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Cyclopentane, 1,2,3-trimethyl-, (1«alpha»,2«alpha»,3«beta»)-

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Phase change data

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil390.7KN/AGlasgow, Gordon, et al., 1957Uncertainty assigned by TRC = 2. K; TRC
Tboil391.3KN/AKoperina and Kazanskii, 1948Uncertainty assigned by TRC = 0.7 K; TRC
Tboil390.35KN/AFenske, Braun, et al., 1947Uncertainty assigned by TRC = 0.3 K; TRC
Tboil391.3KN/AKazanskii, Koperina, et al., 1947Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tfus160.25KN/AStreiff, Murphy, et al., 1946Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap38.1kJ/molN/AReid, 1972AC

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Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 1607

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Gas Chromatography

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-1010.738.Skrbic, 1997 
CapillaryCP Sil 260.750.8Estel, Mohnke, et al., 1995100. m/0.25 mm/0.25 «mu»m
CapillaryOV-10140.744.Laub and Purnell, 1988 
CapillaryOV-10160.748.Laub and Purnell, 1988 
CapillaryOV-10180.753.Laub and Purnell, 1988 
CapillarySqualane50.777.9Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillarySqualane70.782.7Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillaryNonpolar45.747.Stoyanov and Dimov, 1987 
CapillaryNonpolar52.5748.Stoyanov and Dimov, 1987 
CapillaryNonpolar60.750.Stoyanov and Dimov, 1987 
CapillaryOV-10140.745.3Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
CapillaryOV-10150.747.1Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
CapillaryOV-10160.748.9Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
CapillaryOV-10170.750.9Boneva and Dimov, 1986100. m/0.27 mm/0.9 «mu»m
CapillarySqualane50.747.8Krupcik, Cellar, et al., 1986Column length: 180. m; Column diameter: 0.25 mm
CapillarySqualane50.778.8Krupcik, Cellar, et al., 1986Column length: 180. m; Column diameter: 0.25 mm
CapillaryOV-10130.742.Chien, Furio, et al., 1983 
CapillaryOV-10140.744.Chien, Furio, et al., 1983 
CapillaryOV-10150.746.Chien, Furio, et al., 1983 
CapillaryOV-10160.748.Chien, Furio, et al., 1983 
CapillaryOV-10170.750.Chien, Furio, et al., 1983 
CapillaryOV-10180.752.Chien, Furio, et al., 1983 
CapillaryDB-160.779.Lubeck and Sutton, 1983Column length: 60. m; Column diameter: 0.264 mm
CapillaryDB-160.779.2Lubeck and Sutton, 198360. m/0.259 mm/1. «mu»m
CapillaryDB-160.749.4Lubeck and Sutton, 1983Column length: 60. m; Column diameter: 0.264 mm
CapillaryDB-160.749.6Lubeck and Sutton, 198360. m/0.259 mm/1. «mu»m
CapillaryOV-10150.747.Johansen and Ettre, 1982100. m/0.27 mm/0.20 «mu»m
CapillaryOV-10150.747.Johansen and Ettre, 198255. m/0.27 mm/0.9 «mu»m
CapillarySF-9650.747.Johansen and Ettre, 198291.4 m/0.31 mm/0.20 «mu»m
CapillarySqualane70.783.1Nabivach and Kirilenko, 1979N2; Column length: 50. m
CapillarySqualane100.738.4Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
CapillarySqualane100.780.2Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
CapillaryVacuum Grease Oil (VM-4)35.772.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)45.775.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)50.776.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)58.779.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)68.782.Sidorov, Petrova, et al., 1972 
PackedVacuum Grease Oil (VM-4)35.775.Sidorov, Ivanova, et al., 1971 
PackedSE-30130.798.Mitra and Saha, 1970N2, Chromosorb W; Column length: 6.1 m
PackedSqualane27.774.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane49.779.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane67.783.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane86.788.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryPetrocol DH-100772.7Haagen-Smit Laboratory, 1997He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min)

