chlorotrimethylgermane
- Formula: C3H9ClGe
- Molecular weight: 153.20
- CAS Registry Number: 1529-47-1
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -63.67 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on -136.0 ± 4.0 kcal/mol for the estimated enthalpy of formation of [Ge(Me)3]2O(l) Baldwin, Lappert, et al., 1972. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 8.01 | kcal/mol | RSC | Baldwin, Lappert, et al., 1972 | MS |
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 8.68 | 308. | N/A | Ditsent, Skorokhodov, et al., 1972 | Based on data from 293. to 363. K.; AC |
| 8.22 | 307. | SG | Griffiths and Onyszchuk, 1961 | Based on data from 273. to 341. K.; AC |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S.,
J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]
Ditsent, Skorokhodov, et al., 1972
Ditsent, V.E.; Skorokhodov, I.I.; Terent'eva, N.A.; Zolotareva, M.N.,
Zh. Fiz. Khim., 1972, 46, 7, 1888. [all data]
Griffiths and Onyszchuk, 1961
Griffiths, J.E.; Onyszchuk, M.,
ORGANOGERMANIUM COMPOUNDS: PART I. THE INTERACTION OF HEXAMETHYLDIGERMOXANE AND TRIMETHYLMETHOXYGERMANE WITH BORON TRIFLUORIDE,
Can. J. Chem., 1961, 39, 2, 339-347, https://doi.org/10.1139/v61-040
. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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