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Bromine monoxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to BrO+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
2.3530 ± 0.0060LPESGilles, Polak, et al., 1992B
>1.53 ± 0.22R-AVogt, Dreves, et al., 1977Br- + O2 ->; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.46 ± 0.02PIMonks, Stief, et al., 1993LL
10.29 ± 0.01PEDunlavey, Dyke, et al., 1978Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gilles, Polak, et al., 1992
Gilles, M.K.; Polak, M.L.; Lineberger, W.C., Photoelectron Spectroscopy of the Halogen Oxide Anions FO-, ClO-, BrO-, IO-, OClO-, and OIO-, J. Chem. Phys., 1992, 96, 11, 8012, https://doi.org/10.1063/1.462352 . [all data]

Vogt, Dreves, et al., 1977
Vogt, D.; Dreves, W.; Mischke, J., Energy dependence of differential cross sections in endoergic ion-molecule collision processes of negative ions, Int. J. Mass Spectrom. Ion Phys., 1977, 24, 285. [all data]

Monks, Stief, et al., 1993
Monks, P.S.; Stief, L.J.; Krauss, M.; Kuo, S.C.; Klemm, R.B., A discharge-flow photoionization mass-spectrometric study of the BrO(X 2) radical. Photoionization spectrum and ionization energy, Chem. Phys. Lett., 1993, 211, 416. [all data]

Dunlavey, Dyke, et al., 1978
Dunlavey, S.J.; Dyke, J.M.; Morris, A., The first ionization potential of the BrO(X2«pi»3/2) radical obtained using photoelectron spectroscopy, Chem. Phys. Lett., 1978, 53, 382. [all data]


Notes

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