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Bismuth ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

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Individual Reactions

(Bismuth ion (1+) bullet 2Water) + Water = (Bismuth ion (1+) bullet 3Water)

By formula: (Bi+ bullet 2H2O) + H2O = (Bi+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar58.6kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 3Water) + Water = (Bismuth ion (1+) bullet 4Water)

By formula: (Bi+ bullet 3H2O) + H2O = (Bi+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar50.2kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.3J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 4Water) + Water = (Bismuth ion (1+) bullet 5Water)

By formula: (Bi+ bullet 4H2O) + H2O = (Bi+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 5Water) + Water = (Bismuth ion (1+) bullet 6Water)

By formula: (Bi+ bullet 5H2O) + H2O = (Bi+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet Water) + Water = (Bismuth ion (1+) bullet 2Water)

By formula: (Bi+ bullet H2O) + H2O = (Bi+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar74.1kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 2Ammonia) + Ammonia = (Bismuth ion (1+) bullet 3Ammonia)

By formula: (Bi+ bullet 2H3N) + H3N = (Bi+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar56.1kJ/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KHPMSCastleman, 1978gas phase; M

(Bismuth ion (1+) bullet Ammonia) + Ammonia = (Bismuth ion (1+) bullet 2Ammonia)

By formula: (Bi+ bullet H3N) + H3N = (Bi+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar97.1kJ/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar138.J/mol*KHPMSCastleman, 1978gas phase; M

Bismuth ion (1+) + Water = (Bismuth ion (1+) bullet Water)

By formula: Bi+ + H2O = (Bi+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar95.4kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KHPMSTang and Castleman, 1974gas phase; M

Bismuth ion (1+) + Ammonia = (Bismuth ion (1+) bullet Ammonia)

By formula: Bi+ + H3N = (Bi+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar149.kJ/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar149.J/mol*KHPMSCastleman, 1978gas phase; M

Bismuth ion (1+) + Benzene = (Bismuth ion (1+) bullet Benzene)

By formula: Bi+ + C6H6 = (Bi+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar<149.kJ/molPDisWilley, Yeh, et al., 1992RCD

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tang and Castleman, 1974
Tang, I.N.; Castleman, A.W., Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Bismuth Ion, J. Chem. Phys., 1974, 60, 10, 3981, https://doi.org/10.1063/1.1680846 . [all data]

Castleman, 1978
Castleman, A.W., The Properties of Clusters in the Gas Phase: Ammonia about Bi+, Rb+, and K+, Chem. Phys. Lett., 1978, 53, 3, 560, https://doi.org/10.1016/0009-2614(78)80069-4 . [all data]

Willey, Yeh, et al., 1992
Willey, K.F.; Yeh, C.S.; Robbins, D.L.; Duncan, M.A., Charge-transfer in the photodissociation of metal ion-benzene complexes, J. Phys. Chem., 1992, 96, 23, 9106, https://doi.org/10.1021/j100202a007 . [all data]


Notes

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