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Aluminum ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Aluminum ion (1+) + Aluminum = (Aluminum ion (1+) bullet Aluminum)

By formula: Al+ + Al = (Al+ bullet Al)

Quantity Value Units Method Reference Comment
Deltar20.8kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) bullet Aluminum) + Aluminum = (Aluminum ion (1+) bullet 2Aluminum)

By formula: (Al+ bullet Al) + Al = (Al+ bullet 2Al)

Quantity Value Units Method Reference Comment
Deltar25.8kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) bullet 2Aluminum) + Aluminum = (Aluminum ion (1+) bullet 3Aluminum)

By formula: (Al+ bullet 2Al) + Al = (Al+ bullet 3Al)

Quantity Value Units Method Reference Comment
Deltar46.8kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) bullet 3Aluminum) + Aluminum = (Aluminum ion (1+) bullet 4Aluminum)

By formula: (Al+ bullet 3Al) + Al = (Al+ bullet 4Al)

Quantity Value Units Method Reference Comment
Deltar59.3kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) bullet 4Aluminum) + Aluminum = (Aluminum ion (1+) bullet 5Aluminum)

By formula: (Al+ bullet 4Al) + Al = (Al+ bullet 5Al)

Quantity Value Units Method Reference Comment
Deltar55.3kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) bullet 5Aluminum) + Aluminum = (Aluminum ion (1+) bullet 6Aluminum)

By formula: (Al+ bullet 5Al) + Al = (Al+ bullet 6Al)

Quantity Value Units Method Reference Comment
Deltar103.1kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) bullet 6Aluminum) + Aluminum = (Aluminum ion (1+) bullet 7Aluminum)

By formula: (Al+ bullet 6Al) + Al = (Al+ bullet 7Al)

Quantity Value Units Method Reference Comment
Deltar44.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 8Aluminum) + Aluminum = (Aluminum ion (1+) bullet 9Aluminum)

By formula: (Al+ bullet 8Al) + Al = (Al+ bullet 9Al)

Quantity Value Units Method Reference Comment
Deltar65.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 9Aluminum) + Aluminum = (Aluminum ion (1+) bullet 10Aluminum)

By formula: (Al+ bullet 9Al) + Al = (Al+ bullet 10Al)

Quantity Value Units Method Reference Comment
Deltar67.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 10Aluminum) + Aluminum = (Aluminum ion (1+) bullet 11Aluminum)

By formula: (Al+ bullet 10Al) + Al = (Al+ bullet 11Al)

Quantity Value Units Method Reference Comment
Deltar72.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 11Aluminum) + Aluminum = (Aluminum ion (1+) bullet 12Aluminum)

By formula: (Al+ bullet 11Al) + Al = (Al+ bullet 12Al)

Quantity Value Units Method Reference Comment
Deltar81.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 12Aluminum) + Aluminum = (Aluminum ion (1+) bullet 13Aluminum)

By formula: (Al+ bullet 12Al) + Al = (Al+ bullet 13Al)

Quantity Value Units Method Reference Comment
Deltar72.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 13Aluminum) + Aluminum = (Aluminum ion (1+) bullet 14Aluminum)

By formula: (Al+ bullet 13Al) + Al = (Al+ bullet 14Al)

Quantity Value Units Method Reference Comment
Deltar60.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 14Aluminum) + Aluminum = (Aluminum ion (1+) bullet 15Aluminum)

By formula: (Al+ bullet 14Al) + Al = (Al+ bullet 15Al)

Quantity Value Units Method Reference Comment
Deltar67.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) bullet 15Aluminum) + Aluminum = (Aluminum ion (1+) bullet 16Aluminum)

By formula: (Al+ bullet 15Al) + Al = (Al+ bullet 16Al)

Quantity Value Units Method Reference Comment
Deltar69.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

Aluminum ion (1+) + Formaldehyde = (Aluminum ion (1+) bullet Formaldehyde)

By formula: Al+ + CH2O = (Al+ bullet CH2O)

Quantity Value Units Method Reference Comment
Deltar27.5 ± 2.4kcal/molEqGBouchard, Brenner, et al., 1997RCD

Aluminum ion (1+) + Methyl fluoride = (Aluminum ion (1+) bullet Methyl fluoride)

By formula: Al+ + CH3F = (Al+ bullet CH3F)

Quantity Value Units Method Reference Comment
Deltar21.5 ± 2.0kcal/molEqGBouchard, Brenner, et al., 1997RCD

Aluminum ion (1+) + Acetylene = (Aluminum ion (1+) bullet Acetylene)

By formula: Al+ + C2H2 = (Al+ bullet C2H2)

Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.0kcal/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

Aluminum ion (1+) + Ethylene = (Aluminum ion (1+) bullet Ethylene)

By formula: Al+ + C2H4 = (Al+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.0kcal/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

