Bismuth ion (1+)
- Formula: Bi+
- Molecular weight: 208.97985
- IUPAC Standard InChI: InChI=1S/Bi/q+1
- IUPAC Standard InChIKey: SAPXNJKQDHJIRE-UHFFFAOYSA-N
- CAS Registry Number: 16463-30-2
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
( • 2
) +
= (
• 3
)
By formula: (Bi+ • 2H2O) + H2O = (Bi+ • 3H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 14.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 24.4 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 3
) +
= (
• 4
)
By formula: (Bi+ • 3H2O) + H2O = (Bi+ • 4H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 12.0 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 4
) +
= (
• 5
)
By formula: (Bi+ • 4H2O) + H2O = (Bi+ • 5H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 10.5 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 22.7 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 5
) +
= (
• 6
)
By formula: (Bi+ • 5H2O) + H2O = (Bi+ • 6H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 9.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 23.6 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( •
) +
= (
• 2
)
By formula: (Bi+ • H2O) + H2O = (Bi+ • 2H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 17.7 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 25.5 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
( • 2
) +
= (
• 3
)
By formula: (Bi+ • 2H3N) + H3N = (Bi+ • 3H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13.4 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 26.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
( •
) +
= (
• 2
)
By formula: (Bi+ • H3N) + H3N = (Bi+ • 2H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 23.2 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 33.0 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
+
= (
•
)
By formula: Bi+ + H2O = (Bi+ • H2O)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 22.8 | kcal/mol | HPMS | Tang and Castleman, 1974 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 27.1 | cal/mol*K | HPMS | Tang and Castleman, 1974 | gas phase; M |
+
= (
•
)
By formula: Bi+ + H3N = (Bi+ • H3N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 35.5 | kcal/mol | HPMS | Castleman, 1978 | gas phase; M |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrS° | 35.7 | cal/mol*K | HPMS | Castleman, 1978 | gas phase; M |
+
= (
•
)
By formula: Bi+ + C6H6 = (Bi+ • C6H6)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | <35.5 | kcal/mol | PDis | Willey, Yeh, et al., 1992 | RCD |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Tang and Castleman, 1974
Tang, I.N.; Castleman, A.W.,
Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Bismuth Ion,
J. Chem. Phys., 1974, 60, 10, 3981, https://doi.org/10.1063/1.1680846
. [all data]
Castleman, 1978
Castleman, A.W.,
The Properties of Clusters in the Gas Phase: Ammonia about Bi+, Rb+, and K+,
Chem. Phys. Lett., 1978, 53, 3, 560, https://doi.org/10.1016/0009-2614(78)80069-4
. [all data]
Willey, Yeh, et al., 1992
Willey, K.F.; Yeh, C.S.; Robbins, D.L.; Duncan, M.A.,
Charge-transfer in the photodissociation of metal ion-benzene complexes,
J. Phys. Chem., 1992, 96, 23, 9106, https://doi.org/10.1021/j100202a007
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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