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-101775.0Yin, Liu, et al., 2001N2, 1. K/min; Column length: 80. m; Column diameter: 0.22 mm; Tstart: 30. C; Tend: 130. C
CapillaryOV-101744.9Yin, Liu, et al., 2001N2, 1. K/min; Column length: 80. m; Column diameter: 0.22 mm; Tstart: 30. C; Tend: 130. C
CapillaryPetrocol DH742.04Subramaniam, Bochniak, et al., 1994100. m/0.25 mm/0.5 «mu»m, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryUltra-1774.Olson, Sinkevitch, et al., 19924. K/min; Tstart: -40. C; Tend: 230. C

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySqualane100.789.Krupcik, Cellar, et al., 1986, 2Column length: 180. m; Column diameter: 0.25 mm
CapillarySqualane40.776.Krupcik, Cellar, et al., 1986, 2Column length: 180. m; Column diameter: 0.25 mm
CapillarySqualane70.783.Krupcik, Cellar, et al., 1986, 2Column length: 180. m; Column diameter: 0.25 mm
CapillarySqualane100.756.Krupcik, Cellar, et al., 1986, 2Column length: 180. m; Column diameter: 0.25 mm
CapillarySqualane40.746.Krupcik, Cellar, et al., 1986, 2Column length: 180. m; Column diameter: 0.25 mm
CapillarySqualane70.751.Krupcik, Cellar, et al., 1986, 2Column length: 180. m; Column diameter: 0.25 mm
CapillarySqualane86.743.Vigdergauz and Martynov, 1971He; Column length: 150. m; Column diameter: 0.35 mm
CapillarySqualane86.780.Vigdergauz and Martynov, 1971He; Column length: 150. m; Column diameter: 0.35 mm
CapillarySqualane86.736.Vigdergauz and Martynov, 1971He; Column length: 150. m; Column diameter: 0.35 mm

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillarySqualane747.2Krupcik, Cellar, et al., 19860.1 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane748.1Krupcik, Cellar, et al., 19860.2 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane749.5Krupcik, Cellar, et al., 19860.4 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane750.7Krupcik, Cellar, et al., 19860.6 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane751.6Krupcik, Cellar, et al., 19860.8 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane752.7Krupcik, Cellar, et al., 19861. K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane778.2Krupcik, Cellar, et al., 19860.1 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane779.6Krupcik, Cellar, et al., 19860.2 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane781.9Krupcik, Cellar, et al., 19860.4 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane783.7Krupcik, Cellar, et al., 19860.6 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane785.2Krupcik, Cellar, et al., 19860.8 K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane786.5Krupcik, Cellar, et al., 19861. K/min; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane778.Krupcik, Cellar, et al., 1986, 20.1 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane775.Krupcik, Cellar, et al., 1986, 20.2 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane782.Krupcik, Cellar, et al., 1986, 20.4 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane783.Krupcik, Cellar, et al., 1986, 20.6 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane785.Krupcik, Cellar, et al., 1986, 20.8 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane786.Krupcik, Cellar, et al., 1986, 21.0 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane747.Krupcik, Cellar, et al., 1986, 20.1 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane748.Krupcik, Cellar, et al., 1986, 20.2 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane749.Krupcik, Cellar, et al., 1986, 20.4 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane750.Krupcik, Cellar, et al., 1986, 20.6 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane751.Krupcik, Cellar, et al., 1986, 20.8 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C
CapillarySqualane752.Krupcik, Cellar, et al., 1986, 21.0 K/min; Column length: 180. m; Column diameter: 0.25 mm; Tstart: 40. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryMethyl Silicone772.Spieksma, 1999Program: not specified

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Glasgow, Gordon, et al., 1957
Glasgow, A.R.; Gordon, R.J.; Willingham, C.B.; Mair, B.J.; Rossini, F.D., Hydrocarbons in the 116 deg C to 126 deg C Fraction of Petroleum, Anal. Chem., 1957, 29, 357. [all data]

