | He | N2 |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.5 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 40. | 60. | 60. |
Tend (C) | 220. | 280. | 280. | 240. | 220. |
Heat rate (K/min) | 2. | 3. | 6. | 3. | 5. |
Initial hold (min) | 2. | 10. | |||
Final hold (min) | 40. | 30. | 10. | ||
I | 1159. | 1179. | 1178. | 1189. | 1187. |
Reference | Valette, Fernandez, et al., 2003 | Caredda, Marongiu, et al., 2002 | Jirovetz, Smith, et al., 2002 | Maia, da Silva, et al., 2002 | Campeol, Flamini, et al., 2001 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | HP-1 | DB-1 | DB-1 | OV-101 |
Column length (m) | 50. | 25. | 30. | 30. | 50. |
Carrier gas | N2 | H2 | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.17 | 0.25 | 0.25 | ||
Tstart (C) | 80. | 40. | 50. | 50. | 80. |
Tend (C) | 200. | 260. | 240. | 240. | 200. |
Heat rate (K/min) | 2. | 3. | 5. | 5. | 2. |
Initial hold (min) | 5. | 3. | 3. | ||
Final hold (min) | |||||
I | 1166. | 1176. | 1162. | 1163. | 1166. |
Reference | Yang, 2001 | Lopes, Koketsu, et al., 1999 | Shiota, 1993 | Shiota, 1993 | Tamura, Yang, et al., 1993 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | OV-101 | DB-1 | DB-1 | DB-1 | DB-1 |
Column length (m) | 50. | 60. | 60. | 60. | |
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.32 | 0.32 | |
Phase thickness (μm) | |||||
Tstart (C) | 80. | 50. | 50. | 50. | 50. |
Tend (C) | 200. | 230. | 230. | 230. | 250. |
Heat rate (K/min) | 2. | 4. | 4. | 4. | 4. |
Initial hold (min) | 0.1 | ||||
Final hold (min) | 10. | 10. | 10. | 5. | |
I | 1167. | 1167. | 1167. | 1167. | 1167. |
Reference | Tamura, Yang, et al., 1993 | Binder, Benson, et al., 1990 | Binder, Turner, et al., 1990 | Binder, Turner, et al., 1990, 2 | Binder and Flath, 1989 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rodriques, Amorim, et al., 2013
Rodriques, K.A. da.F.; Amorim, L.V.; de Oliveira, J.M.G.; Dias, C.N.; Moraes, D.F.C.; Andrade, E.H. deA.; Maia, J.G.S.; Carneiro, S.M.P.; Carvalho, F.A. deA.,
Eugenia uniflora L. essential oil as a potential anti-Leishmania agent: effect on Leishmania amazonensis and possible mechanism of action,
Evidence-Based Complementary and Alternative Medicine, 2013, 2013, 1-10, https://doi.org/10.1155/2013/279726
. [all data]
Bertoli, Lepnardi, et al., 2011
Bertoli, A.; Lepnardi, M.; Krzyzanowska, J.; Oleszek, W.; Pistelli, L.,
Mentha longifolia in vitro cultures as safe source of flavouring ingradients,
Acta Biochem. Polonica, 2011, 58, 4, 581-587. [all data]
Forero, Quijano, et al., 2008
Forero, M.D.; Quijano, C.E.; Pino, J.A.,
Volatile compounds of Chile pepper (Capsicum annuum L. var. glabriusculum) at two ripening stages,
Flavour Fragr. J., 2008, 24, 1, 25-30, https://doi.org/10.1002/ffj.1913
. [all data]
Lo Presti, Sciarrone, et al., 2008
Lo Presti, M.; Sciarrone, D.; Crupi, M.C.; Costa, R.; Ragusa, S.; Dugo, G.; Mondello, L.,
Evaliation of the volatile and chiral composition in Pistacia lentiscus L. essential oil,
Flavour Fragr. J., 2008, 23, 4, 249-257, https://doi.org/10.1002/ffj.1878
. [all data]
Yasuda, Shigehisa, et al., 2008
Yasuda, T.; Shigehisa, S.; Yuasa, K.; Okutani-Akamatsu, Y.; Teramoto, N.; Watanabe, T.; Mochizuki, F.,
Sex attactant pheromone of the sorghum plant bug Stenotus rubrovittatus (Natsumura) (Heteroptera: Miridae),
Appl. Entomol. Zool., 2008, 43, 2, 219-226, https://doi.org/10.1303/aez.2008.219
. [all data]
Pino, Sauri-Duch, et al., 2006
Pino, J.; Sauri-Duch, E.; Marbot, R.,
Changes in volatile compounds of Habanero chile pepper (Capsicum chinense Jack. cv. Habanero) at two ripening stages,
Food Chem., 2006, 94, 3, 394-398, https://doi.org/10.1016/j.foodchem.2004.11.040
. [all data]
Tepe B., Sokmen M., et al., 2005
Tepe B.; Sokmen M.; Akpulat H.A.; Daferera D.; Polissiou M.; Sokmen A.,
Antioxidative activity of the essential oils of Thymus sipyleus subsp sipyleus var. sipyleus and Thymus sipyleus subsp sipyleus var. rosulans,
J. Food Eng., 2005, 66, 4, 447-454, https://doi.org/10.1016/j.jfoodeng.2004.04.015
