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ClCH2OH


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

OH stretch 3646 gas IR Wallington, Schneider, et al., 2000
OH stretch 3591 Ar IR Kunttu, Dahlqvist, et al., 1988
CH2 a-stretch 2981 Ar IR Kunttu, Dahlqvist, et al., 1988
CH2 a-stretch 2971 Ar IR Kunttu, Dahlqvist, et al., 1988
CH2 s-stretch 2913 Ar IR Kunttu, Dahlqvist, et al., 1988
COH bend 1374 gas IR Tyndall, Wallington, et al., 1993
Wallington, Schneider, et al., 2000
COH bend 1393 Ar IR Kunttu, Dahlqvist, et al., 1988
CH2 wag 1318 gas IR Tyndall, Wallington, et al., 1993
Wallington, Schneider, et al., 2000
CH2 wag 1323 Ar IR Kunttu, Dahlqvist, et al., 1988
CH2 wag 1319 Ar IR Kunttu, Dahlqvist, et al., 1988
1231 Ar IR Kunttu, Dahlqvist, et al., 1988
CH2 twist 1114 Ar IR Kunttu, Dahlqvist, et al., 1988
CO stretch 1083 gas IR Tyndall, Wallington, et al., 1993
Wallington, Schneider, et al., 2000
CO stretch 1096 Ar IR Kunttu, Dahlqvist, et al., 1988
CH2 rock 960 gas IR Tyndall, Wallington, et al., 1993
Wallington, Schneider, et al., 2000
CH2 rock 959 Ar IR Kunttu, Dahlqvist, et al., 1988
CCl stretch 697 gas IR Wallington, Schneider, et al., 2000
CCl stretch 669 Ar IR Kunttu, Dahlqvist, et al., 1988
ClCO deform. 469 Ar IR Kunttu, Dahlqvist, et al., 1988
ClCO deform. 463 Ar IR Kunttu, Dahlqvist, et al., 1988
OH torsion 372 Ar IR Kunttu, Dahlqvist, et al., 1988
368 Ar IR Kunttu, Dahlqvist, et al., 1988

Additional references: Jacox, 1994, page 323; Jacox, 2003, page 321


References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wallington, Schneider, et al., 2000
Wallington, T.J.; Schneider, W.F.; Barnes, I.; Becker, K.H.; Sehested, J.; Nielsen, O.J., Stability and infrared spectra of mono-, di-, and trichloromethanol, Chem. Phys. Lett., 2000, 322, 1-2, 97, https://doi.org/10.1016/S0009-2614(00)00384-5 . [all data]

Kunttu, Dahlqvist, et al., 1988
Kunttu, H.; Dahlqvist, M.; Murto, J.; Rasanen, M., Photochemical processes on chloromethyl formate and vinyl formate in low-temperature matrices: infrared spectra and ab initio calculations on chloromethanol and vinyl alcohol, J. Phys. Chem., 1988, 92, 6, 1495, https://doi.org/10.1021/j100317a024 . [all data]

Tyndall, Wallington, et al., 1993
Tyndall, G.S.; Wallington, T.J.; Hurley, M.D.; Schneider, W.F., Rate coefficient for the reaction of hydroxymethyl radicals with chlorine and infrared spectra of chloromethanol and dichloromethanol, J. Phys. Chem., 1993, 97, 8, 1576, https://doi.org/10.1021/j100110a019 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References