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Ethylene, 1,2-dichloro-, (Z)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil333.5KN/AWeast and Grasselli, 1989BS
Tboil333.5KN/AAmaya, 1961Uncertainty assigned by TRC = 0.4 K; TRC
Tboil333.2KN/AAndrews and Keefer, 1951Uncertainty assigned by TRC = 0.6 K; TRC
Tboil333.5KN/AMaryott, Hobbs, et al., 1941Uncertainty assigned by TRC = 0.3 K; TRC
Tboil333.0KN/AAwbery and Griffiths, 1936Uncertainty assigned by TRC = 2. K; estimate based on distillation curve; TRC
Quantity Value Units Method Reference Comment
Tfus193.KN/ABroers, Ketelaar, et al., 1950Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Deltavap7.4 ± 0.2kcal/molReviewManion, 2002adopted Cox and Pilcher, 1970 recommendation plus a correction for non-ideality; DRB
Deltavap7.385kcal/molVKetelaar, Van Velden, et al., 1947ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
7.60288.N/AKetelaar, van Velden, et al., 2010Based on data from 273. - 356. K.; AC
7.00347.AStephenson and Malanowski, 1987Based on data from 332. - 495. K.; AC
7.53288.AStephenson and Malanowski, 1987Based on data from 273. - 334. K. See also Dykyj, 1970.; AC
7.55307.N/AFlom, Alpert, et al., 1951Based on data from 292. - 335. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
273.91 - 356.784.06331163.729-47.174Ketelaar, van Velden, et al., 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Amaya, 1961
Amaya, K., Thermodynamical studies on bionary systems consisting of polar and non-polar liquids. II. the measurement of the heats of mixing for binary systems of polar and non-polar liquids, Bull. Chem. Soc. Jpn., 1961, 34, 1278. [all data]

Andrews and Keefer, 1951
Andrews, L.J.; Keefer, R.M., The Argentation of Organic Iodides, J. Am. Chem. Soc., 1951, 73, 5733-5736. [all data]

Maryott, Hobbs, et al., 1941
Maryott, A.A.; Hobbs, M.E.; Gross, P.M., Bond Moment Additivity and the Electric Moments of Some Halogenated Hydrocarbons, J. Am. Chem. Soc., 1941, 63, 659. [all data]

Awbery and Griffiths, 1936
Awbery, J.H.; Griffiths, E., The Viscosities of Some Liquid Refrigerants, Proc. Phys. Soc. London, 1936, 48, 372-80. [all data]

Broers, Ketelaar, et al., 1950
Broers, G.H.J.; Ketelaar, J.A.A.; Van Velden, P.F., Melting-point Diagram and Hets of Fusion of cis- and trans-1,2-Dichloro-ethene, Recl. Trav. Chim. Pays-Bas, 1950, 69, 1122. [all data]

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic, London, 1970, 636. [all data]

Ketelaar, Van Velden, et al., 1947
Ketelaar, J.A.A.; Van Velden, P.F.; Zalm, P., Vapour pressures and heats of vaporization of cis- and trans-1,2-dichloroethene, Rec. Trav. Chim. Pays/Bas, 1947, 66, 27. [all data]

Ketelaar, van Velden, et al., 2010
Ketelaar, J.A.A.; van Velden, P.F.; Zalm, P., Vapour pressures and heats of vaporization of cis- and trans-1,2-dichloroethene, Recl. Trav. Chim. Pays-Bas, 2010, 66, 12, 721-732, https://doi.org/10.1002/recl.19470661202 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Flom, Alpert, et al., 1951
Flom, Donald G.; Alpert, Norman; Elving, Philip J., Systems Involving cis-or trans-Dichloroethylene and an Acetal or Ether, Ind. Eng. Chem., 1951, 43, 5, 1178-1181, https://doi.org/10.1021/ie50497a051 . [all data]

Ketelaar, van Velden, et al., 1947
Ketelaar, J.A.A.; van Velden, P.F.; Zalm, P., Vapour Pressures and Heats of Vaporization of cis- and trans-1,2-Dichloroethene, Recl. Trav. Chim. Pays-Bas, 1947, 66, 12, 721-732, https://doi.org/10.1002/recl.19470661202 . [all data]


Notes

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