tris(acetonitrile) molybdenum tricarbonyl


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub22.9 ± 2.4kcal/molN/APilcher and Skinner, 1983See also Adedeji, Connor, et al., 1978.
Δsub26.60 ± 0.72kcal/molN/ACavell, Ernsting, et al., 1980Based on data from 283. - 308. K.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Adedeji, Connor, et al., 1978
Adedeji, Festus A.; Connor, Joseph A.; Demain, Christopher P.; Martinho-Simoes, Jose A.; Skinner, Henry A.; Zafarani Moattar, Mohamed T., The thermochemistry of carbonyl complexes of Cr, Mo and W with pyridine and acetonitrile, Journal of Organometallic Chemistry, 1978, 149, 3, 333-343, https://doi.org/10.1016/S0022-328X(00)90399-1 . [all data]

Cavell, Ernsting, et al., 1980
Cavell, K.J.; Ernsting, J.M.; Stufkens, D.J., Sublimation enthalpies of the complexes W(CO)6-x(NCCH3)x (x=1,2,3) and Mo(CO)6-x(NCCH3x(x=1,3), Thermochimica Acta, 1980, 42, 3, 343-348, https://doi.org/10.1016/0040-6031(80)85095-7 . [all data]


Notes

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