Vanadium,tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-o,o')-,(oc-6-11)-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
3.166 ± 0.087IMRESharpe, Eyler, et al., 1990EA given is actually -ΔGea(350 K); B

Ionization energy determinations

IE (eV) Method Reference Comment
8.68PEEvans, Hamnett, et al., 1972Vertical value; LLK
8.68 ± 0.07PEEvans, Hamnett, et al., 1972, 2Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharpe, Eyler, et al., 1990
Sharpe, P.; Eyler, J.R.; Richardson, D.E., Free Energies of Electron Attachment to Tris(acetylacetonate) and Tris(hexafluoroacetylacetonate) Transition-Metal Complexes in the Gas Phase: Experimental Results and Ligand Field Analysis, Inorg. Chem., 1990, 29, 15, 2779, https://doi.org/10.1021/ic00340a014 . [all data]

Evans, Hamnett, et al., 1972
Evans, S.; Hamnett, A.; Orchard, A.F., The relative orbital energies of metal ligand electrons in some tris(hexafluoroacetylacetonato) transition-metal complexes, J. Coord. Chem., 1972, 2, 57. [all data]

Evans, Hamnett, et al., 1972, 2
Evans, S.; Hamnett, A.; Orchard, A.F.; Lloyd, D.R., Study of the metal-oxygen bond in simple tris-chelate complexes by He(I) photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 227. [all data]


Notes

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