Tungsten, pentacarbonyl(triphenylphosphine)-, (OC-6-22)-

• Formula: C₂₃H₁₅O₅PW
• Molecular weight: 586.18
• IUPAC Standard InChI: InChI=1S/C18H15P.5CO.W/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;5*1-2;/h1-15H;;;;;; Copy

  
• IUPAC Standard InChIKey: LCHJMKIEZQLWKI-UHFFFAOYSA-N Copy
• CAS Registry Number: 15444-65-2
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Tungsten, pentacarbonyl(triphenylphosphine)-
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
  • Switch to calorie-based units

Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Paetzold and Abd-el-Mottaleb, 1975
Paetzold, R.; Abd-el-Mottaleb, S., Correlative studies of some spectroscopic and bonding parameters in octahedrally coordinated metal carbonyl complexes, J. Mol. Struct., 1975, 24, 357. [all data]

Daamen, Oskam, et al., 1980
Daamen, H.; Oskam, A.; Stufkens, D.J., U.V. photoelectron (He I and He II) studies of M(CO)₅PR₃ (M = Cr, W and R = C₆H₁₁, C₆H₅, O-i-C₃H₇, OC₆H₅) and W(CO)₅As(C₆H₅)₃, Inorg. Chim. Acta, 1980, 38, 71. [all data]

Torroni, Innorta, et al., 1974
Torroni, S.; Innorta, G.; Foffani, A.; Distefano, G., Interpretation of the mass spectra of substituted chromium and tungsten carbonyls by means of appearance potential measurements, J. Organomet. Chem., 1974, 65, 209. [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.