3-(Methylsulphonyl)-1-propene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-305. ± 3.kJ/molCcrBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure
Δfgas-305.6 ± 2.8kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -308. ± 2. kJ/mol; see Busfield, Mackle, et al., 1961

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-385.1 ± 1.1kJ/molCcrBusfield, Mackle, et al., 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -384.7 ± 1.1 kJ/mol; Heat of combustion corrected for constant pressure
Δfliquid-385.1 ± 1.1kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -386. ± 1. kJ/mol; see Busfield, Mackle, et al., 1961
Quantity Value Units Method Reference Comment
Δcliquid-2934.6 ± 0.63kJ/molCcrBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap79. ± 3.kJ/molEBusfield, Mackle, et al., 1961Heat of combustion corrected for constant pressure; ALS
Δvap-79.5 ± 2.5kJ/molVMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = 79. ± 1. kJ/mol; see Busfield, Mackle, et al., 1961; ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
68.2420.AStephenson and Malanowski, 1987Based on data from 405. to 450. K. See also Dykyj, Svoboda, et al., 1999.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Busfield, Mackle, et al., 1961
Busfield, W.K.; Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 2 - The standard heats of formation of sulphones of the type RSO2CH3, Trans. Faraday Soc., 1961, 57, 1054-1057. [all data]

Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 6 - Heats of combustion, fusion, vaporization and atomization of six aromatic and two allylic sulphones, Trans. Faraday Soc., 1961, 57, 1521-1526. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]


Notes

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