3-(Methylsulphonyl)-1-propene
- Formula: C4H8O2S
- Molecular weight: 120.170
- IUPAC Standard InChI: InChI=1S/C4H8O2S/c1-3-4-7(2,5)6/h3H,1,4H2,2H3
- IUPAC Standard InChIKey: WOPDMJYIAAXDMN-UHFFFAOYSA-N
- CAS Registry Number: 16215-14-8
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -305. ± 3. | kJ/mol | Ccr | Busfield, Mackle, et al., 1961 | Heat of combustion corrected for constant pressure |
| ΔfH°gas | -305.6 ± 2.8 | kJ/mol | Ccb | Mackle and O'Hare, 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = -308. ± 2. kJ/mol; see Busfield, Mackle, et al., 1961 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -385.1 ± 1.1 | kJ/mol | Ccr | Busfield, Mackle, et al., 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = -384.7 ± 1.1 kJ/mol; Heat of combustion corrected for constant pressure |
| ΔfH°liquid | -385.1 ± 1.1 | kJ/mol | Ccb | Mackle and O'Hare, 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = -386. ± 1. kJ/mol; see Busfield, Mackle, et al., 1961 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -2934.6 ± 0.63 | kJ/mol | Ccr | Busfield, Mackle, et al., 1961 | Heat of combustion corrected for constant pressure |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 79. ± 3. | kJ/mol | E | Busfield, Mackle, et al., 1961 | Heat of combustion corrected for constant pressure; ALS |
| ΔvapH° | -79.5 ± 2.5 | kJ/mol | V | Mackle and O'Hare, 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = 79. ± 1. kJ/mol; see Busfield, Mackle, et al., 1961; ALS |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 68.2 | 420. | A | Stephenson and Malanowski, 1987 | Based on data from 405. to 450. K. See also Dykyj, Svoboda, et al., 1999.; AC |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Busfield, Mackle, et al., 1961
Busfield, W.K.; Mackle, H.; O'Hare, P.A.G.,
Studies in the thermochemistry of sulphones. Part 2 - The standard heats of formation of sulphones of the type RSO2CH3,
Trans. Faraday Soc., 1961, 57, 1054-1057. [all data]
Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G.,
Studies in the thermochemistry of sulphones. Part 6 - Heats of combustion, fusion, vaporization and atomization of six aromatic and two allylic sulphones,
Trans. Faraday Soc., 1961, 57, 1521-1526. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R.,
Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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