Methane, bromodifluoro-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-425.3 ± 0.9kJ/molEqkOkafo and Whittle, 1974 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil258.6KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tfus128.KN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tc411.98KN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.2 K; method of measurement not clearly described; TRC
Quantity Value Units Method Reference Comment
Pc51.32barN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.10 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.275l/molN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.005 l/mol; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
24.0244.AStephenson and Malanowski, 1987Based on data from 194. to 259. K.; AC
24.7209.N/AKudchadker, Kudchadker, et al., 1979Based on data from 194. to 288. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Difluoromethane + Bromine = Hydrogen bromide + Methane, bromodifluoro-

By formula: CH2F2 + Br2 = HBr + CHBrF2

Quantity Value Units Method Reference Comment
Δr-39.9 ± 0.3kJ/molEqkOkafo and Whittle, 1974gas phase

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Okafo and Whittle, 1974
Okafo, E.N.; Whittle, E., Bond dissociation energies from equilibrium studies. Part 5.-The equilibria Br2 + CH2F2 = HBr + CHF2Br and Br2 + CH3F = HBr + CH2FBr. Determination of D(CHF2-Br) and ΔH°f (CHF2Br,g), Trans. Faraday Soc., 1974, 17, 1366-1375. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Salvi-Narkhede, Wang, et al., 1992
Salvi-Narkhede, M.; Wang, B.H.; Adcock, J.I.; Van Hook, W.A., Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2O, J. Chem. Thermodyn., 1992, 24, 1065-75. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kudchadker, Kudchadker, et al., 1979
Kudchadker, A.P.; Kudchadker, S.A.; Shukla, R.P.; Patnaik, P.R., Vapor pressures and boiling points of selected halomethanes, J. Phys. Chem. Ref. Data, 1979, 8, 2, 499, https://doi.org/10.1063/1.555600 . [all data]


Notes

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