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Erythritol

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Condensed phase thermochemistry data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-217.61 ± 0.13kcal/molCcbParks, West, et al., 1946see McClaine, 1947; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-500.18 ± 0.30kcal/molCcbParks, West, et al., 1946see McClaine, 1947; Corresponding «DELTA»fliquid = -217.60 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Deltacsolid-506.21kcal/molCmParks and Manchester, 1952from heat of solution; Corresponding «DELTA»fsolid = -211.57 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar39.79cal/mol*KN/AParks, Kelley, et al., 1929Extrapolation below 90 K, 44.35 J/mol*K. Revision of previous data.; DH
solid,1 bar42.50cal/mol*KN/AParks and Anderson, 1926Extrapolation below 90 K, 55.48 J/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
40.80303.Spaght, Thomas, et al., 1932T = 30 to 150°C.; DH
38.70291.7Parks and Anderson, 1926T = 87 to 292 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil603.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus390.9KN/ABarone, DellaGatta, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Tfus391.6KN/ASpaght, Thomas, et al., 1932, 2Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap22.3kcal/molVNitta, Seki, et al., 1950ALS
Quantity Value Units Method Reference Comment
Deltasub33.5kcal/molVap+FusLopes Jesus, Tomé, et al., 2005AC
Deltasub37.5kcal/molBBarone, Gatta, et al., 1990AC
Deltasub32.3kcal/molVNitta, Seki, et al., 1950ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
23. ± 0.2398.CLopes Jesus, Tomé, et al., 2005AC
27.15 ± 0.26412.TEBarone, Gatta, et al., 1990Based on data from 397. - 428. K.; AC
22.3397.AStephenson and Malanowski, 1987Based on data from 394. - 401. K.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
9.4168390.9Barone and Della Gatta, 1990DH
10.124381.6Spaght, Thomas, et al., 1932DH
9.30391.2Lopes Jesus, Tomé, et al., 2005AC
9.63392.2Jónsdóttir, Cooke, et al., 2002AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
24.09390.9Barone and Della Gatta, 1990DH
26.53381.6Spaght, Thomas, et al., 1932DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 292004

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

McClaine, 1947
McClaine, L.A., Thermodynamic data for some compounds containing carbon, hydrogen and oxygen, Ph.D. Thesis for Stanford University, 1947, 1-57. [all data]

Parks and Manchester, 1952
Parks, G.S.; Manchester, K.E., The heats of solution of erythritol, mannitol and dulcitol; combustion values for liquid polyhydroxy alcohols, J. Am. Chem. Soc., 1952, 74, 3435-34. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Parks and Anderson, 1926
Parks, G.S.; Anderson, C.T., Thermal data on organic compounds. III. The heat capacities, entropies and free energies of tertiary butyl alcohol, mannitol, erythritol and normal butyric acid, J. Am. Chem. Soc., 1926, 48, 1506-1512. [all data]

Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-888. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Barone, DellaGatta, et al., 1990
Barone, G.; DellaGatta, G.; Ferro, D.; Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86, 75. [all data]

Spaght, Thomas, et al., 1932, 2
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-8. [all data]

Nitta, Seki, et al., 1950
Nitta, I.; Seki, S.; Momotani, M.; Suzuki, K.; Nakagawa, S., On the phase transition in pentaerythritol (II)., Proc. Jpn. Acad., 1950, 26, 11. [all data]

Lopes Jesus, Tomé, et al., 2005
Lopes Jesus, A.J.; Tomé, Luciana I.N.; Eusébio, M. Ermelinda; Redinha, J.S., Enthalpy of Sublimation in the Study of the Solid State of Organic Compounds. Application to Erythritol and Threitol, J. Phys. Chem. B, 2005, 109, 38, 18055-18060, https://doi.org/10.1021/jp051621n . [all data]

Barone, Gatta, et al., 1990
Barone, Guido; Gatta, Giuseppe Della; Ferro, Daniela; Piacente, Vincenzo, Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, Faraday Trans., 1990, 86, 1, 75, https://doi.org/10.1039/ft9908600075 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Barone and Della Gatta, 1990
Barone, G.; Della Gatta, G., Ferro D., and Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86(1), 75-79. [all data]

Jónsdóttir, Cooke, et al., 2002
Jónsdóttir, Svava Ósk; Cooke, Stephen A.; Macedo, Eugénia A., Modeling and measurements of solid--liquid and vapor--liquid equilibria of polyols and carbohydrates in aqueous solution, Carbohydrate Research, 2002, 337, 17, 1563-1571, https://doi.org/10.1016/S0008-6215(02)00213-6 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References