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Chromium, pentacarbonyl(triphenylphosphine)-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub170.2 ± 6.8kJ/molN/ABoxhoorn, Ernsting, et al., 1980MS

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
170.2 ± 6.8336.MEBoxhoorn, Ernsting, et al., 1980, 2Based on data from 324. - 347. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.40 ± 0.05EIPaetzold and Abd-el-Mottaleb, 1975 
7.30PEDaamen, Oskam, et al., 1980Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C18H15PCr+10.95COEITorroni, Innorta, et al., 1974 
C19H15OPCr+9.74COEITorroni, Innorta, et al., 1974 
C20H15O2PCr+9.33COEITorroni, Innorta, et al., 1974 
C21H15O3PCr+9.12COEITorroni, Innorta, et al., 1974 
C22H15O4PCr+8.5COEITorroni, Innorta, et al., 1974 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boxhoorn, Ernsting, et al., 1980
Boxhoorn, G.; Ernsting, J.M.; Stufkens, D.J.; Oskam, A., Thermochim. Acta, 1980, 42, 315. [all data]

Boxhoorn, Ernsting, et al., 1980, 2
Boxhoorn, G.; Ernsting, J.M.; Stufkens, D.J.; Oskam, A., Vapour pressure measurements on M(CO)5L complexes (M «58875» Cr, W; L «58875» CO, P(OØ)3, PØ3, PMe3, NMe3 and pyridazine), Thermochimica Acta, 1980, 42, 3, 315-321, https://doi.org/10.1016/0040-6031(80)85092-1 . [all data]

Paetzold and Abd-el-Mottaleb, 1975
Paetzold, R.; Abd-el-Mottaleb, S., Correlative studies of some spectroscopic and bonding parameters in octahedrally coordinated metal carbonyl complexes, J. Mol. Struct., 1975, 24, 357. [all data]

Daamen, Oskam, et al., 1980
Daamen, H.; Oskam, A.; Stufkens, D.J., U.V. photoelectron (He I and He II) studies of M(CO)5PR3 (M = Cr, W and R = C6H11, C6H5, O-i-C3H7, OC6H5) and W(CO)5As(C6H5)3, Inorg. Chim. Acta, 1980, 38, 71. [all data]

Torroni, Innorta, et al., 1974
Torroni, S.; Innorta, G.; Foffani, A.; Distefano, G., Interpretation of the mass spectra of substituted chromium and tungsten carbonyls by means of appearance potential measurements, J. Organomet. Chem., 1974, 65, 209. [all data]


Notes

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