Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Dimethylgermathione


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CH3 deform. 1407 Ar IR Khabashesku, Boganov, et al., 1991
4 CH3 deform. 1237 Ar IR Khabashesku, Boganov, et al., 1991
5 CH3 rock 850 s Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
6 Ge=S stretch 605 vs Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
7 GeC s-stretch 516 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
b1 14 CH3 a-deform. 1390 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
15 CH3 deform 761 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
b2 21 CH3 deform 1229 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
22 CH3 rock 809 Ar IR Khabashesku, Boganov, et al., 1991
23 GeC a-stretch 574 Ar IR Khabashesku, Boganov, et al., 1991

Additional references: Jacox, 2003, page 391

Notes

mMedium
sStrong
vsVery strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Khabashesku, Boganov, et al., 1991
Khabashesku, V.N.; Boganov, S.E.; Zuev, P.S.; Nefedov, O.M., et al., Direct study of unstable dimethylgermathione, Me2Ge«58875»S, by vacuum pyrolysis-MS and low temperature matrix IR spectroscopy, J. Organomet. Chem., 1991, 402, 2, 161, https://doi.org/10.1016/0022-328X(91)83060-H . [all data]

Barrau, Balaji, et al., 1989
Barrau, J.; Balaji, V.; Michl, J., Matrix isolation and IR spectroscopy of germanethione Me2Ge:S, Organomet., 1989, 8, 8, 2034, https://doi.org/10.1021/om00110a033 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References