dysprosium triiodide


Phase change data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub67.4 ± 0.96kcal/molTEBrunetti, Vassallo, et al., 1999Based on data from 889. - 1157. K.

Reaction thermochemistry data

Go To: Top, Phase change data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iodide + DyI3 = (Iodide • DyI3)

By formula: I- + DyI3 = (I- • DyI3)

Quantity Value Units Method Reference Comment
Δr66.7 ± 2.0kcal/molTDAsLelik, Korobov, et al., 1984gas phase; anion heat reworked from reference due to better dHf(DyI3); value altered from reference due to conversion from electron convention to ion convention

DyI4- + DyI3 = Dy2I7-

By formula: DyI4- + DyI3 = Dy2I7-

Quantity Value Units Method Reference Comment
Δr45.20 ± 0.60kcal/molTDAsLelik, Korobov, et al., 1984gas phase; reworked from reference due to better dHf(DyI3); value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

Go To: Top, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
9.6 ± 0.2EIHirayama and Castle, 1973

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Dy+16.4 ± 0.23IEIHirayama and Castle, 1973 
IDy+13.1 ± 0.22IEIHirayama and Castle, 1973 
I2Dy+10.5 ± 0.2IEIHirayama and Castle, 1973 

Ion clustering data

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

DyI4- + DyI3 = Dy2I7-

By formula: DyI4- + DyI3 = Dy2I7-

Quantity Value Units Method Reference Comment
Δr45.20 ± 0.60kcal/molTDAsLelik, Korobov, et al., 1984gas phase; reworked from reference due to better dHf(DyI3); value altered from reference due to conversion from electron convention to ion convention

Iodide + DyI3 = (Iodide • DyI3)

By formula: I- + DyI3 = (I- • DyI3)

Quantity Value Units Method Reference Comment
Δr66.7 ± 2.0kcal/molTDAsLelik, Korobov, et al., 1984gas phase; anion heat reworked from reference due to better dHf(DyI3); value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brunetti, Vassallo, et al., 1999
Brunetti, Bruno; Vassallo, Papirio; Piacente, Vincenzo; Scardala, Paolo, Vaporization Studies of Dysprosium Trichloride, Tribromide, and Triiodide, J. Chem. Eng. Data, 1999, 44, 3, 509-515, https://doi.org/10.1021/je9801821 . [all data]

Lelik, Korobov, et al., 1984
Lelik, L.; Korobov, M.V.; Kaposi, O.; Sidorov, L.N., Negative Ions in the Gas Phase of Dysprosium Triiodide and of the CsI-DyI3 and CsI-NaI-DyI3 Systems, Russ. J. Phys. Chem., 1984, 58, 1164. [all data]

Hirayama and Castle, 1973
Hirayama, C.; Castle, P.M., Mass spectra of rare earth triiodides, J. Phys. Chem., 1973, 77, 3110. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References