1-Propene, 1-chloro-, (Z)-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

trans-1-Chloropropene = 1-Propene, 1-chloro-, (Z)-

By formula: C3H5Cl = C3H5Cl

Quantity Value Units Method Reference Comment
Δr-0.7 ± 0.064kcal/molEqkShevtsova and Andreevskii, 1971gas phase; Heat of isomerization

1-Propene, 1-chloro-, (Z)- = trans-1-Chloropropene

By formula: C3H5Cl = C3H5Cl

Quantity Value Units Method Reference Comment
Δr0.76 ± 0.03kcal/molCisoAbell and Adolf, 1969gas phase; HBr catalyst

1-Propene, 1-chloro-, (Z)- = Allyl chloride

By formula: C3H5Cl = C3H5Cl

Quantity Value Units Method Reference Comment
Δr3.5 ± 0.2kcal/molEqkAlfassi, Golden, et al., 1973liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shevtsova and Andreevskii, 1971
Shevtsova, L.A.; Andreevskii, D.N., Cis-trans isomerization of 1-chloro-1-propene, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1971, 15, 718-720. [all data]

Abell and Adolf, 1969
Abell, P.I.; Adolf, P.K., HBr catalyzed photoisomerization of allyl halides, J. Chem. Thermodyn., 1969, 1, 333-338. [all data]

Alfassi, Golden, et al., 1973
Alfassi, Z.B.; Golden, D.M.; Benson, S.W., The thermochemistry of the isomerization of 3-halopropenes (allyl halides) to 1-halopropenes; entropy and enthalpy of formation contribution of the Cd-(H)(X) group, J. Chem. Thermodyn., 1973, 5, 411-420. [all data]


Notes

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