Thiazyl trifluoride
- Formula: F3NS
- Molecular weight: 103.067
- IUPAC Standard InChI: InChI=1S/F3NS/c1-5(2,3)4
- IUPAC Standard InChIKey: UQUPGRNSXINWBS-UHFFFAOYSA-N
- CAS Registry Number: 15930-75-3
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.46 ± 0.03 | EI | Glemser, Muller, et al., 1968 | RDSH |
| 12.50 | PE | Cowan, Gleiter, et al., 1972 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| FNS+ | 16.82 ± 0.05 | ? | EI | Glemser, Muller, et al., 1968 | RDSH |
| F2NS+ | 15.47 ± 0.04 | F | EI | Glemser, Muller, et al., 1968 | RDSH |
| F2S+ | 15.70 ± 0.05 | ? | EI | Glemser, Muller, et al., 1968 | RDSH |
| F3S+ | 13.46 ± 0.03 | N | EI | Glemser, Muller, et al., 1968 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Glemser, Muller, et al., 1968
Glemser, O.; Muller, A.; Bohler, D.; Krebs, B.,
Die N-S-Bindung: Bindungslangen Kraftkonstanten, Bindungsgrade und Bindungsenergien,
Z. Anorg. Allgem. Chem., 1968, 357, 184. [all data]
Cowan, Gleiter, et al., 1972
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E.,
The photoelectron spectra of NSCl, NSF NSF3,
Helv. Chim. Acta, 1972, 55, 2418. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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