Hydroxylupanine
- Formula: C15H24N2O2
- Molecular weight: 264.3633
- IUPAC Standard InChI: InChI=1S/C15H24N2O2/c18-12-4-5-16-8-10-6-11(14(16)7-12)9-17-13(10)2-1-3-15(17)19/h10-14,18H,1-9H2
- IUPAC Standard InChIKey: JVYKIBAJVKEZSQ-UHFFFAOYSA-N
- CAS Registry Number: 15358-48-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: 7,14-Methano-4H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-4-one, dodecahydro-9-hydroxy-, [7S-(7α,7aβ,9β,14α,14aα)]-; Lupanine, 13α-hydroxy-; Alkaloid C 2, from Cadia purpurea; Jamaidine; Luparine, hydroxy-; Oxylupanine; 13α-Hydroxylupanine; 13-Hydroxylupanin; 13-Hydroxylupanine; 13-Oxylupanine; d-Hydroxylupanine; Lupanine,13-hydroxy; (+)-13-Hydroxylupanine; 7,14-Methano-2H,11H-dipyrido(1,2-a:1',2'-e)(1,5)diazocin-11-one, dodecahydro-2-hydroxy-, (2S-(2α,7β,7aβ,14β,14aα))-; Hydroxylupanin; Lupanine, hydroxy-; NSC 70827
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- Other data available:
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Normal alkane RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|
| Active phase | DB-1 | DB-1 | DB-1 | SE-54 |
| Column length (m) | 15. | 30. | 30. | 15. |
| Carrier gas | Helium | He | Helium | |
| Substrate | ||||
| Column diameter (mm) | 0.317 | 0.32 | 0.3 | 0.25 |
| Phase thickness (μm) | 0.16 | |||
| Program | 150 0C (2 min) 15 0C/min -> 250 0C 25 0C/min -> 300 0C (5 min) | 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min) | not specified | 150 0C (2 min) 15 0C/min -> 250 0C 25 0C/min -> 200 0C (10 min) |
| I | 2402. | 2402. | 2400. | 2410. |
| Reference | El-Shazly, Ateya, et al., 2001 | Greinwald, van Rensen, et al., 1995 | Wink, Meissner, et al., 1995 | Detzel and Wink, 1993 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
El-Shazly, Ateya, et al., 2001
El-Shazly, A.; Ateya, A.-M.M.; Wink, M.,
Quinolizidine alkaloid profiles of lupunus varius orientalis. L. albus albus, L. hartwegii, and L. densiflorus,
Z. Naturforsch., 2001, 56c, 21-30. [all data]
Greinwald, van Rensen, et al., 1995
Greinwald, R.; van Rensen, I.; Veit, M.; Canto, P.; Witte, L.,
A chemical dichotomy in quinolizidine alkaloid accumulation within the section Spartioides of the genus Genista (Fabaceae: Genisteae),
Biochem. Syst. Ecol., 1995, 23, 1, 89-97, https://doi.org/10.1016/0305-1978(95)93662-M
. [all data]
Wink, Meissner, et al., 1995
Wink, M.; Meissner, C.; Witte, L.,
Patterns of quinolizidine alkaloids in 56 species of the genus Lupinus,
Phytochemistry, 1995, 38, 1, 139-153, https://doi.org/10.1016/0031-9422(95)91890-D
. [all data]
Detzel and Wink, 1993
Detzel, A.; Wink, M.,
Attraction. deterrence or intoxication of bees (Apis mellifera) by plant allelochemicals,
Chemoecology, 1993, 4, 1, 8-18, https://doi.org/10.1007/BF01245891
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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