Koperina and Kazanskii, 1948
Koperina, A.V.; Kazanskii, B.A., 1,2,3-TRimethylcyclpentane, Izv. Akad. Nauk S.S.S.R., 1948, 1948, 302-10. [all data]

Fenske, Braun, et al., 1947
Fenske, M.R.; Braun, W.G.; Wiegand, R.V.; Quiggle, D.; McCormick, R.H.; Rank, D.H., Raman Spectra of Hydrocarbons, Anal. Chem., 1947, 19, 700. [all data]

Kazanskii, Koperina, et al., 1947
Kazanskii, B.A.; Koperina, A.V.; Batu'ev, M.I., Synthesis and Properties of Stereoisomeric 1,2,4-Trimethylcyclopentanes, Doklady Akad. Nauk S.S.S.R., 1947, 56, 819-22. [all data]

Streiff, Murphy, et al., 1946
Streiff, A.J.; Murphy, E.T.; Cahill, J.C.; Soule, L.F.; Sedlak, V.A.; Willingham, C.B.; Rossini, F.D., , Am. Pet. Inst. Res. Proj. 6, unpublished, Natl. Bur. Stand., 1946. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Skrbic, 1997
Skrbic, B.D., Unified retention concept -- statistical treatment of Kováts retention index, J. Chromatogr. A, 1997, 764, 2, 257-264, https://doi.org/10.1016/S0021-9673(96)00955-7 . [all data]

Estel, Mohnke, et al., 1995
Estel, D.; Mohnke; Biermans; Rotzsche, The analysis of C4-C11 hydrocarbons in naphtha and reformate with a new apolar fused silica column, J. Hi. Res. Chromatogr., 1995, 18, 7, 403-412, https://doi.org/10.1002/jhrc.1240180703 . [all data]

Laub and Purnell, 1988
Laub, R.J.; Purnell, J.H., Specific retention volumes, retention indices, and family-plot regressions of aliphatic, alicyclic, and aromatic hydrocarbon solutes with OV-101 poly (dimethylsiloxane) stationary phase, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1988, 11, 9, 649-660, https://doi.org/10.1002/jhrc.1240110908 . [all data]

Lunskii and Paizanskaya, 1988
Lunskii, M.Kh.; Paizanskaya, I.L., Identification of hydrocarbons C1-C9 of petrol fractions of oils and condensates in the use of capillary columns with dinonylphthalate, Zh. Anal. Khim., 1988, 43, 127-135. [all data]

Stoyanov and Dimov, 1987
Stoyanov, E.; Dimov, N., Precalculation of the optimum column temperature for gas chromatographic separation of petroleum fractions, Anal. Chim. Acta., 1987, 201, 207-216, https://doi.org/10.1016/S0003-2670(00)85338-6 . [all data]

Boneva and Dimov, 1986
Boneva, S.; Dimov, N., Unified retention index of hydrocarbons separated on dimethylsilicone OV-101, Chromatographia, 1986, 21, 12, 697-700, https://doi.org/10.1007/BF02313682 . [all data]

Krupcik, Cellar, et al., 1986
Krupcik, J.; Cellar, P.; Repka, D.; Garaj, J.; Guiochon, G., Use of Kováts retention indices for characterization of solutes in linear temperature-programmed capillary gas-liquid chromatography, J. Chromatogr., 1986, 351, 111-121, https://doi.org/10.1016/S0021-9673(01)83477-4 . [all data]

Chien, Furio, et al., 1983
Chien, C.-F.; Furio, D.L.; Kopecni, M.M.; Laub, R.J., Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-101 and SP-2100 Polydimethylsiloxane Solvents, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 10, 577-580, https://doi.org/10.1002/jhrc.1240061013 . [all data]

Lubeck and Sutton, 1983
Lubeck, A.J.; Sutton, DL., Kovats retention indices of selected hydrocarbons through C10 on bonded phase fused silica capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 6, 328-332, https://doi.org/10.1002/jhrc.1240060612 . [all data]

