Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

1,5-Cyclooctadiene, (Z,Z)-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas101.0 ± 1.4kJ/molCcbKozina, Timofeeva, et al., 1976 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid57.7 ± 1.4kJ/molCcbKozina, Timofeeva, et al., 1976 
Quantity Value Units Method Reference Comment
Deltacliquid-4920.8 ± 1.3kJ/molCcbKozina, Timofeeva, et al., 1976Corresponding «DELTA»fliquid = 57.70 kJ/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-4880.6kJ/molCcrRauh, Geyer, et al., 1973Corresponding «DELTA»fliquid = 18. kJ/mol (simple calculation by NIST; no Washburn corrections)

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C18H27ClRu (solution) + Benzeneethanamine, 3,4-dimethoxy- (solution) = C16H31ClP2Ru (solution) + 1,5-Cyclooctadiene, (Z,Z)- (solution)

By formula: C18H27ClRu (solution) + C10H15NO2 (solution) = C16H31ClP2Ru (solution) + C8H12 (solution)

Quantity Value Units Method Reference Comment
Deltar-145.6 ± 0.8kJ/molRSCLuo, Zhu, et al., 1994solvent: Tetrahydrofuran; The enthalpy of solution of Ru(Cp*)(cod)(Cl)(cr) was measured as 20.5 ± 0.8 kJ/mol Luo, Nolan, et al., 1993.

Nickel, bis[(1,2,5,6-η)-1,5-cyclooctadiene]- (solution) = 21,5-Cyclooctadiene, (Z,Z)- (solution) + nickel (cr)

By formula: (Ni(C8H12)2) (solution) = 2C8H12 (solution) + Ni (cr)

Quantity Value Units Method Reference Comment
Deltar-12.6 ± 4.2kJ/molRSCTolman, Reutter D.W., et al., 1976solvent: Toluene; The toluene solution contained catalytic amounts of carbon tetrachloride.

Rhodium, bis(η2-ethene)(2,4-pentanedionato-O,O')- (solution) + 1,5-Cyclooctadiene, (Z,Z)- (solution) = C13H19O2Rh (solution) + 2Ethylene (solution)

By formula: C9H15O2Rh (solution) + C8H12 (solution) = C13H19O2Rh (solution) + 2C2H4 (solution)

Quantity Value Units Method Reference Comment
Deltar-9.0 ± 0.4kJ/molRSCJesse, Cordfunke, et al., 1979solvent: n-Heptane

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Timofeeva, et al., 1976
Kozina, M.P.; Timofeeva, L.P.; Gal'chenko, G.L.; Gvozdeva, E.A.; Cherednichenko, V.M., The determination of the enthalphy of combustion of cis, cis-cyclooctadiene-1,5, Termodin. Org. Soedin., 1976, 9-11. [all data]

Rauh, Geyer, et al., 1973
Rauh, H.J.; Geyer, W.; Schmidt, H.; Geiseler, G., Bildungsenthalpien und mesomerieenergien von «pi»-bindungssystemen, Z. Phys. Chem. (Leipzig), 1973, 253, 43-48. [all data]

Luo, Zhu, et al., 1994
Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E.D.; Nolan, S.P.; Fagan, P.J., Organometallics, 1994, 13, 669. [all data]

Luo, Nolan, et al., 1993
Luo, L.; Nolan, S.P.; Fagan, P.J., Organometallics, 1993, 12, 4305. [all data]

Tolman, Reutter D.W., et al., 1976
Tolman, C.A.; Reutter D.W.; Seidel, W.C., J. Organometal. Chem., 1976, 117, C30. [all data]

Jesse, Cordfunke, et al., 1979
Jesse, A.C.; Cordfunke, E.H.P.; Ouweltjes, W., Thermochim. Acta, 1979, 30, 293. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References