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Stannane, trimethyl-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess

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Individual Reactions

C3H10Sn (g) = Hydrogen atom (g) + Trimethyltin (g)

By formula: C3H10Sn (g) = H (g) + C3H9Sn (g)

Quantity Value Units Method Reference Comment
Deltar312. ± 11.kJ/molICRBrinkman, Salomon, et al., 1995The reaction enthalpy was derived from the acidity of Sn(Me)3(H)(g), 1460.2 ± 8.4 kJ/mol, the electron affinity of Sn(Me)3(g), 164.0 ± 6.3 kJ/mol Brinkman, Salomon, et al., 1995, and the ionization energy of H(g), 1312.0 kJ/mol Lias, Bartmess, et al., 1988.; MS

C3H9Sn- + Hydrogen cation = C3H10Sn

By formula: C3H9Sn- + H+ = C3H10Sn

Quantity Value Units Method Reference Comment
Deltar1461. ± 8.8kJ/molG+TSBrinkman, Salomon, et al., 1995gas phase; Acidity between MeCO2H and PhOH; B
Quantity Value Units Method Reference Comment
Deltar1431. ± 8.4kJ/molIMRBBrinkman, Salomon, et al., 1995gas phase; Acidity between MeCO2H and PhOH; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Salomon, et al., 1995
Brinkman, E.A.; Salomon, K.; Tumas, W.; Brauman, J.I., Electron affinities and gas-phase acidities of organogermanium and organotin compounds, J. Am. Chem. Soc., 1995, 117, 17, 4905, https://doi.org/10.1021/ja00122a022 . [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-Phase Ion and Neutral Thermochemistry, J. Phys. Chem. Ref. Data, 1988, 17, Suppl. 1. [all data]


Notes

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