Johansen and Ettre, 1982
Johansen, N.G.; Ettre, L.S., Retention index values of hydrocarbons on open-tubular columns coated with methylsilicone liquid phases, Chromatographia, 1982, 15, 10, 625-630, https://doi.org/10.1007/BF02279488 . [all data]

Nabivach and Kirilenko, 1979
Nabivach, V.M.; Kirilenko, A.V., The use of retention indices for identifying the components of crude benzene, Solid Fuel Chem. (Engl. Transl.), 1979, 13, 3, 82-87. [all data]

Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N., Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]

Sidorov, Petrova, et al., 1972
Sidorov, R.I.; Petrova, V.I.; Ivanova, M.P., Qualitative analysis of wide-boiling fraction C5-C10 with capillary chromatography in Processes in chromatographic columns. Vol.17, 1972, 14-25. [all data]

Sidorov, Ivanova, et al., 1971
Sidorov, R.I.; Ivanova, M.P.; Petrova, V.I., Temperature dependence of cycloalkane's retention and its using in identification of structure, Gazovaya Khromatografiya, 1971, 15, 18-26. [all data]

Mitra and Saha, 1970
Mitra, G.D.; Saha, N.C., Determination of Retention Indices of Saturated Hydrocarbons by Graphical Methods, J. Chromatogr. Sci., 1970, 8, 2, 95-102, https://doi.org/10.1093/chromsci/8.2.95 . [all data]

Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E., Variation of the retention index with temperature on squalane substrates, J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203 . [all data]

Haagen-Smit Laboratory, 1997
Haagen-Smit Laboratory, Procedure for the detailed hydrocarbon analysis of gasolines by single column high efficiency (capillary) column gas chromatography, SOP NO. MLD 118, Revision No. 1.1, California Environmental Protection Agency, Air Resources Board, El Monte, California, 1997, 22. [all data]

Yin, Liu, et al., 2001
Yin, C.; Liu, W.; Li, Z.; Pan, Z.; Lin, T.; Zhang, M., Chemometrics to chemical modeling: structural coding in hydrocarbons and retention indices of gas chromatography, J. Sep. Sci., 2001, 24, 3, 213-220, https://doi.org/10.1002/1615-9314(20010301)24:3<213::AID-JSSC213>3.0.CO;2-4 . [all data]

Subramaniam, Bochniak, et al., 1994
Subramaniam, B.; Bochniak, D.; Snavely, K., Fischer-Tropsch synthesis in supercritical reaction media, Lawrence Department of Chemical and Petroleum Engineering (DOE/PC/92532--T7), United States Department of Energy, Pittsburgh, PA, 1994, 8, retrieved from http://www.NTIS.gov. [all data]

Olson, Sinkevitch, et al., 1992
Olson, K.L.; Sinkevitch, R.M.; Sloane, T.M., Speciation and Quantitation of Hydrocarbons in Gasoline Engine Exhaust, J. Chromatogr. Sci., 1992, 30, 12, 500-508, https://doi.org/10.1093/chromsci/30.12.500 . [all data]

Krupcik, Cellar, et al., 1986, 2
Krupcik, J.; Cellar, P.; Repka, D., Analyza cyklickych a aromatickych uhlovodnikov s poctom uhlikovych atomov 8 kapilarnou plynovou chromatografiou, Ropa a Uhlie, 1986, 28, 8, 485-495. [all data]

Vigdergauz and Martynov, 1971
Vigdergauz, M.S.; Martynov, A.A., Some applications of the gas chromatographic linear retention indices, Chromatographia, 1971, 4, 10, 463-467, https://doi.org/10.1007/BF02268816 . [all data]

Spieksma, 1999
Spieksma, W., Determination of vapor liquid equilibrium from the Kovats retention index on dimethylsilicone using the Wilson mixing tool, J. Hi. Res. Chromatogr., 1999, 22, 10, 565-588, https://doi.org/10.1002/(SICI)1521-4168(19991001)22:10<565::AID-JHRC565>3.0.CO;2-2 . [all data]


Notes

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References