Stannane, trimethyl(trimethylgermyl)-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C6H18GeSn+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.1PESzepes, Koranyi, et al., 1981LLK
8.20 ± 0.10EILappert, Pedley, et al., 1971LLK
8.36PEMochida, Worley, et al., 1985Vertical value; LBLHLM
8.33 ± 0.05PESzepes, Koranyi, et al., 1981Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H9Ge+10.01 ± 0.18(CH3)3SnEILappert, Pedley, et al., 1971LLK
C3H9Ge+10.01 ± 0.18?EILappert, Simpson, et al., 1969RDSH
C3H9Sn+9.85 ± 0.22(CH3)3GeEILappert, Pedley, et al., 1971LLK
C3H9Sn+9.85 ± 0.22?EILappert, Simpson, et al., 1969RDSH
C6H18GeSn+8.20 ± 0.10?EILappert, Simpson, et al., 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Szepes, Koranyi, et al., 1981
Szepes, L.; Koranyi, T.; Naray-Szabo, G.; Modelli, A.; Distefano, G., Ultraviolet photoelectron spectra of group IV hexamethyl derivatives containing a metal-metal bond, J. Organomet. Chem., 1981, 217, 35. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Mochida, Worley, et al., 1985
Mochida, K.; Worley, S.; Kochi, J., UV photoelectron spectra of peralkylated catenates of Group 4B elements (silicon, germanium, and tin), Bull. Chem. Soc. Jpn., 1985, 58, 3389. [all data]

Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals, J.Organometal. Chem., 1969, 17, PI. [all data]


Notes

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