Cyclopropane, 1,1-dimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-1.97 ± 0.28kcal/molCcbGood, Moore, et al., 1974ALS

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
8.25350.Thermodynamics Research Center, 1997p=1 bar. Selected values are lower than other statistically calculated values [ Kabo G.Y., 1973] up to 2.2 and 1.1 J/mol*K for S(T) and Cp(T), respectively.; GT
11.02100.
14.45150.
17.88200.
23.43273.15
25.423298.15
25.571300.
33.289400.
39.955500.
45.483600.
50.105700.
54.037800.
57.416900.
60.3371000.
62.8681100.
65.0651200.
66.9721300.
68.6281400.
70.0741500.
72.941750.
75.022000.
76.582250.
77.752500.
78.632750.
79.353000.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-7.97 ± 0.19kcal/molCcbGood, Moore, et al., 1974 
Quantity Value Units Method Reference Comment
Δcliquid-803.86 ± 0.17kcal/molCcbGood, Moore, et al., 1974Corresponding Δfliquid = -7.97 kcal/mol (simple calculation by NIST; no Washburn corrections)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, Moore, et al., 1974
Good, W.D.; Moore, R.T.; Osborn, A.G.; Douslin, D.R., The enthalpies of formation of ethylcyclobutane, methylenecyclobutane, and 1,1-dimethylcyclopropane, J. Chem. Thermodyn., 1974, 6, 303-310. [all data]

Thermodynamics Research Center, 1997
Thermodynamics Research Center, Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]

Kabo G.Y., 1973
Kabo G.Y., Thermodynamic properties of some hydrocarbons containing three-membered rings, Vestn. Beloruss. Univ., Ser. 2, 1973, 3-6. [all data]


Notes

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