Aluminum ion (1+) + Ethane = (Aluminum ion (1+) bullet Ethane)

By formula: Al+ + C2H6 = (Al+ bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar9.0 ± 2.0kcal/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

(Aluminum ion (1+) bullet Acetone) + Acetone = (Aluminum ion (1+) bullet 2Acetone)

By formula: (Al+ bullet C3H6O) + C3H6O = (Al+ bullet 2C3H6O)

Quantity Value Units Method Reference Comment
Deltar28.3kcal/molHPMSBauschlicher, Bouchard, et al., 1991gas phase; laser desorption; M
Quantity Value Units Method Reference Comment
Deltar30.7cal/mol*KHPMSBauschlicher, Bouchard, et al., 1991gas phase; laser desorption; M

Aluminum ion (1+) + 1,3-Diazine = (Aluminum ion (1+) bullet 1,3-Diazine)

By formula: Al+ + C4H4N2 = (Al+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar38.0 ± 1.4kcal/molCIDTAmunugama and Rodgers, 2001RCD

Aluminum ion (1+) + Pyrrole = (Aluminum ion (1+) bullet Pyrrole)

By formula: Al+ + C4H5N = (Al+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar44.0kcal/molRAKGapeev and Yang, 2000RCD

Aluminum ion (1+) + Pyridine = (Aluminum ion (1+) bullet Pyridine)

By formula: Al+ + C5H5N = (Al+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar45.5 ± 2.5kcal/molCIDTRodgers, Stanley, et al., 2000RCD

Aluminum ion (1+) + Benzene = (Aluminum ion (1+) bullet Benzene)

By formula: Al+ + C6H6 = (Al+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar35.1 ± 1.9kcal/molRAKDunbar, Klippenstein, et al., 1996RCD

Aluminum ion (1+) + Water = (Aluminum ion (1+) bullet Water)

By formula: Al+ + H2O = (Al+ bullet H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
24.9 (+3.6,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) bullet Water) + Water = (Aluminum ion (1+) bullet 2Water)

By formula: (Al+ bullet H2O) + H2O = (Al+ bullet 2H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
16.1 (+1.2,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) bullet 2Water) + Water = (Aluminum ion (1+) bullet 3Water)

By formula: (Al+ bullet 2H2O) + H2O = (Al+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
15.2 (+1.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) bullet 3Water) + Water = (Aluminum ion (1+) bullet 4Water)

By formula: (Al+ bullet 3H2O) + H2O = (Al+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
12.5 (+1.4,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hanley, Ruatta, et al., 1987
Hanley, L.; Ruatta, S.A.; Anderson, S.L., Collision - Induced Dissciation of Aluminum Cluster Ions: Fragmentation Patterns, Bond Energies, and Structures for Al2+ - Al7+, J. Chem. Phys., 1987, 87, 1, 260, https://doi.org/10.1063/1.453623 . [all data]

Jarrold, Ray, et al., 1990
Jarrold, M.F.; Ray, U.; Bower, J.E.; Creegan, K.M., Photodissociation of Metal Cluster Ions. Dissociation Energies and Optical Spectroscopy, J. Chem. Soc. Faraday Trans., 1990, 86, 13, 2537, https://doi.org/10.1039/ft9908602537 . [all data]

Bouchard, Brenner, et al., 1997
Bouchard, F.; Brenner, V.; Carra, C.; Hepburn, J.W.; Koyanagi, G.K.; McMahon, T.B.; Ohanessian, G.; Peschke, M., Energetics and Structure of Complexes of Al+ with Small Organic Molecules in the Gas Phase, J. Phys. Chem. A, 1997, 101, 33, 5885, https://doi.org/10.1021/jp9703465 . [all data]

Stockigt, Schwarz, et al., 1996
Stockigt, D.; Schwarz, J.; Schwarz, H., Theoretical and Experimental Studies on the Bond Dissociation Energies of Al(methane)+, Al(acetylene)+, Al(ethene)+, and Al(ethane)+, J. Phys. Chem., 1996, 100, 21, 8786, https://doi.org/10.1021/jp960060k . [all data]

Bauschlicher, Bouchard, et al., 1991
Bauschlicher, C.W.; Bouchard, F.; Hepburn, J.W.; McMahon, T.B.; Surjasasmita, I.; Roth, L.M.; Gord, J.R., On the Structure of Al(Acetone)2+, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 15, https://doi.org/10.1016/0168-1176(91)85094-3 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Dunbar, Klippenstein, et al., 1996
Dunbar, R.C.; Klippenstein, S.J.; Hrusak, J.; Stockigt, D.; Schwarz, H., Binding Energy of Al(C6H6)+ from the Analysis of Radiative Association Kinetics, J. Am. Chem. Soc., 1996, 118, 22, 5277, https://doi.org/10.1021/ja953235x . [all data]

Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B., Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2), J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045 . [all data]


Notes

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