Trifluorosilyl radical


Gas Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1100.1100. - 6000.
A 42.3964782.72312
B 97.327790.250286
C -88.85937-0.054788
D 28.862400.004184
E -0.415787-3.587279
F -1102.965-1120.312
G 306.0182366.7268
H -1085.330-1085.330
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1977 Data last reviewed in December, 1977
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
298.59.59282.3282.4-0.01
300.59.76282.7282.40.11
400.66.36300.9284.86.44
500.70.79316.2289.613.31
600.73.88329.4295.220.55
700.76.04341.0300.928.05
800.77.52351.2306.635.74
900.78.54360.4312.043.54
1000.79.31368.7317.351.44
1100.80.01376.3322.359.40
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
1100.79.97376.3322.359.40
1200.80.46383.3327.167.43
1300.80.84389.8331.775.49
1400.81.15395.8336.183.59
1500.81.40401.4340.291.72
1600.81.60406.6344.299.87
1700.81.77411.6348.0108.0
1800.81.91416.3351.7116.2
1900.82.04420.7355.2124.4
2000.82.14424.9358.6132.6
2100.82.23428.9361.9140.8
2200.82.31432.8365.0149.1
2300.82.38436.4368.0157.3
2400.82.44439.9370.9165.6
2500.82.50443.3373.8173.8
2600.82.55446.5376.5182.1
2700.82.59449.6379.2190.3
2800.82.63452.6381.7198.6
2900.82.66455.5384.2206.8
3000.82.70458.3386.6215.1
3100.82.72461.1389.0223.4
3200.82.75463.7391.3231.6
3300.82.77466.2393.5239.9
3400.82.79468.7395.7248.2
3500.82.81471.1397.8256.5
3600.82.83473.4399.9264.8
3700.82.85475.7401.9273.0
3800.82.86477.9403.9281.3
3900.82.88480.1405.8289.6
4000.82.89482.2407.7297.9
4100.82.90484.2409.5306.2
4200.82.91486.2411.3314.5
4300.82.92488.2413.1322.8
4400.82.93490.1414.8331.1
4500.82.94491.9416.5339.4
4600.82.95493.8418.2347.7
4700.82.96495.5419.8356.0
4800.82.97497.3421.4364.3
4900.82.98499.0423.0372.6
5000.82.98500.7424.5380.9
5100.82.99502.3426.0389.1
5200.83.00503.9427.5397.4
5300.83.01505.5429.0405.7
5400.83.01507.1430.4414.1
5500.83.02508.6431.8422.4
5600.83.03510.1433.2430.7
5700.83.03511.6434.5439.0
5800.83.04513.0435.9447.3
5900.83.05514.4437.2455.6
6000.83.06515.8438.5463.9

References

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), References