. [all data]
Lis, Boczek, et al., 2004
Lis, A.; Boczek, E.; Góra, J.,
Chemical composition of the essential oils from fruits, leaves and flowers of the Amur cork tree (Phellodendron amurense Rupr.),
Flavour Fragr. J., 2004, 19, 6, 549-553, https://doi.org/10.1002/ffj.1349
. [all data]
Juteau, Jerkovic, et al., 2003
Juteau, F.; Jerkovic, I.; Masotti, V.; Milos, M.; Mastelic, J.; Bessière, J.-M.; Viano, J.,
Composition and antimicrobial activity of the essential oil of Artemisia absinthium from Croatia and France,
Planta Medica, 2003, 69, 2, 158-161, https://doi.org/10.1055/s-2003-37714
. [all data]
da Silva, Luz, et al., 2003
da Silva, J.D.; Luz, A.I.R.; da Silva, M.H.L.; Andrade, E.H.A.; Soghbi, M.G.B.; Maia, J.G.S.,
Essential oils of the leaves and stems of four Psidium spp.,
Flavour Fragr. J., 2003, 18, 3, 240-243, https://doi.org/10.1002/ffj.1219
. [all data]
Valette, Fernandez, et al., 2003
Valette, L.; Fernandez, X.; Poulain, S.; Loiseau, A.-M.; Lizzani-Cuvelier, L.; Levieil, R.; Restier, L.,
Volatile constituents from Romanesco cauliflower,
Food Chem., 2003, 80, 3, 353-358, https://doi.org/10.1016/S0308-8146(02)00272-8
. [all data]
Caredda, Marongiu, et al., 2002
Caredda, A.; Marongiu, B.; Porcedda, S.; Soro, C.,
Supercritical carbon dioxide extraction and characterization of Laurus nobilis essential oil,
J. Agric. Food Chem., 2002, 50, 6, 1492-1496, https://doi.org/10.1021/jf0108563
. [all data]
Jirovetz, Smith, et al., 2002
Jirovetz, L.; Smith, D.; Buchbauer, G.,
Aroma compound analysis of Eruca sativa (Brassicaceae) SPME headspace leaf samples using GC, GC-MS, and olfactometry,
J. Agric. Food Chem., 2002, 50, 16, 4643-4646, https://doi.org/10.1021/jf020129n
. [all data]
Maia, da Silva, et al., 2002
Maia, J.G.S.; da Silva, M.H.L.; Andrade, E.H.A.; Zoghbi, M.G.B.; Carreira, L.M.M.,
Essential oils from Astronium urundeuva (Allemao) Engl. and A. fraxinifolium Schott ex Spreng.,
Flavour Fragr. J., 2002, 17, 1, 72-74, https://doi.org/10.1002/ffj.1046
. [all data]
Campeol, Flamini, et al., 2001
Campeol, E.; Flamini, G.; Chericoni, S.; Catalano, S.; Cremonini, R.,
Volatile compounds from three cultivars of Olea europaea from Italy,
J. Agric. Food Chem., 2001, 49, 11, 5409-5411, https://doi.org/10.1021/jf010455n
. [all data]
Yang, 2001
Yang, R.,
Analysis of the volatile components in peel oil of Yuzu by gas chromatography/mass spectrometry,
Chin. J. Anal. Chem., 2001, 29, 3, 313-316. [all data]
Lopes, Koketsu, et al., 1999
Lopes, D.; Koketsu, M.; Carauta, J.P.P.; de Oliveira, R.R.; Kaplan, M.A.C.,
Chemical composition of Pourouma guianensis Aublet essential oils,
Flavour Fragr. J., 1999, 14, 4, 233-236, https://doi.org/10.1002/(SICI)1099-1026(199907/08)14:4<233::AID-FFJ813>3.0.CO;2-L
. [all data]
Shiota, 1993
Shiota, H.,
New esteric components in the volatiles of banana fruit (Musa sapientum L.),
J. Agric. Food Chem., 1993, 41, 11, 2056-2062, https://doi.org/10.1021/jf00035a046
. [all data]
Tamura, Yang, et al., 1993
Tamura, H.; Yang, R.-H.; Sugisawa, H.,
Aroma profiles of peel oils of acid citrus,
ACS Sym. Ser., 1993, 525, 121-136. [all data]
Binder, Benson, et al., 1990
Binder, R.G.; Benson, M.E.; Flath, R.A.,
Volatile Components of Safflower,
J. Agric. Food Chem., 1990, 38, 5, 1245-1248, https://doi.org/10.1021/jf00095a020
. [all data]
Binder, Turner, et al., 1990
Binder, R.G.; Turner, C.E.; Flath, R.A.,
Volatile components of purple starthistle,
J. Agric. Food Chem., 1990, 38, 4, 1053-1055, https://doi.org/10.1021/jf00094a030
. [all data]
Binder, Turner, et al., 1990, 2
Binder, R.G.; Turner, C.E.; Flath, R.A.,
Comparison of yellow starthistle volatiles from different plant parts,
J. Agric. Food Chem., 1990, 38, 3, 764-767, https://doi.org/10.1021/jf00093a038
. [all data]
Binder and Flath, 1989
Binder, R.G.; Flath, R.A.,
Volatile components of pineapple guava,
J. Agric. Food Chem., 1989, 37, 3, 734-736, https://doi.org/10.1021/jf00087a034
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.