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tri-«mu»-carbonylhexacarbonyldiiron


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub18.0 ± 5.0kcal/molN/APilcher and Skinner, 1983See also Connor, Skinner, et al., 1972.

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
32.34305.AStephenson and Malanowski, 1987Based on data from 296. - 314. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.73 ± 0.10LPESNakajima, Taguwa, et al., 1994Vertical Detachment Energy: 3.32±0.10 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.91 ± 0.01EIJunk, Preston, et al., 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Connor, Skinner, et al., 1972
Connor, J.A.; Skinner, H.A.; Virmani, Y., Microcalorimetric studies. Thermal decomposition and iodination of metal carbonyls, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 0, 1754, https://doi.org/10.1039/f19726801754 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Nakajima, Taguwa, et al., 1994
Nakajima, A.; Taguwa, T.; Kaya, K., Photoelectron Spectroscopy of Iron Carbonyl Cluster Anions (Fen(CO)m(-), n=1-4), Chem. Phys. Lett., 1994, 221, 5-6, 436, https://doi.org/10.1016/0009-2614(94)00301-7 . [all data]

Junk, Preston, et al., 1970
Junk, G.A.; Preston, F.J.; Svec, H.J.; Thompson, D.T., Ligand effects on the ionization potentials and bond energies of some L1L2Fe2(CO)6 complexes, J. Chem. Soc. A, 1970, 3171. [all data]


Notes

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