Reaction data
+ 
= ( • )
- Reaction by formula: NO- + N2O = (NO- • N2O)
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Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
| ΔrH° (kcal/mol) | Method | Reference | Comment |
|---|---|---|---|
| 5.10 ± 0.90 | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
| 4.60 | N/A | Coe, Snodgrass, et al., 1987 | gas phase; Ion-dipole complex; see Resat, Zengin, et al., 1998; B,M |
| 46.1 ± 4.6 | LPES | Resat, Zengin, et al., 1998 | gas phase; Covalently bound species; the ion-dipole complex EA of Coe, Snodgrass, et al., 1987 is also observed.; B |
| 17.5 ± 2.3 | CIDT | Torchia, Sullivan, et al., 1999 | gas phase; B |
| 8.7 | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; M |
| 7.7 ± 0.1 | DT | Illies, 1988 | gas phase; ΔrH(0 K)=7.70 kcal/mol; M |
References
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hendricks, de Clercq, et al., 2002
Hendricks, J.H.; de Clercq, H.L.; Freidhoff, C.B.; Arnold, S.T.; Eaton, J.G.; Fancher, C.; Lyapustina, S.A.; S.,
Anion solvation at the microscopic level: Photoelectron spectroscopy of the solvated anion clusters, NO-(Y)(n), where Y=Ar, Kr, Xe, N2O, H2S, NH3, H2O, and C2H4(OH)(2),
J. Chem. Phys., 2002, 116, 18, 7926-7938, https://doi.org/10.1063/1.1457444
. [all data]
Coe, Snodgrass, et al., 1987
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H.,
Photoelectron spectroscopy of the negative cluster ions, NO-(N2O)n=1,2,
J. Chem. Phys., 1987, 87, 4302. [all data]
Resat, Zengin, et al., 1998
Resat, M.S.; Zengin, V.; Garner, M.C.; Continetti, R.E.,
Dissociative photodetachment dynamics of isomeric forms of N3O2-,
J. Phys. Chem. A, 1998, 102, 10, 1719-1724, https://doi.org/10.1021/jp973228q
. [all data]
Torchia, Sullivan, et al., 1999
Torchia, J.W.; Sullivan, K.O.; Sunderlin, L.S.,
Thermochemistry of N3O2-,
J. Phys. Chem. A, 1999, 103, 50, 11109-11114, https://doi.org/10.1021/jp992289g
. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S.,
Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O,
J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524
. [all data]
Illies, 1988
Illies, A.J.,
Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures,
J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037
. [all data]
Notes
Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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