bis(1,1,1-trimethyl-5,5,5-trifluoro-2,4-pentanedionato)copper (II)


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub120.2 ± 1.0kJ/molMERibeiro da Silva and Gonçalves, 1998 

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
77. ± 2.412.TSysoev, Golubenko, et al., 1993Based on data from 381. - 443. K.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
102. ± 3.366.TSysoev, Golubenko, et al., 1993Based on data from 353. - 379. K.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva and Gonçalves, 1998
Ribeiro da Silva, Manuel A.V.; Gonçalves, Jorge M., Standard molar enthalpies of formation of eight copper(II) fluorinated β-diketonates. Mean (Cu-O) bond dissociation enthalpies, The Journal of Chemical Thermodynamics, 1998, 30, 12, 1465-1481, https://doi.org/10.1006/jcht.1998.0412 . [all data]

Sysoev, Golubenko, et al., 1993
Sysoev, S.V.; Golubenko, A.N.; Nikulina, L.D.; Martynova, T.N., The thermodynamics of sublimation and vaporization of some volatile β-diketonates complexes with the elements of HTSC phases, Thermochimica Acta, 1993, 225, 1, 137-139, https://doi.org/10.1016/0040-6031(93)85089-R . [all data]


Notes

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