Erythritol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil603.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus390.9KN/ABarone, DellaGatta, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Tfus391.6KN/ASpaght, Thomas, et al., 1932Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δvap93.3kJ/molVNitta, Seki, et al., 1950ALS
Quantity Value Units Method Reference Comment
Δsub140.kJ/molVap+FusLopes Jesus, Tomé, et al., 2005AC
Δsub157.kJ/molBBarone, Gatta, et al., 1990AC
Δsub135.kJ/molVNitta, Seki, et al., 1950ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
97. ± 1.398.CLopes Jesus, Tomé, et al., 2005AC
113.6 ± 1.1412.TEBarone, Gatta, et al., 1990Based on data from 397. to 428. K.; AC
93.3397.AStephenson and Malanowski, 1987Based on data from 394. to 401. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
39.400390.9Barone and Della Gatta, 1990DH
42.359381.6Spaght, Thomas, et al., 1932, 2DH
38.9391.2Lopes Jesus, Tomé, et al., 2005AC
40.3392.2Jónsdóttir, Cooke, et al., 2002AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
100.8390.9Barone and Della Gatta, 1990DH
111.0381.6Spaght, Thomas, et al., 1932, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Barone, DellaGatta, et al., 1990
Barone, G.; DellaGatta, G.; Ferro, D.; Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86, 75. [all data]

Spaght, Thomas, et al., 1932
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-8. [all data]

Nitta, Seki, et al., 1950
Nitta, I.; Seki, S.; Momotani, M.; Suzuki, K.; Nakagawa, S., On the phase transition in pentaerythritol (II)., Proc. Jpn. Acad., 1950, 26, 11. [all data]

Lopes Jesus, Tomé, et al., 2005
Lopes Jesus, A.J.; Tomé, Luciana I.N.; Eusébio, M. Ermelinda; Redinha, J.S., Enthalpy of Sublimation in the Study of the Solid State of Organic Compounds. Application to Erythritol and Threitol, J. Phys. Chem. B, 2005, 109, 38, 18055-18060, https://doi.org/10.1021/jp051621n . [all data]

Barone, Gatta, et al., 1990
Barone, Guido; Gatta, Giuseppe Della; Ferro, Daniela; Piacente, Vincenzo, Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, Faraday Trans., 1990, 86, 1, 75, https://doi.org/10.1039/ft9908600075 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Barone and Della Gatta, 1990
Barone, G.; Della Gatta, G., Ferro D., and Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86(1), 75-79. [all data]

Spaght, Thomas, et al., 1932, 2
Spaght, M.E.; Thomas, S.B.; Parks, G.S., Some heat capacity data on organic compounds obtained with a radiation calorimeter, J. Phys. Chem., 1932, 36, 882-888. [all data]

Jónsdóttir, Cooke, et al., 2002
Jónsdóttir, Svava Ósk; Cooke, Stephen A.; Macedo, Eugénia A., Modeling and measurements of solid--liquid and vapor--liquid equilibria of polyols and carbohydrates in aqueous solution, Carbohydrate Research, 2002, 337, 17, 1563-1571, https://doi.org/10.1016/S0008-6215(02)00213-6 . [all data]


Notes

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