Bismuth ion (1+)
- Formula: Bi+
- Molecular weight: 208.97985
- IUPAC Standard InChIKey: SAPXNJKQDHJIRE-UHFFFAOYSA-N
- CAS Registry Number: 16463-30-2
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (Bi+ • 2H2O) + H2O = (Bi+ • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24.4 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ • 3H2O) + H2O = (Bi+ • 4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ • 4H2O) + H2O = (Bi+ • 5H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.5 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.7 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ • 5H2O) + H2O = (Bi+ • 6H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ • H2O) + H2O = (Bi+ • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 25.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: (Bi+ • 2H3N) + H3N = (Bi+ • 3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.4 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 26.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
By formula: (Bi+ • H3N) + H3N = (Bi+ • 2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 23.2 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 33.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
By formula: Bi+ + H2O = (Bi+ • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22.8 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 27.1 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
By formula: Bi+ + H3N = (Bi+ • H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35.5 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 35.7 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
By formula: Bi+ + C6H6 = (Bi+ • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | <35.5 | kcal/mol | PDis | Willey, Yeh, et al., 1992 | RCD |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Tang and Castleman, 1974
Tang, I.N.; Castleman, A.W.,
Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Bismuth Ion,
J. Chem. Phys., 1974, 60, 10, 3981, https://doi.org/10.1063/1.1680846
. [all data]
Castleman, 1978
Castleman, A.W.,
The Properties of Clusters in the Gas Phase: Ammonia about Bi+, Rb+, and K+,
Chem. Phys. Lett., 1978, 53, 3, 560, https://doi.org/10.1016/0009-2614(78)80069-4
. [all data]
Willey, Yeh, et al., 1992
Willey, K.F.; Yeh, C.S.; Robbins, D.L.; Duncan, M.A.,
Charge-transfer in the photodissociation of metal ion-benzene complexes,
J. Phys. Chem., 1992, 96, 23, 9106, https://doi.org/10.1021/j100202a007
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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